C. B. Allen’s research while affiliated with Rensselaer Polytechnic Institute and other places

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Publications (7)


Physical properties data compilations relevant to energy storage-II. Molten salts: Data on single and multi-component salt systems
  • Article

April 1979

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511 Reads

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331 Citations

G. J. Janz

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C. B. Allen

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[...]

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R. P. T. Tomkins

The work provides selected data with value judgments for a set of 49 salt systems of interest as candidate materials for thermal energy storage sub-systems and for electrochemical energy storage systems. The physical properties assessed are melting points; phase diagrams; eutectic compositions; density; surface tension; viscosity; electrical conductivity; diffusion for ions; heat of fusion; heat capacity; volume change on fusion; vapor pressure; thermal conductivity (liquid and solid); and cryoscopic constant. The status of corrosion studies in the form of annotated bibliographic summaries, and salient observations on safety and hazards are also reported. A summarizing series of tables are provided as index to the data-gaps status for this set of candidate materials.


Molten Salts: Volume 4, Part 4 Mixed Halide Melts Electrical Conductance, Density, Viscosity, and Surface Tension Data

January 1979

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38 Reads

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51 Citations

Data on the electrical conductance, density, viscosity, and surface tension of mixed halide melts have been systematically collected and evaluated. Results are given for eighty-five binary mixtures over a range of compositions and temperatures.


Physical properties data compilations relevant to energy storage. 1. Molten salts: Eutectic data

February 1978

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258 Reads

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99 Citations

An authoritative compendium of melting points, and compositions of molten salt eutectic mixtures is presented. Data for mixtures melting in the range - 138 C to 2800 C are reported. Titles of the articles in the literature citations and a system index are included for approximately 6000 eutectic entries.


Molten Salts: Volume 4, Part 3, Bromides and Mixtures; Iodides and mixtures--Electrical conductance, density, viscosity, and surface tension data

April 1977

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19 Reads

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65 Citations

Data on the electrical conductance, density, viscosity, and surface tension of bromide mixtures and iodide mixtures have been systematically collected and evaluated. Results are given for eighty‐five binary mixtures over a range of compositions and temperatures. Values of the above properties for twenty‐three single bromide and iodide salts are also given.



EUTECTIC DATA: safety, hazards, corrosion, melting points, compositions, and bibliography

July 1976

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34 Reads

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11 Citations

Chemischer Informationsdienst

The compilation provides an authoritative compendium of properties relative to safety, hazards, corrosion, melting points, and compositions of molten salt eutectic mixtures. The scope of the single salts data in this compilation encompasses the end-components of the eutectic mixtures reported herewith. Each section contains a systems index and bibliography. The bibliographies in Pt. 1 and Pt. 2 total approximately 4000 entries. More than 6000 eutectic entries are included in the two parts.


Molten salts: Volume 4, part 2, chlorides and mixtures, electrical conductance, density, viscosity, and surface tension data

October 1975

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121 Reads

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267 Citations

Data on the electrical conductance, density, viscosity, and surface tension chloride mixtures have been systematically collected and evaluated. results are given in 124 binary mixtures over a range of compositions and temperatures. Values of the above properties for the single salts have been updated in accord with previously advanced recommendations.

Citations (6)


... Properties like melting point are critical for some applications, as the utilization of mixtures of different compositions enables the tuning of those materials properties to become energetically more efficient. The first attempts to organize a general database for molten salts were made by Janz and co-workers in the Molten Salts Data Center at the Rensselaer Polytechnic Institute [17][18][19][20][21][22], having developed into the most complete database on thermophysical properties of molten salts known. Some recent papers also constitute excellent collection for the thermophysical and thermochemical properties of many salts, and corresponding mixtures, especially for energy applications [23][24][25]. ...

Reference:

Molten alkali carbonates as alternative engineering fluids for high temperature applications
Molten Salts: Volume 4, Part 4 Mixed Halide Melts Electrical Conductance, Density, Viscosity, and Surface Tension Data
  • Citing Article
  • January 1979

... Fluorides, including cryolites, are generally preferred over chloride electrolytes. Fluorides have higher charge density and smaller ionic radii than their equivalent chlorides, leading to easier movement of ions in the molten salt (i.e., higher ionic conductivity) and higher energy efficiency of the MSE process [26,27]. ...

Molten Salts: Volume 4, Part 3, Bromides and Mixtures; Iodides and mixtures--Electrical conductance, density, viscosity, and surface tension data
  • Citing Article
  • April 1977

... Solid-and liquid-phase corrosion processes associated with eutectic mixtures containing chlorine compounds were considered in papers [39][40][41][42][43][44][45], while thermodynamic aspects of the influence of metal alkali in straw combustion processes were characterised in studies [46,47]. The authors of [48][49][50][51][52][53][54][55] found that in the NaCl gas phase, the metal oxidation rate increases significantly compared to the pure air gas phase, and the metal oxide phase degrades significantly. ...

EUTECTIC DATA: safety, hazards, corrosion, melting points, compositions, and bibliography
  • Citing Article
  • July 1976

Chemischer Informationsdienst

... From this, it is clear that the choice of a eutectic mixture of NaOH and KOH as the molten salt medium not only allows for a low reaction temperature (eutectic point at 167°C) but also facilitates the reaction mechanism by acting as an active component and oxygen donor. [39][40][41] The crystal structure of as-synthesized BaMnO 3 and BaTi 0.5 Mn 0.5 O 3 are characterized and compared in Figure 1a. The X-ray diffraction (XRD) pattern of BaMnO 3 reveals a high degree of phase purity with peaks well-indexed to the 2H-hexagonal perovskite crystal structure (JCPDS no. ...

Physical properties data compilations relevant to energy storage. 1. Molten salts: Eutectic data
  • Citing Article
  • February 1978