October 1986
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25 Reads
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26 Citations
Journal of the Less Common Metals
Polycrystalline molybdenum disulphide has been grown by high pressure (about 54.88 × 106 N m−2) reduction of molybdenum trisulphide and characterized by various physicochemical methods. The chemical analysis of the compound established a sulphur to molybdenum ratio of 2, which was also confirmed by thermogravimetric analysis in air. The X-ray data was found to be consistent with 2H-MoS2, n-type conductivity (S = −275 μV °C−1) and diamagnetic behaviour ( c.g.s. e.m.u.). It is a semiconducting material with a room temperature conductivity of of and an activation energy of 0.124 eV in the temperature range 150–300 K. A band gap of 0.95 ± 0.02 eV was found from optical absorption studies on a thin MoS2 film. Thermal studies of MoS2 in an argon atmosphere has shown its stability up to 1200 °C and thereafter it decomposes to Mo2S3. A model has been proposed which describes the thermal behaviour of MoS2 when heated at various temperatures up to 1200 °C and is based on the appearance of lines in X-ray powder diffractogram of the product resulting from the crystallization of MoS2. Scanning electron microscope studies have also been made.