DaeGwi Kim's research while affiliated with Osaka City University and other places

Publications (73)

Article
We investigate effects of several-hundred-micron thick luminescence down-shifting (LDS) films composed of sol-gel glass with Zn-based nanoparticles (NPs) dispersed on characteristics of Si solar cells. Their internal quantum efficiencies (IQEs) are successfully measured by separating contributions of downshifted photons in measuring reflectance for...
Article
Although the photoluminescence (PL) of oil-soluble CuInS 2 (CIS) quantum dots (QDs) has been widely investigated, the origin of PL in water-soluble CIS QDs is less well understood. Elucidation of the PL origin of water-soluble CIS QDs is an important issue in applications such as bioimaging and optical materials. Herein, we prepared CIS and CIS/ZnS...
Article
The formation of minibands in quantum dot (QD) superlattices (SLs) dramatically increases the mobility of carriers, giving a new way to apply QDs for optoelectronic devices. In previous studies on QDSLs, only a few studies have investigated the temperature dependence of the photoluminescence (PL) properties of QDSLs focusing on the formation of min...
Article
Full-text available
Optical properties of semiconductor quantum dots (QDs) can be tuned by doping with transition metal ions. In this study, water-soluble CdSe/ZnS:Mn/ZnS QDs with the core/shell/shell structure were synthesized through a hydrothermal method, in which the surface of the CdSe core was coated with a ZnS:Mn shell and ZnS capping shell. Herein, the CdSe co...
Article
Full-text available
This study was performed to investigate the origin of the photoluminescence (PL) properties of hydrothermally-synthesized water-soluble CuInS2 (CIS) quantum dots (QDs). The corresponding PL decay profiles, time-resolved PL spectra, and excitation intensity dependence of the PL spectra were evaluated. The decay profiles exhibited a strong dependence...
Article
Full-text available
In quantum dot superlattices, wherein quantum dots are periodically arranged, electronic states between adjacent quantum dots are coupled by quantum resonance, which arises from the short-range electronic coupling of wave functions, and thus the formation of minibands is expected. Quantum dot superlattices have the potential to be key materials for...
Article
Semiconductor nanoparticles (NPs) are attractive for use as the constituent blocks of artificial solids. Furthermore, the layer-by-layer (LbL) method allows one to accurately arrange and stack NPs and is being explored widely for the fundamental research and development of artificial solids and devices based on NPs. In this study, we determined the...
Article
Full-text available
This study aims to report the hydrothermal synthesis of water-soluble Mn-doped ZnSe-ZnS alloy quantum dots (QDs), wherein manganese (Mn2+) serves as an emission center. The alloy composition was controlled by the mixing ratio of ZnSe:Mn and ZnS:Mn precursor solutions. The photoluminescence (PL) band originating from the d-d transition in Mn2+ was c...
Article
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We prepared colloidal ZnSe x S 1− x alloy quantum dots (QDs) and investigated their optical properties. ZnSe x S 1− x QDs were successfully prepared by a hydrothermal method, which was confirmed by the results of X-ray structural analysis. When the alloy composition was decreased from x = 1 to 0, the absorption energy continuously shifted to the hi...
Article
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We investigated the size dependence of band-edge photoluminescence (PL) dynamics for CdS quantum dots (QDs). The temperature dependence of the PL-decay profiles of CdS QDs with an average diameter of 3.7–6.0 nm was measured. The PL-decay profiles became longer as the temperature increased. Further, it was found that the temperature dependence of th...
Article
Full-text available
We have investigated the optical properties of ZnSe quantum dots (QDs) prepared by a hydrothermal method. The photoluminescence (PL)-decay profiles become slower with an increase in temperature up to 160 K, contrary to an ordinary behaviour due to thermal quenching. The temperature dependence of the PL-decay profile is explained by a three-state mo...
Article
Full-text available
Herein, we investigated the preparation and optical properties of water-soluble CdSe quantum dots (QDs). CdSe QDs with a narrow size distribution were hydrothermally prepared by reacting Cd ²⁺ with NaHSe in the presence of N -acetyl-L-cysteine as ligand. Furthermore, photoluminescence quantum yield increased to ∼47% when a ZnS shell was applied to...
Article
Full-text available
Water-soluble Mn2+-doped ZnSe quantum dots (QDs) were synthesized using a hydrothermal method. The characteristics of the precursor solutions greatly affected the photoluminescence (PL) properties of the ZnSe:Mn QDs. In QDs synthesized with alkaline precursor solutions, a PL band originating from the intra-3d shell transition of Mn2+ is clearly obs...
Article
Quantum dot superlattices (QDSLs), which are one-, two-, and three-dimensional periodic superlattices composed of QDs, induce dimensionality dependent quantum resonance among component QDs and thus represent a new type of condensed matter exhibiting novel energy, exciton and carrier dynamics. We focused on the two important parameters, the dimensio...
Article
We first report the successful quick synthesis of watersoluble ZnTe nanoparticles (NPs) by a hydrothermal technique. The use of N-acetyl-L-cysteine as a ligand and adjustment of the precursor solution pH to 10.3 ± 0.2 are believed to play key roles in the quick synthesis of ZnTe NPs with a high photoluminescence quantum efficiency of 15%. The react...
Article
Quantum dot (QD) superlattices have the potential to provide new optical properties and functions based on interactions between adjacent QDs. Two types of interactions occur between the QDs: energy transfer (ET) from small-sized QDs to large QDs and resonant coupling between QDs with equal eigenenergies. Since ET and resonant coupling strongly depe...
Article
Possibility of precisely manipulating interior nano space, which can be adjusted by ligand attaching down to subnanometer regime, in hyper-structured quantum dot superlattice (QDSL) induces a new kind of collective resonant couplings among QDs and opens new opportunities for developing advanced optoelectric and photovoltaic devices. Here, we report...
Article
We have systematically investigated the temperature dependence of absorption, photoluminescence (PL), and PL decay profiles in CdTe-core and CdTe/CdS type-II quantum dots (QDs). In CdTe/CdS QDs, Stokes shifts and PL decay time become larger with an increase in temperature above 120 K, while those in CdTe-core QDs are almost independent of temperatu...
Article
CdTe and CdTe/CdS quantum dots (QDs) were synthesized via hydrothermal method in one-step processes just by controlling reaction time. A gradual thermal decomposition of thiol ligand N-acetyl-l-cysteine results in formation of a CdS shell on a CdTe core. The experimental results of X-ray diffraction and energy dispersive X-ray spectroscopy indicate...
Article
Quantum dot (QD) superlattices, periodically ordered array structures of QDs, are expected to provide novel photo-optical functions due to their resonant couplings between adjacent QDs. Here, we computationally demonstrated that electronic structures and phonon dynamics of a QD superlattice can be effectively and selectively controlled by manipulat...
Article
Semiconductor ZnSe quantum dots (QDs) were hydrothermally prepared by the reaction of Zn2+ and NaHSe in the presence of N-acetyl-L-cysteine as a stabilizer. The absorption bandwidth depends strongly on the pH of the working solutions. The PL properties were dramatically improved by selecting appropriately pH value of precursor solution, the PL inte...
Article
We have investigated cavity-polariton condensation effects on the dispersion relation of the lower polariton branch (LPB) at 77K in a CuBr microcavity by angle-resolved photoluminescence (PL) spectroscopy. The intrinsic cavitypolariton dispersion relations were characterized by the analysis of the incident light angle (in-plane wave vector k∥) depe...
Article
We propose a new preparation method of layered structures consisting of lipid-soluble CdSe quantum dots (QDs) and water-soluble Au nanoparticles (NPs). The self-assembled monolayer of (3-mercaptopropyl) trimethoxysilane (MPTMS) was introduced as a “binder” of lipid-soluble QDs on polyelectrolyte layer (PE). Furthermore, the separation distance betw...
Article
We have investigated the exciton-polariton condensation in a CuBr microcavity with HfO2/SiO2 distributed Bragg reflectors, focusing on condensation effects on polariton dispersion relations. The polariton distribution as a function of in-plane wave vector k// under illumination was measured with angle-resolved photoluminescence (PL) spectroscopy. I...
Article
The title nanoparticles are hydrothermally prepared from aqueous mixtures of N-acetyl-L-cysteine, CuCl2, InCl3, and Na2S (autoclave, 180 °C, 5—20 min).
Article
Full-text available
When an exciton in semiconductor is scattered and its energy is decreased far below the resonance energy of the bare exciton state, it has been considered that an exciton-polariton is created immediately by the scattering process because there is no exciton level at that energy. However, according to the recent time-resolved measurements of P emiss...
Article
Semiconductor quantum dot (QD) superlattices, which are periodically ordered three dimensional (3D) array structures of QDs, are expected to exhibit novel photo-optical properties arising from the resonant interactions between adjacent QDs. Since the resonant interactions such as long-range dipole-dipole Coulomb coupling and short-range quantum res...
Article
Full-text available
We have investigated surface-modification effects on photoluminescence (PL) properties of the self-assemble monolayer of CdSe quantum dots from the viewpoint of the temperature dependence of PL properties. The band-edge PL band is strongly activated by the surface modification and is observed as the main PL band, contrary to the fact that the defec...
Article
Full-text available
We have investigated the photoluminescence (PL) properties in a CuBr microcavity with HfO2/SiO2 distributed Bragg reflectors at 10 K from the viewpoint of cavity-polariton condensation. From the excitation-power dependence of PL spectra detected at an in-plane wave vector of k||=0, we found that the PL characteristics of the lower polariton branch...
Article
Highly photoluminescent gel was prepared by embedding water soluble quantum dots (QDs) in an inorganic-organic hybrid gel matrix using a conventional sol-gel process. Aminopropyltrimethoxysilane and citric acid (CA) were found to be the best combination for the gel preparation. 13C-NMR and FT-IR studies indicated hydrogen bond formation between the...
Article
CuInS2 (CIS) nanoparticles (NPs) were hydrothermally prepared by the reaction of Cu2+, In2+, and Na2S in the presence of N-acetyl-L-cysteine as a stabilizer. The X-ray diffraction pattern of the resultant CIS NPs indicated that the chalcopyrite NPs could be obtained. The X-ray photoelectron spectroscopy data suggested that Cu2+ is reduced to Cu+ du...
Article
Full-text available
We have performed time-resolved photoluminescence (PL) spectroscopy for ZnO thin films with thicknesses of 90, 460, and 2800 nm under intense excitation condition. We clearly observed the P emission due to inelastic exciton-exciton scattering. It was found that, in the 460- and 2800-nm thick samples, the decay time of the P emission considerably de...
Article
We have investigated the photoluminescence (PL) properties of a CuBr microcavity at 10 K, including the temporal profiles, from the viewpoint of cavity-polariton condensation. The excitation energy density dependence of the PL intensity (band width) of the lower polariton branch at an in-plane wave vector of k// = 0 exhibits a threshold-like increa...
Article
We report that polarization modulation reflectance (PMR) spectroscopy is highly sensitive to the cavity polaritons in a ZnO microcavity with HfO2/SiO2 distributed Bragg reflectors. We demonstrate that the cavity-polariton dispersion, even in the energy region of strong absorption by exciton continuum states, is clearly observed by PMR spectroscopy....
Article
We have investigated the temperature dependence of photoluminescence (PL) dynamics of self-assembled monolayers (SAMs) of CdSe quantum dots (QDs). The PL decay profiles become slower with an increase in temperature up to 160 K, contrary to an ordinary behavior due to thermal quenching. Such anomalous temperature dependence of the PL-decay profile i...
Article
Photoluminescence (PL) enhancement and quenching using localized surface plasmons in metal nanoparticles (NPs) are important factors to control optical properties of semiconductor quantum dots (QDs). However, the PL enhancement and quenching have not been simultaneously observed in previous works, which lead to the situation that the mechanisms for...
Article
Full-text available
We have investigated the photoluminescence (PL) dynamics of ZnO thin films under intense excitation conditions using an optical-Kerr-gating method. The PL bands originating from exciton-exciton scattering (P emission) and biexciton (M emission) have been observed at 10 K. The ultrashort gating time of 0.6 ps has enabled us to obtain precise informa...
Article
We have investigated the photon-field-shape effects on Rabi splitting energies in CuCl microcavities with HfO2/SiO2 distributed Bragg reflectors (DBRs). The CuCl active layer was prepared by vacuum deposition, while HfO2 and SiO2 layers were prepared by rf magnetron sputtering. The photon-field shape was tuned to a node-type or an antinode-type by...
Article
We have investigated the active-layer-thickness dependence of exciton-photon interactions in CuI microcavities. The active layer thickness was changed from λ/2 to 2λ, where λ corresponds to an effective resonant wavelength of the lowest-lying exciton. In the CuI active layer, thermal strain removes the degeneracy of the heavy-hole (HH) and light-ho...
Article
Water soluble nanoparticles (NPs) with a high emission property were synthesized via hydrothermal routes. In this report, we chose thiol ligand N-acetyl-l-cysteine as the ideal stabilizer and have successfully employed it to synthesize readily size-controllable CdTe NPs in a reaction of only one step. Hydrothermal synthesis of CdTe NPs has been car...
Article
The temperature dependence of absorption, photoluminescence (PL), and PL dynamics of self-assembled monolayers of CdSe quantum dots was investigated. The PL decay profiles become slower with an increase in temperature, contrary to an ordinary behaviour. We have revealed that such anomalous temperature dependence of the PL-decay profile below 200 K...
Article
We have investigated the temperature dependence of the cavity-polariton energies in ZnO and CuCl microcavities with HfO2/SiO2 distributed Bragg reflectors. From angle-resolved reflectance spectra at 10 K, we experimentally confirmed the cavity-polariton dispersions. The experimental dispersions were analyzed with a phenomenological Hamiltonian for...
Article
We have investigated the active-layer-thickness dependence of Rabi splitting energies in ZnO microcavities. We fabricated ZnO microcavities using rf magnetron sputtering for the HfO2/SiO2 distributed Bragg reflector and pulsed-laser deposition for the ZnO active layer. In order to control of the Rabi splitting energies, the active layer thickness w...
Article
We have investigated the characteristics of exciton polaritons in ZnO microcavities with different active layer thicknesses. The microcavity was made from a bulk ZnO active layer and two distributed Bragg reflectors (DBRs) consisting of HfO2 and SiO2 layers. We adopted rf magnetron sputtering and pulsed laser deposition for the preparation of the D...
Article
We have investigated the characteristics of exciton polaritons in a ZnO microcavity with HfO2/SiO2 distributed Bragg reflectors. The results of the angle-resolved reflectance spectra were analyzed by calculating the cavity polariton dispersions with a phenomenological Hamiltonian for the coupling between the cavity photon and three kinds of exciton...
Article
We have investigated the characteristics of exciton polaritons in a CuCl microcavity with distributed Bragg reflectors (DBRs). Two sets of multilayers, PbBr2/PbF2 and HfO2/SiO2, were adopted as the DBRs in order to study the temporal stability of the CuCl microcavity. The thickness of the CuCl active layer was fixed to an effective 3lambda/2 length...
Chapter
We have investigated ultrafast photoluminescence dynamics of electron-hole plasma coupled to longitudinal optical phonons in a ZnO thin film. The dynamical change of the electron-hole-pair density is characterized by time-resolved photoluminescence spectra measured with an optical-Kerr-gating method.
Article
We have investigated the temperature dependence of an energy transfer (ET) between CdSe/ZnS quantum dots (QDs) measuring photoluminescence dynamics in a bilayer structure consisting of differently sized QDs. In the bilayer structure, an effective direct ET from donor QDs to acceptor QDs is realized. The temperature dependence of the observed ET rat...
Article
We have investigated the center-of-mass quantization effect on excitons in layered-compound PbI2 ultra-thin films by precisely changing the layer thickness from 7 to 20 monolayers. Crystalline PbI2 thin films that are fully oriented along the c-axis were prepared by a vacuum deposition method. We confirmed that the surface roughness of the prepared...
Article
We demonstrate the realization of cavity polariton states in bulk CuCl microcavities. The CuCl microcavities made from a bulk CuCl layer and distributed Bragg reflectors consisting of PbF2 and PbBr2 layers prepared by vacuum deposition. Angle-resolved reflectance spectra show the strong coupling characteristics of the excitons and photon mode; name...
Article
We have investigated efficient energy transfer (ET) between CdS quantum dots (QDs) measuring photoluminescence dynamics in layer-by-layer (LBL) self-assembled films. The assembly of negatively charged colloidal QDs and positively charged polyelectrolytes results in QD/polymer multilayers. Furthermore, to reveal how the ET rate depends on the distan...
Article
In recent years, energy transfer (ET) using semiconductor quantum dots (QDs) is getting increased attention. However, it has been postulated that ET between QDs is based on the Förster model, which is a well-established model of ET mechanism in organic dye systems, without verification. In this work, we have investigated ET mechanism in colloidal C...
Article
We have investigated exciton-photon coupling phenomena in a bulk CuCl microcavity with distributed Bragg reflectors consisting of PbF2 and PbBr2 layers prepared by vacuum deposition. Reflectance spectra observed at various incident-light angles demonstrate the strong-coupling behavior of the exciton and photon modes; namely, the energies of reflect...
Article
In recent years, energy transfer (ET) using semiconductor quantum dots (QDs) is getting increased attention. However, it has been postulated that ET between QDs is based on the Förster model, which is a well-established model of ET mechanism in organic dye systems, without verification. In this work, we have investigated ET mechanism in colloidal C...
Article
We have investigated the characteristics of the exciton polaritons in a ZnO microcavity. The microcavity consists of an effective one-wavelength thick ZnO active layer and HfO2/SiO2 distributed Bragg reflectors (DBRs) at the bottom and top. We adopted rf magnetron sputtering and pulsed laser deposition for the preparation of the DBR and ZnO layer,...
Article
We investigated the influence of methylviologen (MV2+), which accelerates the photoetching process used for controlling size distribution, on the photoluminescence (PL) properties of colloidal CdS quantum dots (QDs). A combination of the photoetching process and surface modification with a Cd(OH)2 layer enabled us to prepare size- and surface-contr...
Article
We have investigated the time-resolved photoluminescence (PL) spectra of CuI thin films under intense excitation conditions in the time region up to 25ps. In the time-integrated PL spectra, we have clearly observed the PL band originated from the inelastic scattering of excitons, so-called P emission. The time-resolved PL spectra obtained by using...
Article
The authors have found the self-assembled formation of ZnO hexagonal micropyramids after the growth of a sufficiently thick ZnO layer on a (0001) Al <sub>2</sub> O <sub>3</sub> substrate by rf-magnetron sputtering deposition. It was confirmed by scanning electron microscopy that the orientations of the micropyramids are well arranged. The reflectio...
Article
We have prepared SiO2/CuCl layered structures and investigated the structural and optical properties, focusing on the observation of biexciton-resonant hyper-parametric scattering that is a promising process to generate entangled photons. A crystalline CuCl film, which is the active layer, was grown on an Al2O3 substrate by a vacuum deposition meth...
Article
We have investigated photoluminescence (PL) properties of PbS quantum dots (QDs) prepared by a colloidal method. The QDs were dispersed into polyvinyl alcohol films in order to investigate the temperature dependence of optical properties. In the visible region, both absorption and PL peaks are clearly observed. The temperature dependence of the abs...
Article
We have investigated the time-resolved photoluminescence spectra of the P emission due to exciton–exciton scattering in CuI thin films at various temperatures by using an optical-Kerr-gating method with a time resolution of 0.4ps. It is found that the rise time of the P emission hardly changes with temperature. Since the rise time reflects collisio...
Article
We have prepared ZnS-CdS alloy (Zn1-xCdxS) quantum dots (QDs) using chemical synthetic methods and investigated size-selective photoetching effects on the size distribution. The preparation of Zn1-xCdxS QDs with an alloy composition from x=0 to x=1 is successful using either of the following two methods: a reverse-micelle method using AOT/heptane m...
Article
We have investigated photoluminescence properties of CdS and CdMnS quantum dots (QDs) prepared by a reverse-micelle method. Before the surface modification, a broad luminescence band that originates from defects is dominant in CdS QDs. By the modification, the intensity of the band-edge luminescence is remarkably increased. The surface modification...
Article
We have investigated exciton dynamics in surface-modified CdS quantum dots (QDs) prepared by a colloidal method. The size- and surface-controlled CdS QDs have been successfully prepared by using a size-selective photoetching and surface modification technique. The decay profiles exhibit an unusual temperature dependence: increase of the decay time...
Article
We have investigated the photoluminescence properties of ZnO thin films grown by electrochemical deposition. By applying a thermal treatment at 500°C in O2 atmosphere, a free-exciton photoluminescence is observed. Furthermore, under high-density excitation conditions, a photoluminescence band appears on the low-energy side of the free exciton. The...
Article
We investigated the optoelectronic properties of orientation-controlled lead phthalocyanine (PbPc) films on (0001) sapphire and (001) KCl substrates prepared by vacuum deposition. The results obtained from X-ray diffraction measurements indicate that the orientations of the molecular planes in the PbPc films on the sapphire and KCl substrates are p...
Article
We have investigated self-narrowing and photoetching effects on the size distribution of CdS quantum dots (QDs). The QDs with a narrow size distribution are prepared by a reverse-micelle method and their mean radii are controlled by changing the water content in the reverse micelle. The mean radius and size-distribution width estimated from the lin...

Citations

... Compared with the commonly used nonmetallic modification methods, changing the electronic structure of CDs to provide more active sites is easier, for they have more electrons and vacant orbitals. By introducing transition metal modification, the electronic structure and optical properties of CDs can be adjusted, which greatly expands the application of CDs in catalysis, electricity conduction and so on [22][23][24]. Although transition metals with modified CDs show fluorescent stability, such properties of CDs can be adjusted, which greatly expands the application of CDs in catalysis, electricity conduction and so on [22][23][24]. ...
... These studies have been mostly conducted on NCs with long-chain alkyl ligands, which dissolve well in nonpolar solvents. By contrast, a donor-acceptor pair emission mechanism was recently proposed for water-soluble CIS NCs with cysteine ligands [17]. ...
... Our group has demonstrated that the synergistic combination of polyelectrolytes and carbon nanofillers via layer-by-layer (LbL) assembly creates highly ordered nanocomposites with large PF [3,33]. The LbL method has been utilized for developing multifunctional thin films including bio-film inhabitation, flame retardant, gas sensors, and solar cells [18,34]. LbL coatings are mainly based on electrostatic interactions through charge compensation between oppositely charged components, but other interactions including hydrophobic, van der Waals interactions, π-π interactions, and hydrogen bonding are also employed to form ultra-thin films on various types of substrates [35][36][37][38][39]. ...
... Therefore, it has been used in many photonic applications such as sensors, lasers, luminescent devices, light-emitting diodes, solar cells, and photoconductors. [24][25][26][27][28][29][30][31][32][33] A few research works have been carried out to explore the properties of CdS for enhancing the fluorescence properties of rare-earth-doped sol-gel glass. [34][35][36] One of the recent studies in this direction is the effect of CdS on the emission of Eu 3+ ions implanted in a silicophosphate glass fabricated by the sol-gel method, and it was found that CdS can enhance the photoluminescence (PL) of Eu 3+ ions. ...
... ZnSe thin films have been synthesized using a variety of techniques, including molecular beam evaporation [5], RF magnetron sputtering [12], pulsed laser deposition [4], hydrothermal [13] and chemical bath deposition (CBD) [14][15][16]. The chemical bath deposition appears to be the most suitable method for the growth of ZnSe-based thin films due to its considerable advantages, including simplicity, low cost, low processing temperature [17], easy coating of large areas and high quality of the obtained nanostructured thin films [18]. ...
... 100,103,104 Considering J e−h ≈ 0.3 eV as reported for Jdira, et al . 103 , and taking into account that the maximum of the PL peak in Fig. 10(b) can be used as a measure of E opt , 105 it is possible to obtain that η = 0.8. This value is very close to the theoretical value of η = 0.7 calculated by Jdira, et al . ...
... The decay curve on quartz is fitted according to equation (4) with a median time of 7 ns and a σ = 1.3. The faster decay of the larger QDs was discussed in [44] and explained by the different magnitude of the energy splitting between the bright and dark exciton states. The decay is slightly faster on ZnSe and ZnMnSe. ...
... ZnS has always been a promising material for blue and UV light emitting diodes and laser diodes [1][2][3][4]. When ZnS combines with other materials such as ZnSe, it produces a stimulating and potentially effective heterostructures such as ZnS/ZnSe systems [5][6][7][8]. Such systems are used as phototransistors in the UV detection [4]. ...
... 18,20,29,30) The synthesized NPs reveal hydrophobic properties so that organic solvents are used to disperse these semiconductor NPs. 31) We previously synthesized NPs of compound semiconductors such as CdTe, 32) ZnSe, 33,34) and Mn-doped ZnSe (ZnSe:Mn) 35) NPs using the hydrothermal method, and investigated their optical properties. We adopted ZnSe:Mn/ ZnS core/shell configuration 36) for suppressing the nonradiative recombination at the exposed surfaces of ZnSe:Mn NPs and achieving a higher photoluminescence quantume yield (PLQY). 37) Furthermore we prepared ZnSe/ZnS:Mn/ZnS shell-doped (core/shell/shell) NPs in which the shell was doped with Mn instead of directly doping the ZnSe cores. ...
... These colors demonstrate that the IO QDs have weak fluorescence features. The FL features of IO QDs are completely influenced by the synthetic conditions [38,39]. Several synthesis parameters, such as Fe 3 O 4 NPs concentration, the amount of the citric acid, hydrothermal reaction time, hydrothermal temperature, and total volume of precursors were examined to obtain the IO QDs with optimal quality. ...