November 2024
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13 Reads
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1 Citation
European Polymer Journal
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November 2024
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13 Reads
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1 Citation
European Polymer Journal
January 2024
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1 Read
January 2024
September 2023
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70 Reads
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5 Citations
Polymer Composites
In 3D printing technology, unwanted resin properties such as low mechanical, thermal, electrical, and biocompatibility can be enhanced by using proper fillers. In this study, sucrose urethane microparticles, acrylic modified are used to improve the properties of the final object without losing other properties such as printing resolution. Modification is confirmed by FTIR spectroscopy and hydrogen bonding index enhancement after modification of the urethane filler. Filler particles are reduced in sizes by modification followed by ball‐milling as is confirmed by scanning electron microscopy. When the filler content is 2.5 wt%, mechanical tensile and flexural modulus increase compared to the neat resin however, increases the brittleness of the photo‐cured samples. Thermal degradation temperature is lifted up for 2.5–5.0 wt% of the filler loading in the resin. Improved dimensional accuracy and detailed printing in higher resolution, due to the physical effect of the filler particles, can also be achieved in real 3D‐printed object as is explored. Highlights High‐resolution 3D printing, by random geometry of filler particles in the resin. Scattering from polyurethane foam microparticles lead to high‐resolution printing. Acrylate‐modified polyurethane filler particles provide resin compatibility. Polyurethane filler leads to higher resolution with enhanced mechanical properties.
August 2023
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108 Reads
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3 Citations
Vat photopolymerization-based three-dimensional (3D) printing techniques have been used as an efficient method for complex and special geometries in various applications. Composites are also a group of polymer materials that are obtained by adding a reinforcing component such as filler, fibres with different origins. Therefore, the development of 3D printable composites is paramount due to their high precision and speed of production. Glass beads (GBs) have been favorites as economical reinforcement agents for their chemical stability, water resistance in acidic environments, dimensional stability, and eco-friendly properties. In this study, 3D printable composites based on coated glass beads (CGBs) have been prepared. First, the beads are coated with ultraviolet (UV) curable resins to improve the interface with the polymer matrix. Then, CGBs are mixed with 3D printing resin and formulated for digital light processing (DLP) printing. The coating process is checked by scanning electron microscopy (SEM), and the mechanical properties of the 3D-printed composite structures have been evaluated by bending and compression tests. Also, the fracture behavior of cured resin has been checked with SEM. Mechanical property investigations have shown the success of the 3D printing of the CGBs into a photopolymer resin (PR) composite with behavior modification and compatibility of the interface with the matrix in practice.
August 2023
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27 Reads
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2 Citations
Polymer Composites
Sustainable composites based on blends from polypropylene (PP) and recycled polyethylene terephthalate (RPET) and wood flour (WF) were prepared under industry‐relevant conditions by melt extrusion, followed by continuous drawing through spinnerets. Maleic anhydride grafted polypropylene (PP‐g‐MA) was employed to improve the compatibility between matrix and WF. The effects of incorporation of WF and RPET microstructure on the morphological features, rheological measurements, and mechanical properties were investigated. The drawing process converted elliptical RPET phase into highly oriented microfibrillar structure, as characterized by means of scanning electron microscopy (SEM). The highly oriented blend (HOB) represented nonterminal behavior due to the presence of physical networks and enhanced surface area of microfibers for chemical interactions. The tensile strength of neat PP increased by the addition of WF and the existence of microfibrillar RPET phase, whereas the microstructure of RPET had more pronounce effect. The tensile strength and elastic modulus of PP reinforced by WF and oriented RPET improved by 65% and 92%, respectively, demonstrating the high potential of this environmental‐friendly reinforcement method to intensify the mechanical properties of PP.
March 2023
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9 Reads
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4 Citations
Materials Today Communications
August 2022
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51 Reads
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7 Citations
BMC Research Notes
Objective As a progressive chronic condition, osteoarthritis (OA) causes substantial pain and impairment. Secrete proinflammatory cytokines are essential mediators involved in the pathophysiology of OA. In this regard, the clinical effectiveness of autologous conditioned serum (ASC) has been shown through its injection into OA tissues. This study aimed to assess the effectiveness and concentration level of ACS components produced by Nano-carbon glass beads. Intravenous whole blood was obtained from each New Zealand male rabbit by 10-ml syringes, comprising 33 medical-grade Nano carbon-coated glass beads. Serum retrieving was performed after 6–8 h incubation (37 C, 5% Co 2 ), and then centrifuged. The ACS was then injected into OA rabbits to assess its function. Results Glass beads-prepared ACS coated with Nano-carbon, induced a huge amount of cytokines and growth factors production. The concentration level of anti-inflammatory cytokines and proinflammatory cytokines was improved throughout Nano-carbon coated glass beads stimulation. ACS also shortened the recovery time and improved the function and mobility of OA rabbits. We showed that ACS improved the function and mobility of OA rabbits, as well as shortened the recovery time. It is suggested that further studies evaluate this effectiveness.
January 2022
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2 Reads
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1 Citation
SSRN Electronic Journal
October 2021
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63 Reads
... This technique enables the production of solid prototypes or end-use objects with high resolution, surface quality, and intricate geometries, using layer heights as fine as 15 to 50 μm. Vat photopolymerization involves curing a photosensitive liquid resin-typically composed of functionalized monomers or oligomers-using a light source in the UV/ Vis range (350 to 430 nm), converting the resin into a solid polymer layer by layer (1)(2)(3) . ...
November 2024
European Polymer Journal
... Summary of synergistic effects of combining multiple fillers. Use of nanoparticles[152,153] • Improvement of mechanical properties[154] • Scattering effects of fillers to alter cure depth[155] ...
September 2023
Polymer Composites
... To provide a resource-efficient solution for fossil-based modifiers and reduce waste generation, targeting the United Nations Sustainable Development Goals (SDGs 8 and 12) [23], there is a need to study the effects of recycled materials as modifiers in composites with low toughness. With the use of recycled polymers or/and waste wood to make WPCs [24][25][26][27][28], and the studies presented in this work, companies can design impact-modified WPCs based on recycled materials, contributing to a more sustainable circular production approach. When considering materials that are currently disposed of in landfills or incinerated but could potentially be used as modifiers for enhancing toughness and impact properties, two types could be selected: recycled textiles (long fibers) and elastomers (soft inclusions). ...
August 2023
Polymer Composites
... Glass bead reinforcement was investigated by Gerbroodbar et al. [9] by mixing glass beads pre-coated with a UV resin into a printing UV resin. There is an in-depth description of the cleaning and preparation required to properly coat the beads to achieve proper adhesion to the matrix during printing. ...
August 2023
... Core-shell SiNPs, conventional non-porous SiNPs, mesoporous SiNPs (MSiNPs), and hollow mesoporous HSiNPs are some variants of SiNPs which are colloidal in nature [7,8]. Amongst them, MSiNPs is a popular alternative because of their physical properties such as large surface area and pore volume, tunable pore diameter, inexpensive, thermally stable, chemically inert, non-toxic, and easy surface modification that confer additional crucial advantages for the delivery of therapeutic agents to a particular site [9][10][11][12]. ...
March 2023
Materials Today Communications
... Regenerative medicine involves use of biologics derived from both autologous and allogenic sources. Autologous sources include orthobiologics derived from peripheral blood called autologous peripheral blood-derived orthobiologics (APBOs) including platelet-rich plasma (PRP) [20], platelet lysate (PL) [21], autologous conditioned serum (ACS) [22], gold-induced cytokines (GOLDIC) [23], plasma rich in growth factors (PRGF) [24], growth factor concentrate (GFC) [25], autologous protein solution (APS) [26], platelet-rich fibrin (PRF) [27], hyperacute serum (HAS) [28], and autologous conditioned plasma (ACP) [29]. Allogenic sources include platelet-rich plasma, bone marrow, adipose tissue, perinatal tissue (amniotic fluid and/or membrane, umbilical cord, Wharton's jelly), etc. [30][31][32][33]. ...
August 2022
BMC Research Notes
... Porosity and pore size are key structural characteristics that control the performance of porous polymer films [1]. These films have been utilized in various applications such as separation [2][3][4][5], sensors [6,7], fuel cell [8], lithium-polymer batteries [9], insulation and coating [10,11], electromagnetic interference (EMI) shielding [12], biological scaffolding [13], fabrication of low-dielectric-constant materials [14], and supports for catalysts [15]. The evaporation induced phase separation EIPS (dry-casting process) is one of the methods to prepare porous polymer films [16][17][18][19]. ...
October 2021
Progress in Organic Coatings
... In addition, it can increase the flux value, resulting in faster filtration duration so that these conditions will be more efficient and effective in the filtration process (Soria et al., 2020). In addition, the PEG compound is a type of additive as a template media formed to create and regulate the structure and size of pores (Foroutani et al., 2021;L. Liu et al., 2021). ...
January 2021
Journal of Membrane Science
... It was judiciously concluded that wounds with a pathologic inflammatory state and a high proteolytic microenvironment are a hostile battlefield for GFs and their receptors. It was also demonstrated that, in addition to being degraded, topical GF administration does not ensure adequate local diffusion to responsive cells in deeper layers [113]. These obstacles have contributed to GFs' pharmaceutical applications fading in the wound healing armamentarium, and they explain why the FDA has not approved another GF-based medication for wound healing in more than 25 years. ...
November 2020
Growth factors (Chur, Switzerland)
... Taken together, all of these results suggest that the electrochemical processes emphasized by the voltammograms are generated by quasi-reversible reactions involving charge-transfer processes of PDANI chains. 65 As is well established in the literature, during an electrochemical event, the structural changes, associated with the electron transfers from and onto the backbone of a CP, are typically accompanied by ion exchanges with the surrounding electrolytic solution for charge balancing. The mechanisms underlying these processes can involve anion or cation exchanges, and for PDANI phase they can be, respectively, described by eqs 2 and 3 11 ...
September 2020
Journal of Polymer Research