Alex Deutsch’s research while affiliated with University of Münster and other places

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Publications (22)


The reaction of carbonates in contact with laser‐generated, superheated silicate melts: Constraining impact metamorphism of carbonate‐bearing target rocks
  • Article

July 2018

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150 Reads

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17 Citations

Meteoritics & Planetary Science

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Bernd Lexow

We simulated entrainment of carbonates (calcite, dolomite) in silicate impact melts by 1‐bar laser melting of silicate–carbonate composite targets, using sandstone, basalt, calcite marble, limestone, dolomite marble, and iron meteorite as starting materials. We demonstrate that carbonate assimilation by silicate melts of variable composition is extremely fast (seconds to minutes), resulting in contamination of silicate melts with carbonate‐derived CaO and MgO and release of CO2 at the silicate melt–carbonate interface. We identify several processes, i.e., (1) decomposition of carbonates releases CO2 and produces residual oxides (CaO, MgO); (2) incorporation of residual oxides from proximally dissociating carbonates into silicate melts; (3) rapid back‐reactions between residual CaO and CO2 produce idiomorphic calcite crystallites and porous carbonate quench products; (4) high‐temperature reactions between Ca‐contaminated silicate melts and carbonates yield typical skarn minerals and residual oxide melts; (5) mixing and mingling between Ca‐ or Ca,Mg‐contaminated and Ca‐ or Ca,Mg‐normal silicate melts; (6) precipitation of Ca‐ or Ca,Mg‐rich silicates from contaminated silicate melts upon quenching. Our experiments reproduce many textural and compositional features of typical impact melts originating from silicate–carbonate targets. They reinforce hypotheses that thermal decomposition of carbonates, rapid back‐reactions between decomposition products, and incorporation of residual oxides into silicate impact melts are prevailing processes during impact melting of mixed silicate–carbonate targets. However, by comparing our results with previous studies and thermodynamic considerations on the phase diagrams of calcite and quartz, we envisage that carbonate impact melts are readily produced during adiabatic decompression from high shock pressure, but subsequently decompose due to heat influx from coexisting silicate impact melts or hot breccia components. Under certain circumstances, postshock conditions may favor production and conservation of carbonate impact melts. We conclude that the response of mixed carbonate–silicate targets to impact might involve melting and decomposition of carbonates, the dominant response being governed by a complex variety of factors.



Silicate liquid immiscibility in impact melts

September 2017

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160 Reads

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31 Citations

Meteoritics & Planetary Science

We have investigated silicate emulsions in impact glasses and impact melt rocks from the Wabar (Saudi Arabia), Kamil (Egypt), Barringer (USA), and Tenoumer (Mauritania) impact structures, and in experimentally generated impact glasses and laser-generated glasses (MEMIN research unit) by scanning electron microscopy, electron microprobe analysis, and transmission electron microscopy. Textural evidence of silicate liquid immiscibility includes droplets of one glass disseminated in a chemically distinct glassy matrix; sharp phase boundaries (menisci) between the two glasses; deformation and coalescence of droplets; and occurrence of secondary, nanometer-sized quench droplets in Si-rich glasses. The compositions of the conjugate immiscible liquids (Si-rich and Fe-rich) are consistent with phase separation in two-liquid fields in the general system Fe2SiO4–KAlSi3O8–SiO2–CaO–MgO–TiO2–P2O5. Major-element partition coefficients are well correlated with the degree of polymerization (NBO/T) of the Si-rich melt: Fe, Ca, Mg, and Ti are concentrated in the poorly polymerized, Fe-rich melt, whereas K, Na, and Si prefer the highly polymerized, Si-rich melt. Partitioning of Al is less pronounced and depends on bulk melt composition. Thus, major element partitioning between the conjugate liquids closely follows trends known from tholeiitic basalts, lunar basalts, and experimental analogs. The characteristics of impact melt inhomogeneity produced by melt unmixing in a miscibility gap are then compared to impact melt inhomogeneity caused by incomplete homogenization of different (miscible or immiscible) impact melts that result from shock melting of different target lithologies from the crater's melt zone, which do not fully homogenize and equilibrate due to rapid quenching. By taking previous reports on silicate emulsions in impact glasses into account, it follows that silicate impact melts of variable composition, cooling rate, and crystallization history might readily unmix during cooling, thereby rendering silicate liquid immiscibility a much more common process in the evolution of impact melts than previously recognized.



Correlating laser-generated melts with impact-generated melts: An integrated thermodynamic-petrologic approach: Laser Melting of Planetary Materials

October 2016

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92 Reads

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16 Citations

Planetary collisions in the solar system typically induce melting and vaporization of the impactor and a certain volume of the target. To study the dynamics of quasi-instantaneous melting and subsequent quenching under post-shock P–T conditions of impact melting, we used continuous-wave laser irradiation to melt and vaporize sandstone, iron meteorite, and basalt. Using high-speed imaging, temperature measurements, and petrologic investigations of the irradiation targets, we show that laser-generated melts exhibit typical characteristics of impact melts (particularly ballistic ejecta). We then calculate the entropy gains of the laser-generated melts and compare them with the entropy gains associated with the thermodynamic states produced in hypervelocity impacts at various velocities. In conclusion, our experiments extend currently attainable post-shock temperatures in impact experiments to ranges commensurate with impacts in the velocity range of 4–20 km s–1 and allow to study timescales and magnitudes of petrogenetic processes in impact melts.


Fig. 1 Melting of calcite (a), degassing of calcite (b), and 
Bridging the Gap III (2015)
  • Conference Paper
  • Full-text available

September 2015

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97 Reads

Download


Cosmic Collisions in the Experimental Chamber

May 2015

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139 Reads

German Research

Shedding new light on fundamental evolutionary processes in the solar system: from the beginnings of our planet to the present day, asteroids and comets have shaped the geological development of planetary bodies. The high-speed processes that occur during impact events are now being modelled by a group of researchers in the laboratory.


Impact metamorphism in terrestrial and experimental cratering events

January 2015

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468 Reads

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4 Citations



Citations (16)


... Quartz grains with shock metamorphic features, commonly referred to as "shocked quartz," are a typical diagnostic criterion used for the identification of hypervelocity impact structures on Earth (e.g., Stöffler and Langenhorst 1994;Grieve et al. 1996;French 1998;French and Koeberl 2010;Deutsch et al. 2015;Stöffler et al. 2017;and references therein). In addition to the simple optical properties of quartz and its natural abundance in terrestrial crustal rocks, its shock metamorphic features, forming at a wide pressure range, are well characterized. ...

Reference:

Characterization of shocked quartz grains from Chicxulub peak ring granites and shock pressure estimates
Impact metamorphism in terrestrial and experimental cratering events

... The ∼200 km wide Chicxulub impact structure in México, formed by a hypervelocity impact event ∼66 Myr ago, constitutes a natural laboratory to examine the response of distinct lithological units to extreme shock conditions (1)(2)(3)(4)(5)(6). Constraining the rapid temperature changes that target rocks experience during and after impact cratering events remains extremely challenging due to generally poorly preserved impact lithologies and the complexities of reconstructing high-temperature conditions in a laboratory setting (7,8). Over the last 15 years, carbonate clumped-isotope thermometry has increasingly been used to reconstruct absolute temperatures in the geological record, based on measurements of the abundance of 13 C- 18 O bonds in lattices of carbonate minerals, expressed as Δ 47 (9). ...

The reaction of carbonates in contact with laser‐generated, superheated silicate melts: Constraining impact metamorphism of carbonate‐bearing target rocks
  • Citing Article
  • July 2018

Meteoritics & Planetary Science

... Hypervelocity impacts are extremely complicated geologic processes that have been studied by experiments (e.g., Housen & Holsapple, 2011;Kenkmann et al., 2018) and sophisticated numerical simulations (e.g., Collins et al., 2012). Senft and Stewart (2008) derived the equation-of-state and strength model parameters for H 2 O and modeled impacts into an icy-layer underlain by a rocky target. ...

Experimental impact cratering: A summary of the major results of the MEMIN research unit
  • Citing Article
  • February 2018

Meteoritics & Planetary Science

... This iron, immiscible with the silicate melt, separates as liquid metallic droplets. These droplets, rich in iron, disperse from the silicate melt, and earlyseparated droplets may coalesce into larger ones to minimize surface energy, resulting in np-Fe particles of varying sizes [39,47]. The chemical reaction involved can be expressed as ...

Silicate liquid immiscibility in impact melts
  • Citing Article
  • September 2017

Meteoritics & Planetary Science

... On Earth and other celestial bodies, craters with diameters of several hundred meters up to a few kilometers represent a very common feature. In general they can be formed by meteorite impacts (Osinski and Pierazzo, 2013;Kenkmann et al., 2014Kenkmann et al., , 2017 or by explosive volcanism Geomorphology 367 (2020) 107297 (White and Ross, 2011). However, since crater rims may be more or less eroded and the sedimentary infill of the crater is often not well exposed, the morphological features alone may not be indicative for their origin, which leads often to a certain controversy regarding the possible formation scenarios. ...

Bridging the Gap III: Impact cratering in nature, experiment, and modeling
  • Citing Article
  • July 2017

Meteoritics & Planetary Science

... By fitting our data to Equation 2, our results (the dashed black line with black dots in Figure 4) show a gentler slope (d = 3.09; c = 2.37 × 10 −3 ) than the analytical value. This is partially caused by the decreasing influence of the porosity gradient with increasing projectile size L. To demonstrate the significance of porosity, we conducted iSALE simulations without any target porosity (all other parameters are identical), where the critical shock pressure for melting is assumed to be 60 GPa (Hamann et al., 2016). The results (Figure 4b) show that the relative enhancement of melt abundance gradually increases with decreasing crater size, which corresponds to an increasing influence of the more porous target toward the shallowest strata ( Figure 1). ...

Correlating laser-generated melts with impact-generated melts: An integrated thermodynamic-petrologic approach: Laser Melting of Planetary Materials
  • Citing Article
  • October 2016

... The highly shocked ejecta particles recovered from MEMIN impact experiment A20-5339 (Fig. 1e) were described in detail by Ebert et al. (2014). They are white-to dark-gray composite particles composed of Fig. 1f and Ebert et al. 2015); the images are from LE-I. a, b) Three different silicate emulsion zones between a piece of Campo del Cielo (the projectile piece plucked out during sectioning and polishing) and sandstone target melts. ...

BRIDGING THE GAP BETWEEN LABORATORY AND NATURE: GEOCHEMICAL CLUES FROM EXPERIMENTAL APPROACHES.

... Other instrumentation, such as laser ablation (LA) ICP-MS would yield better detection limits, although NanoSIMS may be the instrument of choice considering their sizes observed in this study. Although most baddeleyite compositional studies in the literature do not include REEs, a few have reported REEs using either EPMA (e.g., Rajesh et al., 2006;Tropper et al., 2007;Huraiová et al., 2011;Zhao et al., 2016) or LA-ICP-MS (e.g., Schärer et al., 2011;Zhang et al., 2017) techniques. In all cases, the REE content is very minor, ≤ 1 wt %-1.5 wt %. ...

The genesis of deep-mantle xenocrystic zircon and baddeleyite megacrysts (Mbuji-Mayi kimberlite): Trace-element patterns
  • Citing Article
  • March 2011

European Journal of Mineralogy

... Despite the indirect evidence raised to date that points towards an exogenous origin for the Colônia structure due to a meteorite impact, there are no scientifically accepted direct evidences of this phenomenon. Based on the analysis of samples from drilling for groundwater wells inside the structure, VELÁZQUEZ et al. (2013VELÁZQUEZ et al. ( , 2018VELÁZQUEZ et al. ( , 2021 presented supposed evidence in this regard that does not stand up to the literature (e.g., REIMOLD et al. 2014, CRÓSTA & REIMOLD 2016, CRÓSTA et al. 2019a). The only "evidence" of shock micro-deformation presented by VELÁZQUEZ et al. (2013) is the supposed occurrence of PDFs in quartz; despite the low quality of the illustration presented for this feature, it is possible to infer that it does not correspond to true PDF and probably results from a typical tectonic deformation event of the local basement rocks and, therefore, from a pressure regime well below the shock regime. ...

Impact controversies: Impact recognition criteria and related issues
  • Citing Article
  • May 2014

Meteoritics & Planetary Science

... Cratering experiments in solid rocks have been conducted for a broad range of target, projectile and velocity conditions by Shoemaker et al. (1963), Gault and Greeley (1978), Polanskey and Ahrens (1990), Love et al. (1993, Housen and Holsapple (2003), Burchell and Whitehorn (2003), and Ai and Ahrens (2004). Recently, a large number of impact experiments into solid rocks have been conducted in the framework of the MEMIN (Multidisciplinary Experimental and Modeling Impact Research Network) program (Kenkmann et al. 2011Kenkmann et al. , 2013 Poelchau et al. 2013). Such experiments are suited to investigate the deformation inventory of the crater subsurface (Maurer and Rinehart 1960; Kenkmann et al. 2011; Onose et al. 2011; Buhl et al. 2013a Buhl et al. , 2013b), and also to search for shatter cones and to constrain the formation conditions (Shoemaker et al. 1961; Moore et al. 1962; Schneider and Wagner 1976; Roddy and Davis 1977; Kenkmann et al. 2012). ...

The MEMIN research unit: Experimental impact cratering
  • Citing Article
  • January 2013

Meteoritics & Planetary Science