Eric David’s research while affiliated with École de Technologie Supérieure and other places

This study investigates the role of filler interface on suppressing the erosion of room temperature vulcanized silicone rubber composites filled with fumed silica, nano alumina trihydrate and sub-micron hexagonal boron nitride fillers during DC dry-band arcing. Simultaneous thermogravimetric-differential thermal analyses indicate a superior effect for fumed silica in suppressing the depolymerization of silicone rubber and promoting radical based crosslinking. This can be attributed to favorable interactions at the fumed silica-silicone interface tethering the siloxane chains. At low filler loading of alumina trlhydrate, water of hydration has insignificant effects on suppressing depolymerization compared to that influenced by fumed silica's interface at equal filler loading. Similarly, incorporating thermally conductive boron nitride filler in silicone rubber does not show improvement in the depolymerization rate compared to that influenced by fumed silica. These findings correlate with the +DC inclined plane tracking and erosion test outcomes indicating superior erosion performance for the fumed silica filled composite. This accordingly supports the influential role of the filler interface over the water of hydration and thermal conductivity enhancement in suppressing the DC erosion of silicone rubber composites under the test conditions of this study. A statistical boxplot analysis technique is introduced to elucidate the inception of the stable dry-band arc in terms of the change in leakage current randomness during the +DC inclined plane tracking and erosion test. The boxplots reveal a slow inception of the stable dry-band arc with the fumed silica filled composite delaying the erosion of silicone rubber during the test. This finding confirms the influence of the filler interface over composite thermal conductivity in suppressing erosion of silicone rubber under DC dry-band arcing.

Graphene, the newest member of the carbon’s family, has proven its efficiency in improving polymers’ resistance against photodegradation, even at low loadings equal to 1 wt% or lower. This protective role involves a multitude of complementary mechanisms associated with graphene’s unique geometry and chemistry. In this review, these mechanisms, taking place during both the initiation and propagation steps of photodegradation, are discussed concerning graphene and graphene derivatives, i.e., graphene oxide (GO) and reduced graphene oxide (rGO). In particular, graphene displays important UV absorption, free radical scavenging, and quenching capabilities thanks to the abundant π-bonds and sp2 carbon sites in its hexagonal lattice structure. The free radical scavenging effect is also partially linked with functional hydroxyl groups on the surface. However, the sp2 sites remain the predominant player, which makes graphene’s antioxidant effect potentially stronger than rGO and GO. Besides, UV screening and oxygen barriers are active protective mechanisms attributed to graphene’s high surface area and 2D geometry. Moreover, the way that graphene, as a nucleating agent, can improve the photostability of polymers, have been explored as well. These include the potential effect of graphene on increasing polymer’s glass transition temperature and crystallinity.

This paper discusses the charge transport and accumulation in clay-containing LDPE (low density polyethylene) nanocomposites. LDPE is shown to host charges of both polarities in the form of homo and heterocharge when subjected to high electric fields. The addition of nanoclays has been shown to always increase the high field DC conductivity of the nanocomposites. This is shown to actually work in favor of the ability of the material to prevent the accumulation of space charge by slowly, but persistently, allowing space charges to flow across the insulation wall. However, in severe conditions of a combined high electric field and high temperature, the current flow exceeds a threshold where massive injected charges negatively impact the charge profile and the electric field distribution is greatly distorted.