Akihisa Takeuchi’s research while affiliated with Japan Synchrotron Radiation Research Institute and other places

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Publications (427)


Assessment of Fatigue Crack Initiation Behaviour in Ti-6Al-4V Alloy Using a Coarsened Surrogate Model
  • Article

May 2025

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11 Reads

MATERIALS TRANSACTIONS

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Shuo Feng

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The microstructure and fatigue crack initiation process of Ti-6Al-4V alloys were measured using a multimodal technique combining synchrotron X-ray microtomography and electron backscatter diffraction (EBSD) serial sectioning techniques. Various microstructural design variables were generated to describe the shape, size and crystallographic information of the polycrystalline microstructure that is the fatigue crack initiation point. The microstructural information was coarsened based on the similarity between the design variables and their correlation with fatigue crack initiation. An objective function describing the resistance to fatigue crack initiation was also established. By combining these variables, the relationship between the microstructural information and fatigue crack initiation resistance was described by a metamodel in the form of a multidimensional response surface using a support vector machine. A limited number of design variables with a high correlation with transgranular and intergranular fatigue cracking were identified, and the optimum or weakest microstructural patterns for fatigue crack initiation were quantitatively represented. This approach is expected to allow much more efficient microstructure control to enhance the fatigue crack initiation resistance than has previously been possible with the conventional surface-based approach.



Analysis of Void Formation and Crack Propagation at Grain Boundaries in Al-Zn-Mg-Cu Alloy

April 2025

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29 Reads

MATERIALS TRANSACTIONS

Hydrogen embrittlement in Al-Zn-Mg-Cu alloys is suggested to originate from debonding of the η phase interface. Previous studies have shown that intragranular T phase precipitation, facilitated by increased Mg content, contributes to the mitigation of quasi-cleavage fracture. However, the role of T phase precipitation on the grain boundary in suppressing intergranular fracture remains unclear. In this study, in-situ observational techniques were used to examine the relationship between grain boundary precipitates and hydrogen-induce intergranular cracking. Obtained results showed that while the T phase precipitates in the matrix of Mg-enhanced alloy, the η phase predominates on grain boundaries, which lead intergranular fracture. The presence of numerous voids at intergranular crack tips suggests that void nucleation along grain boundaries and subsequent coalescence is the primary mechanism of crack propagation. The observed void formation at η phase interfaces is consistent with first-principles calculations and supports the concept that intergranular fracture originates from debonding at η phase interfaces.


In-situ SSRTs results for each specimen: (a) nominal stress-strain curves, (b) a comparison of the SCC performance between the current work and Al-Zn-Mg-Cu alloys treated by other methods proposed in the literatures [17–28], (c) average and total corrosion depth evolutions over pre-exposure time, (d) crack numbers and total crack length during SSRT tests in which the initial length at εa = 0% comes from the depth of corrosion that would transit into cracks.
In-situ observation results of the corrosion behaviors during pre-exposure in LT specimen. 3D perspective views and the corresponding virtual cross-sections of (a–h) pitting corrosion and (i–p) exfoliation corrosion after immersed in 3.5 wt.% NaCl solution for 0, 6, 12, and 17 h, in which the red and blue colors represent the corrosion pits and IMCp, respectively. (q) SEM micrographs and the corresponding EDS mapping of the corrosion products in the surface of (l), and (r) cross-sectional SEM image and EBSD orientation imaging maps of the exfoliation corrosion in (p), with color representing grain orientations as determined by the inserted color legend.
SCC propagation behaviors: (a-c) 3D perspective views illustrating the propagation behavior of the main cracks in LT specimen at an applied strain of 0%, 1.5% and 4.5%, respectively (the red, yellow and blue colors represent the corrosion pits, cracks and IMCp, respectively), (d) SEM fracture morphology corresponding to the main cracks in LT specimen, and (e) virtual cross-sections of ultra-high resolution XNT images showing the crack tip features in (c), with intergranular SCC (IGSCC) and TGSCC indicated by black and white arrows, respectively. The transition from IG to TGSCC might occur when the combined effects of the mechanical driving force and H are no longer adequate to sustain the IGSCC but are sufficient to support the TGSCC since crack propagation tends to follow the paths of least resistance within the H-affected zone. Moreover, the decohesion of IMCp may occur as a result of the H accumulation and clustering-induced stress localization, as highlighted by the blue circles in (e). (f-i) 3D perspective views illustrating the propagation behavior of the main cracks in HTMn specimen at an applied strain of 0%, 1.7%, 3.9% and 7.9%, respectively, (j) virtual cross-sections of ultra-high resolution XNT images showing the crack tip features in (i), and (k) SEM fracture morphology corresponding to the main cracks in HTMn specimen.
Analysis of the nano-sized precipitates: (a, c, e) HAADF-STEM micrographs and the corresponding SAED patterns and (b, d, f) atomic-resolution HAADF-STEM images of LT, HT and HTMn, respectively, and (g, h) representative examples of T phases and variants of the η phases in (f). Analysis of the Al31Mn5Cu3 dispersoids: HAADF-STEM micrographs of Al31Mn5Cu3 in (i) low magnification and (j) high magnification, (k) the corresponding EDS result, and (l) atomic-resolution HAADF-STEM images of Al31Mn5Cu3 and the corresponding inserted FFT pattern. All the STEM images and the corresponding SAED patterns are taken from the zone axes of <110 > Al.
Local H partitioning analysis: Virtual cross-section XMT image of the main crack in the (a) LT, (b) HT and (c) HTMn. Comparison of (d) H concentrations (CH) and (e) occupancies at various critical trap sites for each specimen. Attention was concentrated on the H-affected zone located ahead of the main crack (rectangular regions with a size of 80 × 80 × 20 µm³ marked by dashed lines in Figure 5(a–c)), with each specimen being observed at a comparable strain level. The H concentrations and occupancies at various trap sites were calculated and are shown in Figure S8.
Exceptional stress corrosion cracking resistance-strength synergy of Al-Zn-Mg-Cu alloys via tailored nano-sized particles
  • Article
  • Full-text available

March 2025

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73 Reads

High-strength Al-Zn-Mg-Cu alloys are extensively utilized in the aeronautics sector for lightweighting, but they are notoriously susceptible to stress corrosion cracking (SCC). Herein, a novel strategy was proposed to mitigate SCC in Al-Zn-Mg-Cu alloys by manipulating nano-sized particles. Mn-bearing dispersoids significantly curbed hydrogen (H) production and infiltration into Al matrix, and T precipitates notably reduced H concentration and occupancy at grain boundaries, intermetallic compound particles and interfaces of η precipitates, which were potentially implicated in hydrogen embrittlement (HE). The synergistic effects of Mn-bearing dispersoids and T precipitates yielded an optimal balance of strength and SCC resistance in Al-Zn-Mg-Cu alloys.

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Analysis of void formation and crack propagation at grain boundaries in Al-Zn-Mg-Cu alloyAl-Zn-Mg-Cu合金の粒界におけるボイド形成・亀裂進展解析

February 2025

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27 Reads

Journal of Japan Institute of Light Metals

Hydrogen embrittlement in Al-Zn-Mg-Cu alloys is suggested to originate from debonding of the η phase interface. Previous studies have shown that intragranular T phase precipitation, facilitated by increased Mg content, contributes to the mitigation of quasi-cleavage fracture. However, the role of T phase precipitation on the grain boundary in suppressing intergranular fracture remains unclear. In this study, in-situ observational techniques were used to examine the relationship between grain boundary precipitates and hydrogen-induce intergranular cracking. Obtained results showed that while the T phase precipitates in the matrix of Mg-enhanced alloy, the η phase predominates on grain boundaries, which lead intergranular fracture. The presence of numerous voids at intergranular crack tips suggests that void nucleation along grain boundaries and subsequent coalescence is the primary mechanism of crack propagation. The observed void formation at η phase interfaces is consistent with first-principles calculations and supports the concept that intergranular fracture originates from debonding at η phase interfaces.





Citations (55)


... Three-dimensional CT image of closed pores in sintered pure Fe of 3.8% porosity under no load24 . ...

Reference:

Quantification of Three-Dimensional Pore Configurations in Porous Materials Using Persistent Homologyパーシステントホモロジーを用いた多孔質材料の3次元気孔配置の数値化
Analysis Of The Mechanism Of Ductile Crack Initiation In High Densely Sintered Iron - Visualization And Quantification Of The 3D Pore-configurations By Synchrotron X-ray Tomography And Persistent Homology
  • Citing Conference Paper
  • September 2022

... Brines are a subject of intense interest to the planetary science community 39 in regard to understanding the internal structure of ice-rich worlds, and to the formation and preservation of prebiotic organics and their astrobiological potential. Samples returned from the carbonaceous asteroid Ryugu contain Ca,Mg carbonates, Mg,Na phosphate 40 and Na carbonate 41 . Extracts produced with hot water, termed salts, contain (Na + K/Na + K + Mg + Ca) of about 0.9 and, for formic acid extracts, termed carbonates, this value is roughly 0.10-0.15 ...

Sodium carbonates on Ryugu as evidence of highly saline water in the outer Solar System

Nature Astronomy

... 11,100−109 A large portion of the early work exclusively focused on lithium metal anodes and degradation mechanisms that occur at solid electrolyte-lithium metal interfaces, including void formation during electrodissolution, 59,101,107,110 dendrite initiation and penetration, 70,100,111−114 and solid electrolyte fracture. 3,104,113,115−117 Research since then has expanded to additional materials 3,118 and other aspects of SSB behavior, including cathode phase transformations, structural evolution and morphological changes, 119−121 full SSB cell failure mechanisms, 119 and the chemical evolution of electrode materials. 48,122 Figure 5a illustrates the characteristic length scales for a cathode, solid electrolyte, and lithium metal anode, which cycles 4 mAh cm −2 capacity or 100% of the active material (lithium). ...

Investigating Plastic Deformation Between Silicon and Solid Electrolyte in All-Solid-State Batteries Using Operando X-ray Tomography

... ZG25MnCrNiMo is the primary material used for the hook tongue of rail vehicles, exhibiting characteristics such as high strength, favorable forming properties for both hot and cold machining, good corrosion resistance, and high fatigue strength [10]. The development of the railway industry toward high-speed and heavy-duty operations has significantly deteriorated the service conditions of such material. ...

In-situ observation of solidification behaviors of Fe-Mn-Cr-Ni-Si alloy during TIG melt-run welding using synchrotron radiation X-ray
  • Citing Article
  • June 2024

Materials Characterization

... These local structures likely formed because of variations in particle agglomeration during the drying process: closely packed particles formed the high-density regions, whereas loosely packed particles formed the low-density regions. 33 The local packing distribution and pores were isotropic across all the specimens. Okuma et al. 33 fabricated alumina products via tape casting, one of the slurry processing technologies, and lamination, and they visualized a layered interface because of linearly distributed pores. ...

Evolution of microstructure and defects in sintering of tape-cast alumina laminates observed by synchrotron X-ray multiscale tomography
  • Citing Article
  • April 2024

Ceramics International

... In the taxonomic studies of another macroturbellarian taxon, Tricladida (triclad flatworms including planarians), micro-CT imaging has yielded good results in the re-observation of type specimens as well as in the description of a new species (Carbayo and Lenihan, 2016;Silva and Carbayo, 2020). In polyclad flatworms, micro-CT scanning has been employed to explore the nervous system anatomy (Ikenaga et al., 2024); however, there has been no research using the system for taxonomic studies. The inherent gray-scale nature of CT images can limit detailed characterization when organ contrast is low. ...

Volume X-Ray Micro-Computed Tomography Analysis of the Early Cephalized Central Nervous System in a Marine Flatworm, Stylochoplana pusilla
  • Citing Article
  • April 2024

ZOOLOGICAL SCIENCE

... For Ryugu samples, this volume fraction is ∼12% ± 4% (A. Tsuchiyama et al. 2024), which we consider the upper value (16%) to derive an upper bound on the amount of water that was physically removed after aqueous alteration. It can be calculated as ...

Three-dimensional textures of Ryugu samples and their implications for the evolution of aqueous alteration in the Ryugu parent body
  • Citing Article
  • March 2024

Geochimica et Cosmochimica Acta

... By leveraging the dualconduction capabilities of halides, we aim to design halogenated sulfur-based cathodes that enable a single-phase reaction mechanism, thereby eliminating the challenges associated with threephase interfaces. This strategy differs from previously reported Li 2 S-LiI-MS x (M═V, Mo) and related composite materials, [30,69,70] which inherently compromise specific capacity through transition metal incorporation, despite their beneficial reduction in conductive additive requirements. Actually, improving the redox kinetics of the S/S 2− redox couple has been demonstrated by Pang et al., [2] who successfully simplified the reaction mechanism from a three-phase to a two-phase process by designing a surface redox mediator on the sulfur-based cathode. ...

Tuning the ionic and electronic paths in Li2S-based cathode for high-rate performance all-solid-state lithium‑sulfur batteries
  • Citing Article
  • March 2024

Solid State Ionics

... The microstructural features of these materials, such as grain boundaries, serve as pathways for hydrogen migration, while dislocations can serve as both rapid diffusion pathways and trapping sites [11]. Precipitates and the general lattice structure further complicate the diffusion processes, which can lead to localized hydrogen accumulation and the formation of cracks [4,12,13]. ...

Assessment of hydrogen embrittlement behavior in Al-Zn-Mg alloy through multi-modal 3D image-based simulation

International Journal of Plasticity

... This carbonate exhibits the 290.5-eV peak characteristic of the carbonate functional group (Extended Data Fig. 3), but does not diffract as crystals on TEM. Similar amorphous carbonate was observed in Ryugu samples 18,19 . This carbonate could represent an important reservoir of total carbonate ions in Bennu samples, given the abundance of phyllosilicates (about 80 vol.%) 5 . ...

Electron microscopy observations of the diversity of Ryugu organic matter and its relationship to minerals at the micro‐ to nano‐scale
  • Citing Article
  • January 2024

Meteoritics & Planetary Science