Donna M. Pierce’s research while affiliated with Mississippi State University and other places

We examine the spatial distribution of C2, C3, and NH radicals in the coma of comet Encke in order to understand their abundances and distributions in the coma. The observations were obtained from 2003 October 22-24, using the 2.7 m telescope at McDonald Observatory. Building on our original study of CN and OH, we have used our modified version of the vectorial model, which treats the coma as one large cone, in order to reproduce Encke's highly aspherical and asymmetric coma. Our results suggest that NH can be explained by the photodissociation of NH2, assuming that NH2 is produced rapidly from NH3 in the innermost coma. Our modeling of C2 and C3 suggests a multi-generational photodissociation process may be required for their production. Using the results of our previous study, we also obtain abundance ratios with respect to OH and CN. Overall, we find that Encke exhibits typical carbon-chain abundances, and the results are consistent with other studies of comet Encke.

We have observed comet 103P/Hartley 2 using the George and Cynthia Mitchell Spectrograph (formerly VIRUS-P) on the 2.7 m telescope at McDonald Observatory (Hill et al. 2008). Data for CN, C2, C3, and NH2 were collected over six nights from 2010 July 15 to November 10. The data were processed to form images of the coma for each of the observed species. We have performed azimuthal average division on each of the coma images to examine jet morphology and have investigated the nature of the production of the radical species using our modified vectorial model (Ihalawela et al. 2011). This work enhances the ongoing investigation of the chemistry and outgassing behavior of Hartley 2 as studied by the EPOXI flyby mission.

Multiple potential parent species have been proposed to explain CN abundances in comet comae, but the parent has not been definitively identified for all comets. This study examines the spatial distribution of CN radicals in the coma of comet Encke and determines the likelihood that CN is a photodissociative daughter of HCN in the coma. Comet Encke is the shortest orbital period (3.3 years) comet known and also has a low dust-to-gas ratio based on optical observations. Observations of CN were obtained from 2003 October 22 to 24, using the 2.7 m telescope at McDonald Observatory. To determine the parent of CN, the classical vectorial model was modified by using a cone shape in order to reproduce Encke's highly aspherical and asymmetric coma. To test the robustness of the modified model, the spatial distribution of OH was also modeled. This also allowed us to obtain CN/OH ratios in the coma. Overall, we find the CN/OH ratio to be 0.009 ± 0.004. The results are consistent with HCN being the photodissociative parent of CN, but we cannot completely rule out other possible parents such as CH3CN and HC3N. We also found that the fan-like feature spans ~90°, consistent with the results of Woodney et al..

When a circular electric dipole moment, rotating in the x – y plane, is embedded in a material with relative permittivity ε r and relative permeability μ r , the field lines of energy flow of the emitted radiation are dramatically influenced by the surrounding material. For emission in free space, the field lines swirl around the z axis and lie on a cone. The direction of rotation of the field lines around the z axis is the same as the direction of rotation of the dipole moment. We found that when the real part of ε r is negative, the rotation of the field lines changes direction, and hence the energy counter-rotates the dipole moment. When there is damping in the material, due to an imaginary part of ε r , the cone turns into a funnel, and the density of the field lines diminishes near the location of the source. In addition, all radiation is emitted along the z axis and the x – y plane, whereas for emission in free space, the radiation is emitted in all directions. It is also shown that the displacement of the dipole image in the far field depends on the material parameters and that the shift can be much larger than the shift of the image in free space.

The field lines of energy flow of the radiation emitted by a linear dipole in free space are straight lines, running radially outward from the source. When the dipole is embedded in a medium, the field lines are curves when the imaginary part of the relative permittivity is finite. It is shown that due to the damping in the material all radiation is emitted in directions perpendicular to the dipole axis, whereas for a dipole in free space the radiation is emitted in all directions except along the dipole axis. It is also shown that some field lines in the near field form semiloops. Energy flowing along these semiloops is absorbed by the material and does not contribute to the radiative power in the far field.

Understanding the sources of CO in cometary comae is important for understanding comet chemistry and the roles comets have played in the development of the solar system. Among comets sampled to date, the CO abundances vary widely and no direct correlation of CO abundance with other known comet properties has been identified. The picture is complicated further by the discovery of CO production in the comae of some comets, most notably comets Halley and Hale-Bopp. In this study, we investigate the conditions under which CO can be produced in the coma via gas-phase phenomena. We include photochemistry of several parent molecules, as well as two-body chemical reactions that involve the parents and their photodissociative daughter and granddaughter products. We also consider the level of excitation of "hot" hydrogen (H*) and O(1D) in the network, because the level of excitation of these reactants strongly influences reaction rates. Our results suggest that the dominant gas-phase contributor to CO formation is the photodissociation of H2CO. Even though typical abundances of H2CO are at ~1% relative to water in the coma, it produces more CO than other processes due to its relatively short photodissociation lifetime. Because other studies have shown H2CO to have a distributed source as well, it suggests that at least some CO formation in the coma is connected to the H2CO distributed source. We take the time to examine the CO2/CO ratio and note that while the CO2/CO ratio in comets Halley, Hale-Bopp, and Hyakutake are noticeably different when only native CO is considered, the CO2/CO ratios show greater similarity when total CO is considered. Although this sample is relatively small, should the relatively similar CO2/COTotal ratio of ~0.25 indeed be constant for comets with distributed CO sources, it suggests that the extended CO source of these comets is tied directly to the overall C, H, O chemistry of comets, as is likely to happen if hydrogenation of CO occurred on icy grains.