April 2025
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5 Reads
Soft Matter
Water repellency is often defined as the territory of contact angles θ larger than 150° and there is some paradox between the huge number of papers devoted to this effect...
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April 2025
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5 Reads
Soft Matter
Water repellency is often defined as the territory of contact angles θ larger than 150° and there is some paradox between the huge number of papers devoted to this effect...
May 2024
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47 Reads
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2 Citations
Physical Review Fluids
Here we discuss how the use of textured liquid-infused solids can expedite the dynamics of spreading of viscous drops, when the subjacent oil layer is less viscous. We characterize the nature and amplitude of the effect, and the laws governing the spreading at short time. More generally, our findings affirm the universality of the early dynamics of viscous contact, found to hold for drops that coalesce, spread, or even, like here, slip on their substrate.
April 2024
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146 Reads
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11 Citations
Proceedings of the National Academy of Sciences
Superhydrophobic surfaces are often seen as frictionless materials, on which water is highly mobile. Understanding the nature of friction for such water-repellent systems is central to further minimize resistance to motion and energy loss in applications. For slowly moving drops, contact-line friction has been generally considered dominant on slippery superhydrophobic surfaces. Here, we show that this general rule applies only at very low speed. Using a micropipette force sensor in an oscillating mode, we measure the friction of water drops approaching or even equaling zero contact-line friction. We evidence that dissipation then mainly stems from the viscous shearing of the air film (plastron) trapped under the liquid. Because this force is velocity dependent, it can become a serious drag on surfaces that look highly slippery from quasi-static tests. The plastron thickness is found to be the key parameter that enables the control of this special friction, which is useful information for designing the next generation of ultraslippery water-repellent coatings.
December 2023
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124 Reads
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1 Citation
Annual Review of Condensed Matter Physics
At the scale of drops, water either sticks to inclined solids or moves, yet slowly—without the mobility we expect of a liquid of low viscosity. We first recall that the contact line that bounds a drop is responsible for these special adhesion and enhanced friction properties. Then, we discuss how inducing nonwetting states (pearls and marbles) minimizes the role of this line, restores mobility, and even boosts the liquid when it is viscous. Expected final online publication date for the Annual Review of Condensed Matter Physics, Volume 15 is March 2024. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.
November 2023
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128 Reads
November 2023
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60 Reads
Soft Matter
Pure water is known to bounce on super-hydrophobic materials, and we discuss here whether this remains true if the surface tension of water is lowered by either alcohol or surfactants....
October 2023
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47 Reads
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1 Citation
Non-wetting solids have been extensively studied for about 20 years due to the spectacular mobility they provide to water drops. However, they have other noteworthy properties: For instance, such materials immersed in water entrain a plastron of air, a phenomenon exploited by many creatures to hunt or breathe underwater. We measure the thickness of this plastron and model the results by modifying the Landau–Levich–Derjaguin theory established for a plate drawn out of a wetting liquid.
May 2023
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91 Reads
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5 Citations
The spectacular nature of non-wetting drops mainly arises from their extreme mobility, and quick-silver, for instance, was named after this property. There are two ways to make water non-wetting, and they both rely on texture: either we can roughen a hydrophobic solid, which makes drops looking like pearls, or we can texture the liquid with a hydrophobic powder that “isolates” the resulting marble from its substrate. We observe, here, races between pearls and marbles, and report two effects: (1) the static adhesion of the two objects is different in nature, which we interpret as a consequence of the way they meet their substrates; (2) when they move, pearls are generally quicker than marbles, which might arise from the dissimilarity of the liquid/air interface between these two kinds of globules.
May 2023
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30 Reads
The spectacular nature of non-wetting drops mainly arises from their extreme mobility, and quick-silver, for instance, was named after this property. There are two ways to make water non-wetting, and they both rely on texture: either we can roughen a hydrophobic solid, which makes drops looking like pearls, or we can texture the liquid with a hydrophobic powder that "isolates" the resulting marble from its substrate. We observe, here, races between pearls and marbles, and report two effects: (1) the static adhesion of the two objects is different in nature, which we interpret as a consequence of the way they meet their substrates; (2) when they move, pearls are generally quicker than marbles, which might arise from the dissimilarity of the liquid/air interface between these two kinds of globules. Published under an exclusive license by AIP Publishing. https://doi.
December 2022
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36 Reads
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1 Citation
Physical Review Fluids
... The pH range in the nasal mucus is associated 60 with a distinct hydrophilic behavior, which justifies the assumption of the airway walls to be perfectly absorbing via surface tension forces. The absorbed droplets will spread on impact [61][62][63][64] , and mechanistically, the virions embedded in the droplets could be conjectured to disperse over and percolate through the top gel-like layer of mucus. ...
May 2024
Physical Review Fluids
... In most previous work where MFS has been used to probe forces in soft and/or living mesoscale systems (e.g., Refs. (32)(33)(34)(44)(45)(46)), the measurements were deemed quasi-static and the cantilever drag and inertia was neglected. In such case, the force was determined as = , where is the elastic spring constant of the cantilever. ...
April 2024
Proceedings of the National Academy of Sciences
... They measured the thickness of these plastrons and applied a model of the process of withdrawing plates from a liquid by modifying the Landau-Levich-Derjaguin theory. 11 Additionally, Erbil and McHale have synthesized the research on droplet evaporation on superhydrophobic surfaces to date, focusing on the theory of droplet evaporation on smooth and patterned superhydrophobic surfaces and the practical applications by exploiting the dynamics of droplet evaporation. 12 Hoque et al. have discussed important recent advancements and challenges to the development of durable superhydrophobic surfaces, including scalable fabrication, efficacy with low surface tension fluids, and the absence of standardized durability testing methods. ...
October 2023
... The We influence on the impact force also warrants further exploration, especially in the regime We 1 for arbitrary Oh (Chevy et al. 2012;Moláček & Bush 2012) and drop impact on compliant surfaces (Alventosa et al. 2023;Ma & Huang 2023). Another potential extension of this work is to non-Newtonian fluids (Martouzet et al. 2021;Agüero et al. 2022;Bertin 2024;Jin et al. 2023). ...
May 2023
... This alters the bubble temperature and surface tension, which can enhance or weaken bubble drainage. 7,71 Specifically, when Ta > Tw, the cap film temperature increases, which leads to a downward flow u Dr that thickens the film [ Fig. 5(a)]. When T a < T w , the cap film cools, which leads to an upward flow u Dr that thins the film [ Fig. 5(b)]. ...
September 2022
Soft Matter
... Although drops begin to move at low tilt angles on LIS, they still experience significantly more friction during motion than on superhydrophobic surfaces (by around 1-2 orders of magnitude) [18][19][20][21][22] . On LIS, friction arises due to the complex interplay between capillary forces and viscous forces acting inside the drop and in the lubricant meniscus (called wetting ridge) surrounding the drop [23][24][25][26][27][28] . Previous works have suggested that most energy is dissipated in the wetting ridge and possibly in the lubricant film underneath the drop, rather than in the drop itself when the lubricant is more viscous than the drop [23][24][25]29,30 . ...
August 2022
Physical Review Fluids
... Typically, the liquid-vapor interface at the bottom of the droplet ehibits higher temperatures compared to the liquid-air interface at the apex, potentially triggering thermobuoyant currents and Marangoni flows within the Leidenfrost droplet. These dynamics can lead to heightened horizontal and vertical rotation (Chakraborty et al., 2022;Yim et al., 2022), as shown in Figs. 3(a) and (b). ...
July 2022
... While the grinding temperature exceeded than saturation point of biodegradable fluid, the mist droplets boiled, evaporated, and formed a significant number of bubbles. Further, these bubbles accumulate heat and move aside from the primary grinding region due to leidenfrost effect [37]. However, the impression of this emulsion was visible on the micro-glass slide. ...
January 2022
Nature
... 6 In addition, Leidenfrost droplets are able to self-propel on a flat substrate with a thermal gradient, which was originally demonstrated theoretically by Sobac et al., 26 and was further confirmed experimentally. 27,28 The propulsion of Leidenfrost droplets on hot liquid surfaces exhibits distinct motion modes compared with that on solid surfaces. Janssens et al. 29 reported the self-propulsion of acetone drops on heated water surfaces in straight line trajectories at constant speed of about 18 cm/s, and such motion was attributed to the solutocapillary Marangoni flow. ...
June 2021
Soft Matter
... For large puddle-like droplets, the vapour pocket grows until it eventually pops up as a central 'chimney' due to a Rayleigh-Taylor mechanism (Biance et al. 2003;Snoeijer et al. 2009). Instability of large droplets can also occur (either spontaneously or forced) in the form of 'star-faceted' shapes when azimuthal surface oscillations develop along the periphery of the droplets (Brunet & Snoeijer 2011;Ma et al. 2017;Ma & Burton 2018;Bergen et al. 2019;Bouillant et al. 2021a). Selfinduced spontaneous oscillations can also occur in the vertical plane, yielding the recently reported bobing, bouncing or trampolining dynamics when Leidenfrost droplets reach moderate and small sizes with R c (Liu & Tran 2020;Graeber et al. 2021). ...
Reference:
Small Leidenfrost droplet dynamics
June 2021
Proceedings of the National Academy of Sciences