A. V. Savenko’s research while affiliated with A. N. Kosygin Moscow State Textile University and other places

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Publications (119)


Fluorine in the Waters of Hypersaline Water Bodies: Dead Sea, Lake Urmia
  • Article

April 2024

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2 Reads

Water Resources

A. V. Savenko

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V. S. Savenko


PRESENT-DAY FLUORINE CONCENTRATION IN THE OB RIVER WATER

February 2024

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4 Reads

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2 Citations

Lomonosov Geography Journal

Based on the potentiometric measurements average fluorine concentrations for different phases of the hydrological regime were determined in water samples taken in 2018-2020 in the outlet of the Ob River: 0,103 mg/L in the winter low-water period, 0,079 mg/L in the spring - summer flood, and 0,095 mg/L in the summer - autumn low-water period. The present-day weighted average concentration of fluorine in the Ob River water (0,086 mg/L) closely corresponds to the values measured in 1954-1956 and 1976-1980 (0,090 and 0,084 mg/L, respectively), therefore the fluorine content of 0,08-0,09 mg/L could be taken as a natural background.


Figure 2. Comparison of the mean concentrations of dissolved trace elements (μg/L) in the waters of mouth reaches of rivers of the Russian Arctic sea watersheds with the global runoff (СGR). (a) Watersheds of the White and Pechora seas: (1) СWS is the mean for the rivers of Kandalaksha Bay, Onega, Kyanda, Severnaya Dvina, Kuloy, Mezen, and Semzha, taking into account the ratio of the volumes of their long-term average water runoff; (2) СPS is the mean for the Pechora River. (b) Watersheds of the Kara and Laptev seas: (1) СKS is the mean for the Ob, Pur, Taz, and Yenisei rivers, taking into account the ratio of the volumes of their long-term average water runoff; (2) СLS is the mean for the Lena River. (c) Watershed of the East Siberian Sea: СESS is the mean for the Kolyma River. Dash and dot-and-dash lines show three-and fivefold differences, respectively.
Characteristic of water sampling in the mouth reaches of rivers of the Russian Arctic sea watersheds.
The mean concentrations of dissolved trace elements in the waters of mouth reaches of rivers of the White and Pechora sea watersheds, µg/L.
Cont.
The mean concentration of dissolved trace elements in the waters of mouth reaches of rivers of the Kara, Laptev, and East Siberian sea watersheds, µg/L.
Trace Element Composition of the Dissolved Matter Runoff of the Russian Arctic Rivers
  • Article
  • Full-text available

February 2024

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60 Reads

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7 Citations

Data on the content of dissolved trace elements (P, Si, Li, Rb, Cs, Be, Sr, Ba, Mn, Fe, Co, Ni, Cu, Zn, Cd, Tl, Pb, Al, Ga, Y, Ti, Zr, Hf, Th, U, rare earth elements, F, B, Ge, V, As, Sb, Cr, Se, Mo, and W) in the river runoff from the Russian Arctic sea watersheds were systematized and generalized. There is a tendency for the decrease in the trace element concentrations in the direction from west to east for the considered Arctic watersheds (the White, Pechora, Kara, Laptev, and East Siberian seas). It was shown that the concentrations of dissolved trace elements in the river runoff from the Russian Arctic sea watersheds are in general consistent with modern estimates of the average composition of the global river runoff.

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The solubility of CaF2 in seawater of normal and increased salinity (associated with genesis of fluorite in sedimentary rocks)

October 2023

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9 Reads

Moscow University Bulletin Series 4 Geology

The solubility of crystalline and precipitated calcium fluoride in seawater and brines of the first stages of its evaporative concentration (before the beginning of gypsum and halite setting) was experimentally studied. It was established that in the entire studied range of salinity, seawater and its derivatives are strongly undersaturated by the calcium fluoride, which excludes its spontaneous precipitation in drying isolated sea basins. A necessary condition for the formation of sedimentary fluorite is the entry into the drying sea basins of significant amounts of dissolved fluorine from external sources, which can be river runoff, volcanic emanations, and hydrothermal solutions.



Solubility of BaSO4 in Standard and Desalinated Seawater

September 2023

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3 Reads

Океанология

The solubility of BaSO4 in seawater with a salinity of 0.35–35‰ was experimentally determined. With an increase in salinity from 0.35 to 10‰, the equilibrium concentration of dissolved barium decreases from 42 to 28 μg/L, remains at the level of ~28 μg/L in the salinity range from 10 to 25‰, and increases to 30.7 μg/L at the salinity of 35‰. When the concentration of dissolved barium in the river runoff is higher than 40–45 μg/L, BaSO4 can precipitate in the mixing zone of river and sea waters, most likely with the participation of living organisms. When the concentration of dissolved barium in the river runoff is below 40–45 μg/L, its additional source in the mixing zone of river and sea waters can be the dissolution of suspended BaSO4, but presence of the latter in the composition of removed terrigenous material is unlikely and is not detected by direct observations.


FLUORINE IN THE NORTH ATLANTIC WATERS

July 2023

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9 Reads

Lomonosov Geography Journal

New data on the fluorine content in North Atlantic waters was obtained by the method of direct potenti-ometry with a fluoride ion-selective electrode. The measured fluorine concentration was equal to 1,27 0,03 mg/kg at F/Cl mass ratio of (6,59 0,11) · 10-5, which closely corresponds to the normal fluorine content in seawater. The totality of available data on the F/Cl ratio in different areas of the World Ocean suggests rather low variability of the fluorine content in seawater salts.


Citations (45)


... For a long time, the authors systematically studied the abundance of dissolved trace elements in the waters of the outlet sections (mouth reaches) of large, medium, and small rivers of the Russian Arctic using modern, highly sensitive analytical methods. The objective of this work is to systematize and generalize the results of these studies [7][8][9][10] (including the unpublished data from A.V. Savenko) in conjunction with data from other literature sources [11][12][13][14][15][16][17][18][19][20][21][22][23][24][25][26][27][28] and to estimate the mean concentrations of dissolved trace elements in the river runoff from the White, Pechora, Kara, Laptev, and East Siberian sea watersheds. ...

Reference:

Trace Element Composition of the Dissolved Matter Runoff of the Russian Arctic Rivers
Fluorine Concentrations in the Lena R. Water from 1995 to 2021
  • Citing Article
  • March 2024

Water Resources

... For a long time, the authors systematically studied the abundance of dissolved trace elements in the waters of the outlet sections (mouth reaches) of large, medium, and small rivers of the Russian Arctic using modern, highly sensitive analytical methods. The objective of this work is to systematize and generalize the results of these studies [7][8][9][10] (including the unpublished data from A.V. Savenko) in conjunction with data from other literature sources [11][12][13][14][15][16][17][18][19][20][21][22][23][24][25][26][27][28] and to estimate the mean concentrations of dissolved trace elements in the river runoff from the White, Pechora, Kara, Laptev, and East Siberian sea watersheds. ...

PRESENT-DAY FLUORINE CONCENTRATION IN THE OB RIVER WATER
  • Citing Article
  • February 2024

Lomonosov Geography Journal

... In fact, the inter-annual monthly variation of elemental yields for the same river (a factor of 2 to 5; see Table S2) and intrinsic uncertainties (at least 50 %) on yields estimated for the large rivers based on <6-7 samplings per year (Gordeev et al., 2024) are comparable with the differences between mean values for 7 Artic rivers and the two small tributaries of the Ob River studied in this work (Table S3). Generally, for Arctic rivers, due to the strong spatial-temporal variability of dissolved trace element concentrations in their waters and a relatively small number of measurements, only differences in mean values as high as a factor of 3 are considered significant (Savenko and Savenko, 2024). ...

Trace Element Composition of the Dissolved Matter Runoff of the Russian Arctic Rivers

... For a long time, the authors systematically studied the abundance of dissolved trace elements in the waters of the outlet sections (mouth reaches) of large, medium, and small rivers of the Russian Arctic using modern, highly sensitive analytical methods. The objective of this work is to systematize and generalize the results of these studies [7][8][9][10] (including the unpublished data from A.V. Savenko) in conjunction with data from other literature sources [11][12][13][14][15][16][17][18][19][20][21][22][23][24][25][26][27][28] and to estimate the mean concentrations of dissolved trace elements in the river runoff from the White, Pechora, Kara, Laptev, and East Siberian sea watersheds. ...

Trace Element Composition of the Waters of the Mouth of the Kolyma River
  • Citing Article
  • May 2023

Doklady Earth Sciences

... The consumption of dissolved mineral phosphorus by biota occurs in the surface layer or in the vertically mixing water column throughout the entire salinity range and varies from 6 to 100% of its content in river runoff. The most intensive consumption of mineral phosphorus by aquatic organisms is observed during the vegetative season and is most often accompanied by the extraction from the solution of another biogenic element, silicon [71][72][73][74]82,83,91,92]. Along with this, in the mouths of some rivers (Strelna of the Kandalaksha Bay of the White Sea, Chernaya of the Sevastopol Bay of the Black Sea, and Razdolnaya of the Amur Bay of the Sea of Japan), the removal of dissolved mineral phosphorus was found even in winter, with relatively low biological activity. ...

Transformation of the Major and Trace Element Composition of Dissolved Matter Runoff in the Mouths of Medium and Small Rivers of Russia’s Black Sea Coast
  • Citing Article
  • June 2022

Oceanology

... On the geochemical barrier river -sea, exchange processes occur. They lead to the transformations of the dissolved elements' runoff in the sorbed complex of freshwater terrigenous material, which are described in detail in [19]. It is known from this work that when terrigenous substances penetrate into the marine environment, ion-exchange transformation of the runoff of the dissolved substances occurs. ...

Adsorbed Chemical Elements of River Runoff of Solids and Their Role in the Transformation of Dissolved Matter Runoff into the Ocean

... The range of reported concentrations of phosphorus compounds in river waters is considerable. The mean median concentrations of dissolved mineral phosphorus and total phosphorus in rivers worldwide are 28 and 85 mg•dm −3 , respectively (Savenko and Savenko, 2022). The PO 4 2− levels in the polish river Szreniawa were found to be between 0.16 and 0.25 mg•dm −3 , while in the stream Korzeń, the concentration of PO 4 2− was significantly higher -0.718 mg•dm −3 (Fudała, Bogdał and Kowalik, 2023;Lach et al., 2023). ...

The Main Features of Phosphorus Transport in World Rivers

... The longevity of the Lusi eruption (still active after more than 5 years) is atypical when compared to other mud volcanoes that usually extinguish the largest amount of overpressure after few hours or days and become dormant (Aliyev et al., 2002;Deville and Guerlais, 2009;Shnyukov et al., 1986). Is this surprising activity related to the Lusi infancy, or are mud volcanoes not relevant analogues for understanding Lusi? ...

Fluorine in the Waters of Mud Volcanoes in the Kerch-Taman Region
  • Citing Article
  • March 2021

Moscow University Geology Bulletin

... The greatest differences between the relative MIC and the SSW composition are observed in deep ocean waters due to dissolution of carbonates, silicates and oxidation of plant residues, etc. [5,6], in waters with high dissolved organic carbon concentrations and total alkalinity. The most pronounced ion variations are in such parts of the World Ocean as estuaries, basins with anoxic zones, as well as in thermal springs, evaporation basins, etc. [4,5,7]. ...

Sorption–Desorption Transformation of the Runoff of Dissolved Microelements at River–Sea Geochemical Barrier (Based on Data of Experimental Laboratory Simulation)
  • Citing Article
  • March 2021

Water Resources

... The large water consumption of industry results in the co-production of heterogeneous wastewater streams that often contain a wide range of chemical pollutants, including fluorides, which dissolve and enter groundwater through weathering processes and water circulation [3]. High concentrations of aluminum, low concentrations of magnesium and calcium oxides, and soil conditions such as alkalinity increase subsoil fluoride ion leaching [4] 47 which also increase the availability of fluorides in water sources [5,6]. ...

Patterns in the Organic-Acid Leaching of Fluorine from Rocks
  • Citing Article
  • September 2020

Moscow University Geology Bulletin