Esko I. Kauppinen’s research while affiliated with The University of Tokyo and other places

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Publications (737)


Corrigendum to “Direct patterning of carbon nanotube aerosols for high-performance flexible electronics” [Nanotoday 61 (2025) 102635]
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April 2025

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2 Reads

Nano Today

Zhenyu Xu

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David Fox

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Esko I. Kauppinen



Efficient Growth of 1D Van der Waals Heterostructures on Zeolite‐Supported SWCNTs (Small 8/2025)

February 2025

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17 Reads



Concept of GNW-5-doped SWCNTs utilized as electrodes in PSCs. (a) Doping GNW-5 dye molecules using spin-coating. (b) Perovskite solar cell structure used for this work. (c) Schematic diagram of the molecular structure of GNW-5 and its interaction with SWCNTs.
Cross-sectional TEM images of (a) GNW-5-doped PSCs and (b) detailed enlargement of the GNW-5-doped SWCNT layer. (c) J–V curves of PSCs using GNW-5-doped SWCNTs and pristine SWCNTs. (d) EQE spectra of PSCs before and after doping with GNW-5.
Properties of SWCNT before and after GNW-5 doping. (a) Seebeck coefficient measurement with fitting curve. (b) 2D peak maximum of Raman spectrum. (c) Photoelectron yield spectroscopy. (d) Energy level diagram of PSCs with GNW-5 doping.
The perovskite solar cell performance of different concentration of GNW-5.
Heptamethine Cyanine Dye-Doped Single-Walled Carbon Nanotube Electrodes for Improving Performance of HTL-Free Perovskite Solar Cells
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  • Full-text available

December 2024

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14 Reads

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1 Citation

Perovskite solar cell (PSC) technology holds great promise with continuously improving power conversion efficiency; however, the use of metal electrodes hinders its commercialization and the development of tandem designs. Although single-walled carbon nanotubes (SWCNTs), as one-dimensional materials, have the potential to replace metal electrodes in PSCs, their poor conductivity still limits their application. In this study, the near-infrared (NIR)-absorbing anionic heptamethine cyanine dye-doped SWCNTs functioned in a dual role as an efficient charge-selective layer and electrode in PSCs. Benefiting from the improvement in conductivities and matched energy level of doped-SWCNT, the dual-role SWCNT electrodes applied to PSCs achieved a better performance than the undoped PSCs with a higher short circuit current (JSC) and fill factor (FF).

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a) Fabrication of the Au‐CNT‐PI C2H2 gas sensor integrated with a heater. b) Photo of the fabricated device, along with individual images of the sensing and heating layers. SEM images of c) pristine FCCVD‐CNT, d) CNT‐PI, and e) Au (3 nm)‐decorated CNT. f) EDS analysis of Au (3 nm)‐decorated CNT. g) XPS survey spectra for CNT‐glass, CNT‐PI, and Au (3 nm)‐decorated CNT. XPS analyses of the C1s peaks of h) CNT‐glass and i) CNT‐PI. j) FTIR spectra of the PI substrate and CNT‐PI.
a) Gas response as a function of varying density of the FCCVD‐CNT film. b) Sensitivity and linearity within the range of 1–30 ppm. c) Gas response at 5 ppm in terms of different CNT densities. d) Gas response in terms of different Au NP thicknesses. e) Comparison of response with and without Au NP decoration at 0.5 and 1 ppm. f) Selectivity comparison of the CNT sensors at 90 °C with and without the Au NPs. g) Comparison of gas response characteristics under air and nitrogen flows. Gas sensing mechanism h) in an oxygen‐rich environment (21%) and i) in an oxygen‐deficient environment (2%).
a) Gas response characteristics in terms of the different temperatures within the range of 1–100 ppm. b) Response and recovery time with different operating temperatures at 30 ppm c) Gas response with different relative humidity values. d) Sensitivity and linearity within the range of 1–30 ppm. Cyclic response of the sensor under e) 30 ppm and f) 1 ppm. g) Long‐term stability of 60 days with different gas concentrations. h) Comparison of the sensor response with different bending radii.
a) Schematic of the testing set‐up for the C2H2 sensor in insulation oil. b) The variation in sheet resistance before and after 6 months of oil exposure with and without PI embedding. c) Sensor response in terms of the C2H2 concentration in transformer insulation oil. d) Response and recovery time with different operating temperatures in oil at 50 ppm. e) Sensitivity and linearity of the sensor in insulation oil. f) Repeatability depending on the speed of magnetic stirring. g) Hysteresis curve between 10 and 100 ppm.
a) Temperature–time plots for the CNT‐PI heater with a HD sample under various biases. b) Steady‐state temperatures of the CNT‐PI heater with respect to the transparency of the CNT film under different bias voltages. c) Time‐dependent temperature curve and steady‐state temperatures under 20 times on/off cyclic voltages. d) Hysteresis curve between 30 and 90 °C. e) Long‐term stability of the CNT‐PI heater over 5 h. f) Analysis of surface temperature by thermal imaging camera based on bending distances under 10.5 V bias voltage. g) Temperature of the CNT‐PI heater during 10,000 bending cycles.
Highly Sensitive and Stable In Situ Acetylene Detection in Transformer Oil Using Polyimide‐Embedded Carbon Nanotubes

November 2024

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51 Reads

This study presents an acetylene gas sensor capable of in situ monitoring transformer oils. This sensor utilizes carbon nanotubes (CNTs) embedded in polyimide (PI) synthesized by floating catalyst chemical vapor deposition. Unlike conventional sensors that target hydrocarbon gases dissolved in oil and measure the gas extracted from the oil, the proposed CNT‐PI sensor detects gas within the oil in real time. The PI embedding technique effectively anchors and shields the CNT network against fluidic damage, ensuring stable sensing performance over 6 months, even under friction stress caused by oil convection. Decorating CNTs with gold nanoparticles further enhances the sensitivity and response of the sensor. The sensor achieves a high response (10.5% at 30 ppm) and fast response/recovery times (28 s/77 s), Furthermore, the sensor demonstrates good response (10.4% at 30 ppm) and moderate response/recovery times (444 s/670 s) in an oil medium, which qualifies for industrial applications. Additionally, a CNT‐PI‐based heater is integrated into the sensor as a multilayer component, maintaining an optimal operating temperature of 90 °C. The CNT‐PI sensor demonstrates consistent gas‐sensing performance even after 10,000 bending cycles and exhibits superior characteristics, indicating its compatibility with various forms of transformers.


Efficient Growth of 1D Van der Waals Heterostructures on Zeolite‐Supported SWCNTs

October 2024

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78 Reads

The controlled synthesis of 1D van der Waals (1D vdW) heterostructures, specifically single‐walled carbon nanotubes encapsulated within boron nitride nanotubes (SWCNT@BNNT), presents a challenge due to an incomplete understanding of the factors influencing BNNT growth. This study investigates the growth yield of SWCNT@BNNT heterostructures produced using zeolite‐supported SWCNT templates on SiO2‐coated Transmission Electron Microscopy (TEM) grids, which enable in situ synthesis and thorough evaluation of each step without compromising the nanotube structure. The high‐resolution TEM analysis reveals a significant improvement in BNNT coverage on individual nanotubes, increasing from 9% to 42%, through optimization of the ammonia borane precursor amount. A thorough comparison of BNNT growth efficiency is performed using zeolite‐supported SWCNT templates against the current benchmark of free‐standing SWCNT films, highlighting comparable synthesis yields despite different morphologies and SWCNT diameter distributions. By integrating all Raman and TEM data from the studied SWCNT@BNNT samples, a correlation between BNNT coverage and the intensity of the buckling R‐mode of BNNTs is established, providing a reliable criterion for evaluating BNNT growth efficiency in 1D vdW heterostructures. This work advances the understanding and characterization of 1D vdW heterostructures, offering insights into synthesizing hetero‐nanotubes using other types of SWCNT templates and paving the way for their diverse applications.


Concept of hyperband synergistic metadevices. a) Proposal of metadevices with an operation bandwidth covering the whole non‐ionizing electromagnetic spectrum range. Conceptual illustrations of hyperband (b) hologram and (c) communication. d) Schematic illustration of our demonstrated hyperband metadevice integrating three functionalities (selective microwave absorption, THz beam steering, and enhanced optical transparency) and (e) its potential application example for multifunctional vehicle windshields.
Multi‐scale meta‐atom architecture design of hyperband synergistic metadevices. a) Flowchart of the realization of the hyperband synergistic multifunctions. b) Structural configuration of the proposed DWCNT‐based metadevice.
Enhanced optical transparency of the hyperband synergistic metadevice prototype. Optical images of the used a) unpatterned DWCNT film (inset: scanning electron microscopy image), b) patterned DWCNT film, c) DWCNT fishnet and d) DWCNT patch array films. e) Measured optical spectra of a pristine DWCNT device and an integrated three‐layer patterned DWCNT prototype.
Selective microwave absorption of the hyperband synergistic metadevice prototype. a) Simulated reflection and transmission spectra of the coding array and pristine DWCNT film. b) Simulated transmission spectra of DWCNT fishnet, patch array and the integrated metadevice. Simulated absorption spectra of the proposed metadevice with different parameters (c) d and (d) hq, respectively. e) Equivalent lumped circuit model of the DWCNT‐based metadevice. f) Measured reflection, transmission and absorption coefficients of the fabricated DWCNT‐based metadevice with the simulated results.
THz beam steering of the hyperband synergistic metadevice prototype. a) 3D schematic and working principle of the DWCNT hyperband metadevice in the THz band. b) THz reflection amplitude of “0” and “1” elements and (c) phase difference between them in zones A and B, respectively. Simulated normalized 3D scattering patterns of the proposed DWCNT‐based metadevice with coding arrangement of (d) all “1” elements, e) the chessboard “0” and “1” distribution, and (f) specially designed “0” and “1” distribution. g) Schematic of the THz‐TDS experimental setup. h) Time‐domain THz signals of a pristine DWCNT film and metal plate reference. i) Measured 2D scattering patterns of the fabricated DWCNT‐based metadevice at ≈0.81 THz.
Hyperband Synergistic Metadevices

August 2024

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51 Reads

Recent advances in metadevices, featuring complex subwavelength metastructures, have dramatically transformed the control and manipulation of electromagnetic waves. However, the inherently narrow operational bandwidth of these devices, stemming from their wavelength‐specific meta‐atoms, restricts their application in rapidly advancing fields such as the Internet of Things and advanced intelligent systems. Here, a novel hyperband synergistic metadevice is introduced, realized through a comprehensive multi‐scale meta‐atom architecture. The complementary metal‐oxide‐semiconductor (CMOS)‐compatible prototype integrates the distinct properties of double‐walled carbon nanotubes with advanced interlayer and intralayer coupling mechanisms, coherently combining nanoscale, microscale, and macroscale meta‐atoms. This prototype is thus adept at operating across a wide electromagnetic spectrum, spanning from the centimeter‐wavelength microwave band to the hundred nanometer‐wavelength visible and infrared optical band. Significantly, this singular device synergistically delivers three critical functionalities: selective microwave absorption, efficient terahertz beam steering, and enhanced optical transparency. These result signifies a breakthrough in hyperband electromagnetic device engineering, leading to compact, versatile, intelligent electromagnetic platforms.



Citations (68)


... Modern skyscrapers now increasingly use glass in facades, while semitransparent solar cells with a high-power conversion efficiency (PCE) and high average visible light transmittance (AVT; over 20%) [2] are promoting the development of power glass and sustainable buildings. Among the existing PV technologies, perovskite solar cells (PSCs) have attracted significant attention because of their adjustable bandgap and color, high PCE, low cost, and flexibility [3][4][5]. Semitransparent perovskite solar cells (PSCs) can be constructed by substituting the opaque metal electrode, but the primary challenge associated with balancing the power conversion efficiency (PCE) and optical transmittance lies in the development of high-quality perovskite films and minimizing the energy lost in devices. ...

Reference:

Fabrication of Bifacial-Modified Perovskites for Efficient Semitransparent Solar Cells with High Average Visible Transmittance
Heptamethine Cyanine Dye-Doped Single-Walled Carbon Nanotube Electrodes for Improving Performance of HTL-Free Perovskite Solar Cells

... [258] Alternative selective filtration techniques were developed using silicon sealant and high pressure for the fabrication of 2D nanotube structures in various shapes, for instance, concentric circles and spiral zones, for optical applications. [531,532] The fourth level is paramount for scaling as it provides not only new devices (for example, diffraction elements, [258] gratings, [642] or heaters [643] ) but ready-to-use industrial components for FETs, solar cells, transparent sensors, etc. [644,645] The fifth level of nanotube organization (dealing with the interaction between films) is the least explored for CNT films or aerogels. [646] A few works published to date describe www.advancedsciencenews.com www.advmat.de ...

Wafer-Scale Fabrication of Wearable All-Carbon Nanotube Photodetector Arrays
  • Citing Article
  • July 2024

ACS Nano

... New experiments are focusing on the role of temperature in suppressing coherence between droplets [19,20] opening the way to the study of the finite temperature phase diagram. On the other hand, a supersolid phase in the sense predicted by Andreev and Lifshitz [1], namely a condensate of zero-point vacancies, has been observed in a single layer of 3 He adsorbed on a carbon nanotube [21,22]. On the theory side, while usually ultracold dilute Bose gases are very well described by the Gross-Pitaevskii (GP) theory, the dipolar cluster and supersolid states require the inclusion of the repulsive Lee-Huang-Yang correction in the GP equation (a.k.a. ...

Quantum degeneracy in mesoscopic matter: Casimir effect and Bose-Einstein condensation
  • Citing Article
  • June 2024

... Pristine CNTs typically undergo p-doping at ambient conditions due to oxygen adsorption, increasing hole concentration. [200,201] Exposure to electron acceptors such as NO 2 gas, a p-type dopant, further increases hole concentration and conductivity, [325,326,327] while electron donors such as NH 3 , an n-type dopant, decrease conductivity. [328,329] CNT diameter and chirality significantly influence gas adsorption and doping. ...

Aerosol‐Synthesized Surfactant‐Free Single‐Walled Carbon Nanotube‐Based NO2 Sensors: Unprecedentedly High Sensitivity and Fast Recovery

... In this work, we have focused on the changes that occur in the resonance Raman spectra of SWCNT thin films as a result of their treatments. Figure 3 [38], which show the evolution of peak parameters related to doping effects and the influence of applied pressure on mixed-chirality SWCNT film, respectively. ...

Evaluating the Efficiency of Boron Nitride Coating in Single-Walled Carbon-Nanotube-Based 1D Heterostructure Films by Optical Spectroscopy

ACS Nano

... While cold storage (e.g., -80°C) stabilized Ti 3 C 2 T x for over 39 weeks, it is energy-intensive [18]. Compelling MXenes in organic solvents isolated them from water, improving the chemical stability but impairing physical dispersity and complicating re-dispersion in water for subsequent applications [19]. Similarly, covalent surface modifications with agents such as silane [4], protein [20], diazonium [21], and organophosphate passivated defects/ edges on Ti 3 C 2 T x but irreversibly altered its interfacial charge properties in water, compromising electrochemical performance. ...

High‐permittivity Solvents Increase MXene Stability and Stacking Order Enabling Ultraefficient Terahertz Shielding

... The Raman signal is collected using the same objective lens, focused into a 230 μm core fiber, and transmitted to a spectrometer (Jobin-Yvan, FNR640) equipped with a TE-cooled CCD (Andor, Newton). 64 Soft XAS and XES are carried out at the Advanced Light Source (ALS) at Lawrence Berkeley National Laboratory on beamline 8.0.1. using the iRIXS endstation. ...

Interacting Phonons between Layers in Raman Spectra of Carbon Nanotubes inside Boron Nitride Nanotubes
  • Citing Article
  • November 2023

The Journal of Physical Chemistry Letters

... For example, D. Polli et al. successfully used three independent, synchronized non-collinear OPAs to generate a pump pulse at 520 nm and two probe pulses in the visible and near-infrared regions, highlighting the existence and significance of conical intersections in visual photochemistry [13]. Nonetheless, the generation of multiple wavelength ultrafast pulses through multi-oscillator systems involves complex optical path designs [14], leading to increased costs, difficulties in system adjustment, and challenges in achieving precise pulse synchronization. This highlights the pressing need for single-cavity high-peak-power multi-wavelength laser sources. ...

Broadband synchronization of ultrafast pulse generation with double-walled carbon nanotubes

... Therefore, for the Er 3+ -Yb 3+ ion pair, the up-conversion luminescence intensity of the sample is significantly enhanced because the process can significantly increase the utilization rate of Er 3+ ions for 1550 nm photons. [44][45][46][47][48][49][50][51][52][53] Since we do not observe the reverse energy transfer between Ho 3+ -Yb 3+ ion pairs, the up-conversion luminescence intensity of the samples was significantly quenched due to the cross-relaxation between the Ho 3+ -Yb 3+ ions. The schematic diagram of the reverse energy transfer between the ions in Fig. 17 can well summarize the process of the reverse energy transfer between the Er 3+ -Ho 3+ -Yb 3+ ions. ...

Upconversion Nanoparticles@Single-walled Carbon Nanotubes Composites as Efficient Self-monitored Photo-Thermal Agents
  • Citing Article
  • July 2023

Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy

... Mode-locked fiber lasers have attracted great interest from researchers due to their advantages of high pulse energy, short pulse duration, minimum alignment requirement, and low maintenance. [1][2][3] Up to now, mode-locked fiber lasers have been widely applied in the fields of industrial processing, medical diagnosis and treatment, optical fiber communication, and terahertz optics. [4][5][6] Compared to the active mode-locking realized by inserting a modulator or injecting an external pulse into the fiber cavity to actively modulate the light wave, the passive mode-locking is simpler and more efficient, which incorporates a saturable absorber (SA) into the laser cavity to generate ultrashort pulses. ...

Temporal soliton dynamics of synchronised ultrafast fibre lasers