Frank Ligterink’s research while affiliated with Rijksdienst voor Cultureel Erfgoed and other places

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Publications (13)


An enhanced optical micro-fading device
  • Article

September 2022

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56 Reads

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6 Citations

Journal of Cultural Heritage

Gauthier Patin

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Robert G. Erdmann

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Frank Ligterink

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[...]

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This paper introduces a new set-up for the determination of colour change on cultural heritage objects, referred to herein as a stereo-microfading tester. The system uses high quality optics through the implementation of a stereo-microscope as its central element. This technology enables new developments such as incorporation of high quality imaging systems, and separation of fading and colour measurement processes. This paper describes this new micro-fading set-up and evaluates its performance against traditional devices based on the measurement of blue wool standards. The results show a correlation between the fading performance obtained on different devices while highlighting a significant variability inherent to the blue wool samples


Recreating Van Gogh's original colors on museum displays

January 2019

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421 Reads

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5 Citations

Electronic Imaging

The colors of Van Gogh's landscape painting Field with Irises near Arles have changed considerably. To digitally reconstruct its original colors, we use an unprecedented broad scientific analysis and experimental art technological approach, by physically reconstructing oil paints of all pigments used by Van Gogh. We closely match the original paints, and for the first time determine all the optical properties involved. The investigation led to a digital image representing the original colors as good as possible. We found that for the digital color reconstruction it is important to take into account that museum lighting is often relatively dark in order to better preserve paintings. Since this affects the best way of representing the reconstructed colors on the display, we adapted the digital reconstructed image. We also corrected for the technical specifications of the electronic display on which the reconstructions will be displayed in the museum. Based on the reconstruction we conclude that the original colors in the painting used to be much brighter, and agreed much better with Van Gogh's own description of the color composition of this painting. We show that unlike the current colors of the painting, the reconstructed colors are consistent with the color theories on which Van Gogh based his work.


Schematic model structure with environmental and paper intrinsic variables
Predicted pH change of the paper extract upon uptake of airborne acetic acid
Predicted DP change for a neutral paper exposed or not exposed to 150 ppb of acetic acid
Predicted depolymerization in 100 years of papers with different initial pH, unexposed (circles) and exposed (disks) to 150 ppb of acetic acid. RH = 50% and T = 20 °C
pH shift of the extract of three papers upon adding acetic acid. Broken lines are experimental data while solid lines theoretical predictions based on Eq. 3 in the text
The limited impact of acetic acid in archives and libraries
  • Article
  • Full-text available

October 2018

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572 Reads

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22 Citations

Abstract For over two decades the exposure of paper heritage collections to outdoor and indoor generated gaseous pollutants has been perceived as an important threat to their preservation. Following explicit or implicit advise from conservation science, many archives, libraries and museums have implemented special chemical filtration units to prevent possible pollution induced damage. The most abundant, potentially harmful, indoor generated pollutant found in paper loaded storage rooms is acetic acid. Acids are known to promote the chemical degradation of cellulose, the major constituent of paper. These combined facts make clear why acetic acid has received much attention by conservation science as a prime suspect pollutant causing paper degradation. However, new experimental evidence contradicts the claim that acetic acid in typical storage situations causes significant damage to paper heritage. In this study a mathematical model is presented that expresses our understanding of the causal chain of processes connecting acetic acid exposure to paper damage. The model simply combines existing partial models describing (1) the transfer of acetic acid through air, (2) the pH response of paper and (3) the kinetics of acid-catalyzed hydrolytic depolymerization. The model makes apparent that the impact of acetic acid on archival and library collections is rather limited and poses an insignificant risk and as such requires a re-evaluation of existing data.

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Preservation Management for Libraries, Archives and Museums

June 2018

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150 Reads

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1 Citation

[Preservation is] the management of risks to collections to restrict the rate of loss of collection value to an optimum, low level. (Waller, 2003) [Conservation is] the management of resources, especially but not exclusively, material cultural resources, to prolong the lifetime of material culture, to enhance usability, and to clarify contained messages of various kinds for the continuance and betterment of humanity. (Rosvall et al., 1995) [Conservation research is] the generation of knowledge that can be applied to achieve a maximum effective collection value through optimisation of the combination of preservation of and access to a collection as a whole, under a given conservation budget. (this chapter) Introduction The preservation and conservation of cultural heritage collections are core activities of libraries, archives and museums. They are recognized as important issues that require significant resources. Conservation research, carried out in many locations all over the world by a variety of researchers, forms an integral part of conservation policies. Knowledge generated by conservation research is necessary to underpin sound decision making. Actors involved in conservation research range from specialized conservation scientists and conservators to students of conservation colleges and professionals in related, sometimes industrial, research disciplines. Their work is condensed into an expanding body of literature and knowledge. It must be recognized that the incentive for conservation research does not always originate from the objective of collection preservation only. The involvement in research of commercial companies may, for example, be motivated by public relations concerns. Non-commercial research institutes almost always act in political environments that may influence the conservation research agenda. We should be aware that these external forces do introduce a risk of biased research. In practice it can be difficult to recognize this potential bias. It is interesting to see, as an example, how and to what extent a major funding programme, such as that of the European Union, has influenced directions in conservation research by importing its political ambitions in research programmes. An overview of several developments and certain ‘trends’ in conservation science is presented in Porck and Teygeler (2000). Another external motive for conservation research (i.e., not instigated by the goal of preservation), is pure scientific curiosity. Scientific curiosity is definitely a vital driving force for any research, but is also difficult to control. At some point research may become an aim in itself and will get detached from its original goals.




Reconstructing Van Gogh’s palette to determine the optical characteristics of his paints

March 2018

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2,361 Reads

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28 Citations

The colors of Field with Irises near Arles, painted by Van Gogh in Arles in 1888, have changed considerably. To get an idea of how this painting, as well as other works by Van Gogh, looked shortly after their production, the Revigo (Reassessing Vincent van Gogh’s colors) research project was initiated. The aim of this project was to digitally visualize the original colors of paintings and drawings by Vincent van Gogh, using scientific methods backed by expert judgement where required. We adopted an experimental art technological approach and physically reconstructed Van Gogh’s full palette of oil paints, closely matching those he used to paint Field with Irises near Arles. Sixteen different paints were reconstructed, among which the most light-sensitive pigments and linseed oil, which is prone to yellowing, were produced according to 19th century practice. The resulting pigments and oils were chemically analyzed and compared to those used by Van Gogh. The ones that resembled his paints the most were used in the paint reconstructions. Other pigments were either obtained from the Cultural Heritage Agency’s collection of historical pigments, or purchased from Kremer Pigmente. The reconstructed paints were subsequently used to calculate the absorption K and scattering S parameters of the individual paints. Using Kubelka–Munk theory, these optical parameters could in turn be used to determine the color of paint mixtures. We applied this method successfully to digitally visualize the original colors of Field with Irises near Arles. Moreover, the set of optical parameters presented here can similarly be applied to calculate digital visualizations of other paintings by Van Gogh and his contemporaries.



In this third and last part of our series of articles, we conclude the analysis and present the color reconstruction of Van Gogh's Field with Irises near Arles. Here, we combine hyperspectral imaging, XRF, microscopic analysis, paint reconstructions and colorimetric investigations.
Digitally reconstructing Van Gogh's Field with Irises near Arles part 3: Determining the original colors

December 2017

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769 Reads

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26 Citations

Color Research & Application

In earlier articles, we determined the spatial distributions and concentrations of all pigments used by Van Gogh in his painting Field with Irises near Arles. The colors of some pigments are expected to have changed over time, especially those of chrome yellow, cochineal, and eosin lake. For all pigments in this painting, we made physical paint reconstructions by following historical sources on raw materials and production processes, and we determined their optical properties. We combined this with pigment concentration maps to reconstruct the original colors of the painting digitally. When substituting the reconstruction paints into the calculations, we found that technical-scientific data was not sufficient to resolve several issues. In those cases, discussions within the broad interdisciplinary team allowed us to make informed decisions. These issues refer to the representation of the sky area, and the original contributions of the red lake pigments to local colors. The digitally reconstructed colors of the painting show that due to discoloring of red lake pigments, the irises in the field have changed from a warm purple to purplish blue, and many pink spots in the field have turned to white. The range of yellows in the field has decreased and partly turned to dark brown. The digital reconstruction gives a better understanding of the color scheme used by Van Gogh when compared to remarks the artist made in letters when describing this painting. Also, the original color composition is seen to be aligned with color theories on which Van Gogh based his work.


Predicted concentration variation of pigment Prussian Blue.
Digitally reconstructing van Gogh's Field with Irises near Arles part 2: Pigment concentration maps: KIRCHNER et al.

August 2017

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378 Reads

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25 Citations

Color Research & Application

Colors in many paintings of great art historical value have changed over time, due to the combined effects of natural ageing, accumulated surface grime, and materials added during later conservation treatments. The physical restoration of the colors in such paintings is not possible. This article describes one part of work done to digitally restore the colors of van Gogh's painting Field with Irises near Arles, dating from May 1888. We have used multispectral reflectance data to estimate absorption K and backscattering S parameters of Kubelka-Munk 2-constant theory. This was done for all 13 pigments known to have been used by van Gogh in this painting, and based on this the concentration maps for each of these pigments were calculated. We validated the calculated concentration maps in several ways. For some pigments, we were able to predict spots on the painting where the pigment is expected to occur in unmixed form based on visual examination. For several other pigments, the concentration maps could be shown to agree with XRF data. Finally, for some other pigments the concentration maps were supported by additional evidence from microscopic examinations, remarks in van Gogh's letters and from early color reproductions. For the 1.7 million pixels for which multispectral data is available, the average color difference between the calculated and measured spectral reflectance curves is CIEDE2000 = 1.05. This further confirms that the Kubelka-Munk calculations are well suited to describe the variety of spectral reflectance on the painting.


Citations (9)


... While Bitossi et al. 35 offer a more extensive survey on spectroscopy technique, their work lacks timeliness in relevant assessments. Recent advancements in the use of spectroscopy technique in cultural heritage include their application for depth profiling of material surfaces 36 and detecting information in opaque layers 37,38 . However, the current literature has yet to comprehensively evaluate these emerging applications, revealing a significant gap in research. ...

Reference:

Application of spectroscopy technique in cultural heritage: systematic review and bibliometric analysis
An enhanced optical micro-fading device
  • Citing Article
  • September 2022

Journal of Cultural Heritage

... It is interesting that van Gogh himself was well aware that paintings age, as he wrote to his brother on April 30th 1889 that "paintings fade like flowers" [2]. Many studies have focused on the chemistry of aging of van Gogh's paintings [9][10][11][12][13][14][15][16], as well as attempts to predict the evolution of the appearance of those paintings [23][24][25]. With this as a background, there are two main directions that we have followed in our analyses of the digital images of F454, F457, and F458: ...

Recreating Van Gogh's original colors on museum displays
  • Citing Article
  • January 2019

Electronic Imaging

... These mechanisms include internal diffusion and surface evaporation. The emissions from a material can be controlled through one or both mechanisms at different times [55][56][57] . For materials where the change in airflow visibly influences its emissions, either by an observed increase or decrease, these emissions are governed by the surface evaporation mechanism 56,58,59 . ...

The limited impact of acetic acid in archives and libraries

... Madden and Seifi (2011) initially argue in favor of viewpoint A) by stating that digitization can help prevent the destruction of ancient manuscripts and their intellectual content, but that the manuscripts are invaluable because they embody the physical materials of Iran's cultural heritage. However, these authors corroborate an idea by Deegan (2006) that provokes reflection on the distinction of preserving physical artifacts as opposed to the idea of preserving information within artifactsviewpoint B). Deegan (2006) states that physical manuscripts are less valuable than their digital copies for research involving extensive detailed reading-reading can even weaken the manuscript. ...

Preservation Management for Libraries, Archives and Museums
  • Citing Article
  • June 2018

... Although a substantial amount of research is available on the materials and techniques employed by Van Gogh in later periods , less information is available for his early Dutch period paintings [ 31 , 32 ]. Numerous papers have evaluated the physical and chemical properties of materials used by Van Gogh with an emphasis on the identification of materials [ 11-13 , 22 , 23 , 25 , 28 , 30 ], degradation of colorants [ 9 , 10 , 14-21 , 24 , 26 , 29 ], mechanical behavior of oil paints associated with aging [ 33 , 34 ], and reconstruction of the artist's palette [ 27 ]. Nevertheless, research has been conducted on the materials found in earlier paintings by Van Gogh [ 31 , 32 ] including The Head of Peasant [ 35 ] and The Potato Eaters [ 36 ] both from 1885. ...

Reconstructing Van Gogh’s palette to determine the optical characteristics of his paints

... Digital rejuvenation (Berns, 2019) is the attempt to reconstruct the appearance of an artwork as it was in the past, and it is of high interest for a wide range of stakeholders: art historians, conservators, museum curators, educators and the general public. Very often, rejuvenation approaches start from accurate colour representations of the artwork based on spectrophotometric measurements of its current status (Kirchner et al., 2018). This is combined with knowledge about the constituent materials and their colour change behaviour, which is usually assessed with accelerated aging experiments (Kirchner et al., 2018). ...

Digitally reconstructing Van Gogh's Field with Irises near Arles part 3: Determining the original colors
  • Citing Article
  • December 2017

Color Research & Application

... They conducted virtual restoration of the color in specific areas of Vincent Van Gogh's painting "Bedroom." Hyperspectral imaging and scanning XRF spectrometry were utilized by Kirchner [4,5] from the Netherlands to determine the spatial distribution of the pigments in Van Gogh's "Field with Irises near Arles," and then the Kubelka-Munk model was used to determine a concentration map for all pigments to achieve a virtual recovery of this painting. The color change mechanism of lead white pigment in mural paintings was investigated by Bruder et al. [6] by utilizing laser-induced breakdown spectroscopy. ...

Digitally reconstructing van Gogh's Field with Irises near Arles part 2: Pigment concentration maps: KIRCHNER et al.
  • Citing Article
  • August 2017

Color Research & Application

... In 2013, the REVIGO (REassessing VIncent van GOgh's colors) project was started by the Van Gogh museum in collaboration with the University of Amsterdam, RCE (Dutch: Rijksdienst voor het Cultureel Erfgoed, English: The Cultural Heritage Agency of the Netherlands), and AKZO Nobel [11][12][13][14]. The purpose of this project is to establish an optimal and transparent methodology for the virtual reconstruction of colors that could then be usefully applied to otherworks. ...

Digitally reconstructing Van Gogh's Field with Irises near Arles . Part 1: Varnish: KIRCHNER etal.
  • Citing Article
  • August 2017

Color Research & Application

... As mentioned in the method, participants in the first phase include reporting actions of medical librarians in specialized journals, newspapers, libraries' websites, local publications, published lectures, libraries reports, social media, and electronic discussion groups about COVID-19 crisis. Therefore, after identifying the resources and the degree of their relevance to the medical librarian's experiences about the COVID-19, finally 19 documents (number [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18][19] were analyzed in a thematic manner. Demographic informations of participants in the second phase consisting of 10 medical librarians (number 20-29) are as follows: ...

Chemical air filtration in archives and libraries reconsidered

Studies in Conservation