September 2024
·
9 Reads
Fusion Engineering and Design
This page lists works of an author who doesn't have a ResearchGate profile or hasn't added the works to their profile yet. It is automatically generated from public (personal) data to further our legitimate goal of comprehensive and accurate scientific recordkeeping. If you are this author and want this page removed, please let us know.
September 2024
·
9 Reads
Fusion Engineering and Design
August 2024
Fusion Engineering and Design
January 2024
·
1 Read
September 2023
·
13 Reads
AM&P Technical Articles
The development of polymers, traditionally neglected in fusion materials research, is crucial to the success of commercial fusion energy. This article provides an overview of the materials science and technology challenges that will need to be addressed to develop the mechanically “soft” materials that will serve functional needs in a fusion pilot plant.
August 2023
·
34 Reads
·
1 Citation
Fusion Science & Technology
July 2023
·
100 Reads
·
2 Citations
We have studied photoluminescence (PL) properties of vacuum pump mineral oil as a function of the type and intensity of ionizing radiation exposure. The mineral oil has a simple aliphatic structure, which possesses no chromophore in the traditional sense. Unexpected PL in the mineral oil has characteristic features such as variation of the emission peak wavelength depending on the excitation wavelength and intensity dramatically increasing with radiation dose. The observed behavior can be understood in the framework of a previously suggested model introducing aggregation-induced PL and the formation of conjugated clusters comprising nontraditional chromophores. Our findings can be used for the development of optical sensors for real-time monitoring of oil utilized in vacuum pumps in nuclear fusion reactors.
June 2023
·
5 Reads
·
1 Citation
Fusion Science & Technology
March 2023
·
95 Reads
·
8 Citations
Nano Energy
Magnetism in curved nano-geometries has opened a new path to design novel characteristics and phenomena that could greatly impact the future fundamental and applied studies of materials. In this report, a hexagonally-packed array of magnetic nano-caps (or nano-patches, NP) exhibiting unique magnetic anisotropy and optimal nanostructure for fast hydrogen kinetics is explored as a sensing element for the spark-free magnetic-circular-dichroism (MCD) H2 sensor. The MCD H2 sensor outperforms the state-of-the-art optical sensors reported to date and satisfies the most challenging performance targets imposed by US Department of Energy. In particular, a Pd67Co33 NP sensor exhibits response time of t90 < 0.9 s, recovery time of t10 < 9.0 s over the 1-100 mbar H2 partial pressure range, and limit of detection (LOD) of ~1 ppm. The LOD improves to <700 ppb, when the signal-to-noise ratio is enhanced by stacking three NP arrays. Using a 30-nm TAF (Teflon AF 2400) polymer coating, the sorption kinetics of the Pd67Co33/TAF sensor are significantly accelerated, with t90 < 0.4 s and t10 < 2.8 s over the same pressure range. When the Pd67Co33/TAF sensor is further coated with a 100-nm poly(methyl methacrylate) (PMMA) layer, a rapid sorption time of t90 < 0.5 s, LOD < 1 ppm and excellent sensor accuracy (<2.5% full scale) are maintained, while the sensor obtains strong selectivity against interference gases and moisture and a negligible aging effect. The MCD nano-cap sensor platform may have a great impact on the future deployment of H2 fuel, H2 environmental monitoring sensors, and fast proton-based magneto-ionic devices.
October 2022
·
12 Reads
Fusion Science & Technology
The study of tritium aging effects on materials requires a significant time commitment as a consequence of its 12.3-year half-life, making developmental studies prohibitively difficult and expensive. However, detailed knowledge of long-term aging effects is critical to the development of structural and storage materials for future fusion reactor technologies. As a result, multiple approaches to simulated aging effects have been investigated. We report a method of simulated tritium aging achieved though the incorporation of trapped gases via high-energy ball milling of LaNi4.25Al0.75 alloy storage material. Experimental results verify the presence of trapped gases by a combination of temperature programmed desorption and LECO chemical analysis. Following gas incorporation, we find that many of the degraded hydrogen sorption properties found in aged storage materials are reproduced by the ball milled powders.
October 2022
·
19 Reads
·
1 Citation
Fusion Science & Technology
Developing a Fusion Pilot Plant (FPP) design that minimizes risks due to tritium in-process inventory (IPI) is an important concern for the operation of commercial devices. This becomes even more of concern since an FPP will be breeding more tritium than is burned in the reactor for sustainability. The IPI is the tritium moving through the system that is not in the storage and delivery subsystem. A process model that solves time-dependent differential equations based on processing times was used to investigate the reduction of the IPI of a potential fuel cycle design. The impact of new and more efficient technologies such as direct internal recycling (DIR), metal foil pumps, continuous pumping, improved isotope separation, and hydrogen separating continuous pumps on IPI was investigated by adjusting subsystem processing times and material flow streams. It was shown that any of the insertions of DIR studied in this paper caused a reduction in the total IPI of the system and proved to be the optimal way to reduce the IPI in the system. Fuel cycle modifications near the torus, such as a coupled DIR and improved pumping systems, produced the largest reductions in tritium inventory.
... Among the industrial applications of mineral oils, one should mention first of all their usage as lubricants (engines, bearings etc.), insulators (high voltage transformers), and coolant fluids (e.g., solar energy concentrators) [8]. High-purity mineral oils can be also used in the rotary or diffusion pumps of vacuum systems [9]. Therefore, physical properties such as viscosity, thermal stability, dielectric constant, specific heat and vapor pressure are of paramount importance. ...
August 2023
Fusion Science & Technology
... It should be noted that the combination in Eq. (11) uses equal weighting. In solar forecasting studies, once the initial conditions need to be perturbed, parameter diversity is a useful method as it considers numerical weather prediction models (NWP) [76,77]. Kalman filter is the best method for NWP which estimates the "true" state of a dynamical system from noisy measurement data [76]. ...
March 2022
Fusion Engineering and Design
... For plasmonic patchy NPs, a key challenge has been on the synthesis, as it is hard to achieve high precision in patterning ligand molecules on a NP surface with nanometer precision. For colloidal particles that are micrometer in size, various top-down methods such as electron beam lithography and deposition have been utilized to coat the particles with surface patches [14][15][16], thereby enabling directional self-assembly [16,17] and diverse applications such as biomedicine [18], sensing [19], self-propelling motors [20,21], and anti-counterfeiting [22]. However, most of these methods have a resolution that is around tens to hundreds of nanometer resolution [23,24], not sufficient for NPs. ...
Reference:
Polymer-Patched Plasmonic Nanoparticles
April 2021
... The magnetic circular dichroism (MCD) is used to probe the magnetic dynamics in the magnetic nano-cap arrays upon (de)hydrogenation. Owing to unique magnetic property such as tunable magnetic anisotropy and magnetochiral effect [1,[22][23][24][25] and optimal material and nanostructure design for fast hydrogen sorption kinetics [18,26], the MCD spark-free H 2 sensor exhibits excellent sensing performance that meets or surpasses the most challenging performance targets imposed by DOE [17]. In particular, a Pd 67 Co 33 sensor exhibits response time of t 90 < 0.9 s, recovery time of t 10 < 9.0 s over the entire 1-100 mbar H 2 partial pressure range, with limit of detection (LOD) of ~1 ppm. ...
March 2021
ACS Applied Nano Materials
... The monitoring of tritium concentrations in the vicinity of power plants is currently a subject of heightened interest. As tritium levels decline, there is a need to monitor lower levels of tritium activity in the environment [6][7][8]. ...
September 2020
Fusion Engineering and Design
... In fact, the peculiar dynamics associated with the molecular sublattice makes HPs a case study of the outmost complexity for what concerns electric polarization and RE, two interlaced phenomena that depend on the detail of the atomic structure. To rationalize this complexity, in the literature, a distinction is made between static RE and dynamic RE: the former is derived by static, built-in dipole fields that may occur in a number of situations: genuinely polarized low-temperature surfaces, 19 ferroelastic nanodomains, 20 nanocrystals, 21,22 2D perovskites, [23][24][25][26][27][28] heterostructures, 29,30 perovskite quantum-dots, 31 and doped perovskites. 32 The dynamical RE 6,14 explores the possibility that even in a globally centrosymmetric phase, which is believed to represent the HPs at room temperature, the RE can still show up, due to correlated molecular fluctuations, albeit on short length-scale ($nm) and timescale ($ps). ...
March 2020
... Note that the ΔMCD H 2 isotherm could be measured at any combination of λ and B. The shape of ΔMCD isotherm curve is generally similar to that of optical transmission isotherm [18], and no hysteresis is observed at the measured pressure range. In addition, the plateau pressure shifts significantly to higher pressure than that of a pure Pd NP sensor [18,38] and is above the probing pressure range. The result is consistent with the previous observation for bulk PdCo alloys [26,39,40] and similar to the behaviors of the PdCu alloy nanoparticles [41]. ...
February 2020
Nano Energy
... So, they have been widely used in many fields. [25][26][27] Based on this advantage, protein imprinting also began to develop magnetic micro/nanomaterials as polymeric carriers. A series of protein imprinting was carried out on their surfaces to obtain magnetic surface imprinted polymers with easy separation and good adsorption performance. ...
May 2020
ACS Applied Materials & Interfaces
... Note that the optical transmission of a stand-alone PS nanosphere monolayer does not change upon its exposure to hydrogen ( Supplementary Fig. 14). The increasing trend of optical transparency upon hydrogenation has been also observed in Pd thin films, although this increase is independent of wavelength in the visible-NIR region 30,31 . ...
September 2019
... 13,76 They are crucial in making magnetic storage devices, magnetic beads that are used in biotechnology, contrast enhancement in magnetic resonance imaging (MRI), targeted drug delivery and ferrofluids. 13,77 The magnetic nanoparticles that are based on green synthesis have been utilised in semiconductors, 78 Iron nanoparticles (FeNPs) gained importance in the industrial sites, textile 82 and plastic industries with coatings made of nanofibre and nanowire. 13 It is also used in tissue repair, 83 drug delivery, 84 biological fluids detoxification, 85,86 hyperthermia, 85 and cell separation by immunoassay. ...
June 2019
Materials Horizons