April 2025
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2 Reads
Nano Today
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April 2025
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2 Reads
Nano Today
April 2025
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10 Reads
Carbon
April 2025
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4 Reads
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1 Citation
Nano Today
February 2025
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17 Reads
February 2025
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49 Reads
The Journal of Physical Chemistry Letters
December 2024
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14 Reads
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1 Citation
Perovskite solar cell (PSC) technology holds great promise with continuously improving power conversion efficiency; however, the use of metal electrodes hinders its commercialization and the development of tandem designs. Although single-walled carbon nanotubes (SWCNTs), as one-dimensional materials, have the potential to replace metal electrodes in PSCs, their poor conductivity still limits their application. In this study, the near-infrared (NIR)-absorbing anionic heptamethine cyanine dye-doped SWCNTs functioned in a dual role as an efficient charge-selective layer and electrode in PSCs. Benefiting from the improvement in conductivities and matched energy level of doped-SWCNT, the dual-role SWCNT electrodes applied to PSCs achieved a better performance than the undoped PSCs with a higher short circuit current (JSC) and fill factor (FF).
November 2024
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51 Reads
This study presents an acetylene gas sensor capable of in situ monitoring transformer oils. This sensor utilizes carbon nanotubes (CNTs) embedded in polyimide (PI) synthesized by floating catalyst chemical vapor deposition. Unlike conventional sensors that target hydrocarbon gases dissolved in oil and measure the gas extracted from the oil, the proposed CNT‐PI sensor detects gas within the oil in real time. The PI embedding technique effectively anchors and shields the CNT network against fluidic damage, ensuring stable sensing performance over 6 months, even under friction stress caused by oil convection. Decorating CNTs with gold nanoparticles further enhances the sensitivity and response of the sensor. The sensor achieves a high response (10.5% at 30 ppm) and fast response/recovery times (28 s/77 s), Furthermore, the sensor demonstrates good response (10.4% at 30 ppm) and moderate response/recovery times (444 s/670 s) in an oil medium, which qualifies for industrial applications. Additionally, a CNT‐PI‐based heater is integrated into the sensor as a multilayer component, maintaining an optimal operating temperature of 90 °C. The CNT‐PI sensor demonstrates consistent gas‐sensing performance even after 10,000 bending cycles and exhibits superior characteristics, indicating its compatibility with various forms of transformers.
October 2024
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78 Reads
The controlled synthesis of 1D van der Waals (1D vdW) heterostructures, specifically single‐walled carbon nanotubes encapsulated within boron nitride nanotubes (SWCNT@BNNT), presents a challenge due to an incomplete understanding of the factors influencing BNNT growth. This study investigates the growth yield of SWCNT@BNNT heterostructures produced using zeolite‐supported SWCNT templates on SiO2‐coated Transmission Electron Microscopy (TEM) grids, which enable in situ synthesis and thorough evaluation of each step without compromising the nanotube structure. The high‐resolution TEM analysis reveals a significant improvement in BNNT coverage on individual nanotubes, increasing from 9% to 42%, through optimization of the ammonia borane precursor amount. A thorough comparison of BNNT growth efficiency is performed using zeolite‐supported SWCNT templates against the current benchmark of free‐standing SWCNT films, highlighting comparable synthesis yields despite different morphologies and SWCNT diameter distributions. By integrating all Raman and TEM data from the studied SWCNT@BNNT samples, a correlation between BNNT coverage and the intensity of the buckling R‐mode of BNNTs is established, providing a reliable criterion for evaluating BNNT growth efficiency in 1D vdW heterostructures. This work advances the understanding and characterization of 1D vdW heterostructures, offering insights into synthesizing hetero‐nanotubes using other types of SWCNT templates and paving the way for their diverse applications.
August 2024
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51 Reads
Recent advances in metadevices, featuring complex subwavelength metastructures, have dramatically transformed the control and manipulation of electromagnetic waves. However, the inherently narrow operational bandwidth of these devices, stemming from their wavelength‐specific meta‐atoms, restricts their application in rapidly advancing fields such as the Internet of Things and advanced intelligent systems. Here, a novel hyperband synergistic metadevice is introduced, realized through a comprehensive multi‐scale meta‐atom architecture. The complementary metal‐oxide‐semiconductor (CMOS)‐compatible prototype integrates the distinct properties of double‐walled carbon nanotubes with advanced interlayer and intralayer coupling mechanisms, coherently combining nanoscale, microscale, and macroscale meta‐atoms. This prototype is thus adept at operating across a wide electromagnetic spectrum, spanning from the centimeter‐wavelength microwave band to the hundred nanometer‐wavelength visible and infrared optical band. Significantly, this singular device synergistically delivers three critical functionalities: selective microwave absorption, efficient terahertz beam steering, and enhanced optical transparency. These result signifies a breakthrough in hyperband electromagnetic device engineering, leading to compact, versatile, intelligent electromagnetic platforms.
July 2024
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39 Reads
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7 Citations
ACS Nano
... Modern skyscrapers now increasingly use glass in facades, while semitransparent solar cells with a high-power conversion efficiency (PCE) and high average visible light transmittance (AVT; over 20%) [2] are promoting the development of power glass and sustainable buildings. Among the existing PV technologies, perovskite solar cells (PSCs) have attracted significant attention because of their adjustable bandgap and color, high PCE, low cost, and flexibility [3][4][5]. Semitransparent perovskite solar cells (PSCs) can be constructed by substituting the opaque metal electrode, but the primary challenge associated with balancing the power conversion efficiency (PCE) and optical transmittance lies in the development of high-quality perovskite films and minimizing the energy lost in devices. ...
December 2024
... [258] Alternative selective filtration techniques were developed using silicon sealant and high pressure for the fabrication of 2D nanotube structures in various shapes, for instance, concentric circles and spiral zones, for optical applications. [531,532] The fourth level is paramount for scaling as it provides not only new devices (for example, diffraction elements, [258] gratings, [642] or heaters [643] ) but ready-to-use industrial components for FETs, solar cells, transparent sensors, etc. [644,645] The fifth level of nanotube organization (dealing with the interaction between films) is the least explored for CNT films or aerogels. [646] A few works published to date describe www.advancedsciencenews.com www.advmat.de ...
July 2024
ACS Nano
... New experiments are focusing on the role of temperature in suppressing coherence between droplets [19,20] opening the way to the study of the finite temperature phase diagram. On the other hand, a supersolid phase in the sense predicted by Andreev and Lifshitz [1], namely a condensate of zero-point vacancies, has been observed in a single layer of 3 He adsorbed on a carbon nanotube [21,22]. On the theory side, while usually ultracold dilute Bose gases are very well described by the Gross-Pitaevskii (GP) theory, the dipolar cluster and supersolid states require the inclusion of the repulsive Lee-Huang-Yang correction in the GP equation (a.k.a. ...
June 2024
... Pristine CNTs typically undergo p-doping at ambient conditions due to oxygen adsorption, increasing hole concentration. [200,201] Exposure to electron acceptors such as NO 2 gas, a p-type dopant, further increases hole concentration and conductivity, [325,326,327] while electron donors such as NH 3 , an n-type dopant, decrease conductivity. [328,329] CNT diameter and chirality significantly influence gas adsorption and doping. ...
April 2024
... In this work, we have focused on the changes that occur in the resonance Raman spectra of SWCNT thin films as a result of their treatments. Figure 3 [38], which show the evolution of peak parameters related to doping effects and the influence of applied pressure on mixed-chirality SWCNT film, respectively. ...
March 2024
ACS Nano
... While cold storage (e.g., -80°C) stabilized Ti 3 C 2 T x for over 39 weeks, it is energy-intensive [18]. Compelling MXenes in organic solvents isolated them from water, improving the chemical stability but impairing physical dispersity and complicating re-dispersion in water for subsequent applications [19]. Similarly, covalent surface modifications with agents such as silane [4], protein [20], diazonium [21], and organophosphate passivated defects/ edges on Ti 3 C 2 T x but irreversibly altered its interfacial charge properties in water, compromising electrochemical performance. ...
December 2023
... The Raman signal is collected using the same objective lens, focused into a 230 μm core fiber, and transmitted to a spectrometer (Jobin-Yvan, FNR640) equipped with a TE-cooled CCD (Andor, Newton). 64 Soft XAS and XES are carried out at the Advanced Light Source (ALS) at Lawrence Berkeley National Laboratory on beamline 8.0.1. using the iRIXS endstation. ...
November 2023
The Journal of Physical Chemistry Letters
... For example, D. Polli et al. successfully used three independent, synchronized non-collinear OPAs to generate a pump pulse at 520 nm and two probe pulses in the visible and near-infrared regions, highlighting the existence and significance of conical intersections in visual photochemistry [13]. Nonetheless, the generation of multiple wavelength ultrafast pulses through multi-oscillator systems involves complex optical path designs [14], leading to increased costs, difficulties in system adjustment, and challenges in achieving precise pulse synchronization. This highlights the pressing need for single-cavity high-peak-power multi-wavelength laser sources. ...
July 2023
... Therefore, for the Er 3+ -Yb 3+ ion pair, the up-conversion luminescence intensity of the sample is significantly enhanced because the process can significantly increase the utilization rate of Er 3+ ions for 1550 nm photons. [44][45][46][47][48][49][50][51][52][53] Since we do not observe the reverse energy transfer between Ho 3+ -Yb 3+ ion pairs, the up-conversion luminescence intensity of the samples was significantly quenched due to the cross-relaxation between the Ho 3+ -Yb 3+ ions. The schematic diagram of the reverse energy transfer between the ions in Fig. 17 can well summarize the process of the reverse energy transfer between the Er 3+ -Ho 3+ -Yb 3+ ions. ...
July 2023
Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy
... Mode-locked fiber lasers have attracted great interest from researchers due to their advantages of high pulse energy, short pulse duration, minimum alignment requirement, and low maintenance. [1][2][3] Up to now, mode-locked fiber lasers have been widely applied in the fields of industrial processing, medical diagnosis and treatment, optical fiber communication, and terahertz optics. [4][5][6] Compared to the active mode-locking realized by inserting a modulator or injecting an external pulse into the fiber cavity to actively modulate the light wave, the passive mode-locking is simpler and more efficient, which incorporates a saturable absorber (SA) into the laser cavity to generate ultrashort pulses. ...
September 2023