A. Messina’s research while affiliated with University of Messina and other places

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Publications (45)


Transformation of kyanite to andalusite in the Benamocarra Unit (Betic Cordillera, S. Spain). Kinetics and petrological significance
  • Article

March 2016

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56 Reads

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9 Citations

European Journal of Mineralogy

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Elisa Macaione

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Rita De Cassia Oliveira-Barbosa

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[...]

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Kyanite is directly replaced by andalusite in quartz-plagioclase veins included within graphite-bearing micaschists of the Alpine Benamocarra Unit (Betic Cordillera, Spain). Electron back-scattered diffraction indicates that: i) precursory kyanite contains planar defects; andalusite growth was crystallographically controlled by the kyanite; and iii) the structure of both Al2SiO5 phases shares nearly the closest-packed oxygen array and chains of edge-sharing octahedra. The small entropy difference of the kyanite andalusite polymorphic inversion makes it difficult to overcome the energy barrier of this transformation. The driving force needed for the kyanite-to-andalusite reaction was a temperature (7) increase during a pre-Alpine tectonometamorphic evolution. The low-P/medium-T metamorphic conditions that affected the rocks studied took place in relation to a late Variscan extensional collapse. The reaction pathway proposed here corresponds to the first part of a poly-orogenic tectonometamorphic evolution, consisting of a pre-Alpine metamorphism of high thermal gradient with mainly static growth of porphyroblasts, followed by an essentially dynamic metamorphism during the Alpine orogeny.


Fig. 1. A general view that shows the previous stream sediment study area (box A and B) (De Vivo et al. 1993, 1998a) and the current study area (box C) on the island of Sicily, Italy. Also shown is the shear contact between Aspromonte, Mandanici and Fondachelli units (De Vivo et al. 1993).
Fig. 3. Cumulative frequency curves for selected potentially toxic elements As, Zn, Sb, Pb, Cd, Hg, Sn and V (A-H). Also shown is the percentage cumulative value corresponding to the RAL (continuous orange line) and to the IAL (continuous red line).
Fig. 4. Interpolated geochemical maps of As, Zn Sb and Pb (A-D). Areas of mineralization and old mining locations are also shown. For potentially toxic elements, class intervals where the upper limit corresponds to the Residential Action Limit (RAL) and/or to the Industrial Action Limit are also indicated.
Fig. 5. Interpolated geochemical maps of Sn, Au, Ag, and Fe (E-H). Areas of mineralization and old mining locations are also shown. For potentially toxic elements, class intervals where the upper limit corresponds to the Residential Action Limit (RAL) and/or to the Industrial Action Limit IAL are also indicated.
Fig. 6. (A) Comparison between the isotopic ratio values of selected topsoil and profile samples and galena samples (this study), which are used to establish the geogenic field. Pb isotopic ratios of fossil fuels (gasoline) and gaseous emissions in the atmosphere (aerosols) of industrial areas of Sicily (Monna et al., 1999) establish the anthropogenic field. (B) Plot of Pb isotopic ratios. Leached and residue data are plotted for selected topsoils and profile soils.

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Soil geochemical survey of abandoned mining sites in the Eastern-Central Peloritani Mountains, Sicily, Italy
  • Article
  • Full-text available

November 2015

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113 Reads

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4 Citations

Geochemistry Exploration Environment Analysis

This investigation focused on topsoils ( n = 122) and vertical profiles ( n = 6) distributed over an area of 250 km ² in the eastern-central Peloritani Mountains, northeastern Sicily. Georeferenced concentration of 53 elements (including potentially harmful ones), determined by ICP-MS after an aqua regia leach, were used to produce geochemical maps by means of a GIS-aided spatial interpolation process. Results show that there are two distinct areas: the larger, located between the Fiumendinisi, Budali and Ali villages, and the other between C. Postlioni and Femmina Morta, which contain anomalous As (up to 727 mg/kg), Sb (up to 60 mg/kg), Ag (up to 1 mg/kg) and Au (up to 0.1 mg/kg) concentrations. Most of the investigated areas have high contamination levels for As, Zn, Sb, and Pb that exceed the threshold values (As = 20 mg/kg, Zn = 150 mg/kg, Sb = 10 mg/kg and Pb = 100 mg/kg) established for soils by the Italian Environmental Law ( Decreto Legislativo 2006 , number 152). The isotopic ratios of ²⁰⁶ Pb/ ²⁰⁷ Pb and ²⁰⁸ Pb/ ²⁰⁷ Pb have been measured in selected soils on both leaches [using 1M HNO 3 –1.75M HCl (50:50)] and residues thereof. Soil leach reflects possible anthropogenic contamination, whereas soil residues indicate geogenic contributions. Results suggest that most of contamination in the soils is related to the presence of sulphide and sulphosalt rock-forming minerals in the surveyed area. The soil fraction contains a Pb value >1600 mg/kg and has ratios of 1.1695 for ²⁰⁶ Pb/ ²⁰⁷ Pb and 2.4606 for ²⁰⁸ Pb/ ²⁰⁷ Pb. Only one soil leach isotopic composition could reflect possible anthropogenic contamination. The correlation among As, Zn, Pb contents v. Pb isotopic signatures of ²⁰⁶ Pb/ ²⁰⁷ Pb indicates that surface and deep soils collected from profiles are dominated by geogenic compositions.

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Soil geochemical survey of abandoned mining sites in the Eastern-Central Peloritani Mountains, Sicily, Italy

July 2015

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90 Reads

This investigation focused on topsoils (n = 122) and vertical profiles (n = 6) distributed over an area of 250 km in the eastern-central Peloritani Mountains, northeastern Sicily. Georeferenced concentration of 53 elements (including potentially harmful ones), determined by ICP-MS after an aqua regia leach, were used to produce geochemical maps by means of a GIS-aided spatial interpolation process. Results show that there are two distinct areas: the larger, located between the Fiumendinisi, Budali and Ali villages, and the other between C. Postlioni and Femmina Morta, which contain anomalous As (up to 727 mg/kg), Sb (up to 60 mg/kg), Ag (up to 1 mg/kg) and Au (up to 0.1 mg/kg) concentrations. Most of the investigated areas have high contamination levels for As, Zn, Sb, and Pb that exceed the threshold values (As = 20 mg/kg, Zn = 150 mg/kg, Sb = 10 mg/kg and Pb = 100 mg/kg)# established for soils by the Italian Environmental Law (Decreto Legislativo 2006, number 152). The isotopic ratios of Pb/ Pb and Pb/ Pb have been measured in selected soils on both leaches [using 1M HNO3–1.75M HCl (50:50)] and residues thereof. Soil leach reflects possible anthropogenic contamination, whereas soil residues indicate geogenic contributions. Results suggest that most of contamination in the soils is related to the presence of sulphide and sulphosalt rock-forming minerals in the surveyed area. The soil fraction contains a Pb value >1600 mg/kg and has ratios of 1.1695 for Pb/ Pb and 2.4606 for Pb/ Pb. Only one soil leach isotopic composition could reflect possible anthropogenic contamination. The correlation among As, Zn, Pb contents v. Pb isotopic signatures of Pb/ Pb indicates that surface and deep soils collected from profiles are dominated by geogenic compositions.







Bulk rock composition and geochemistry of olivine-hosted melt inclusions in the Grey Porri Tuff and selected lavas of the Monte dei Porri volcano, Salina, Aeolian Islands, southern Italy

May 2012

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196 Reads

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6 Citations

The Aeolian Islands are an arcuate chain of submarine seamounts and volcanic islands, lying just north of Sicily in southern Italy. The second largest of the islands, Salina, exhibits a wide range of compositional variation in its erupted products, from basaltic lavas to rhyolitic pumice. The Monte dei Porri eruptions occurred between 60 ka and 30 ka, following a period of approximately 60,000 years of repose. The bulk rock composition of the Monte dei Porri products range from basaltic-andesite scoria to andesitic pumice in the Grey Porri Tuff (GPT), with the Monte dei Porri lavas having basaltic-andesite compositions. The typical mineral assemblage of the GPT is calcic plagioclase, clinopyroxene (augite), olivine (Fo72−84) and orthopyroxene (enstatite) ± amphibole and Ti-Fe oxides. The lava units show a similar mineral assemblage, but contain lower Fo olivines (Fo57−78). The lava units also contain numerous glomerocrysts, including an unusual variety that contains quartz, K-feldspar and mica. Melt inclusions (MI) are ubiquitous in all mineral phases from all units of the Monte dei Porri eruptions; however, only data from olivine-hosted MI in the GPT are reported here. Compositions of MI in the GPT are typically basaltic (average SiO2 of 49.8 wt %) in the pumices and basaltic-andesite (average SiO2 of 55.6 wt %) in the scoriae and show a bimodal distribution in most compositional discrimination plots. The compositions of most of the MI in the scoriae overlap with bulk rock compositions of the lavas. Petrological and geochemical evidence suggest that mixing of one or more magmas and/or crustal assimilation played a role in the evolution of the Monte dei Porri magmatic system, especially the GPT. Analyses of the more evolved mineral phases are required to better constrain the evolution of the magma.



Citations (33)


... For instance, De Vivo et al. (1993) stressed the presence of anomalous contents of As, Hg, Sb, Zn and Pb in stream sediments from this area, whereas Dongarrà et al. (2009) found high As concentrations in waters from mineralised areas. A geogenic source for the As contamination detected in the Peloritani Mountains was also suggested by Cangemi et al. (2021), agreeing with previous results of Cosenza et al. (2015) who reported high PTE content in soils from Fiumedinisi, Budali and Alì, related to the weathering of ore deposits and mine wastes. ...

Reference:

Occurrence and crystal chemistry of austinite, conichalcite, and zincolivenite from the Peloritani Mountains, northeastern Sicily, Italy
Soil geochemical survey of abandoned mining sites in the Eastern-Central Peloritani Mountains, Sicily, Italy

Geochemistry Exploration Environment Analysis

... The Aspromonte-Peloritani Unit consists of orthogneisses (mostly augen gneisses), paragneisses, amphibolites, and marbles [55], intruded by Late Carboniferous-Permian granitoids [56]. It underlies the Stilo Unit of the Aspromonte Massif [57], that is composed by low greenschist-to amphibolite-facies metapelites [58] deriving from a former Paleozoic succession [59], and overlies a stack of nappes, among which the Variscan metamorphic rocks are included in the Mandanici Unit and the Lower Complex [29,60] (Figure 2). The Mandanici Unit is composed of phyllites and quartzites, with metabasites and calc-schists [61], while the Lower Complex consists of minor tectonic slices dominated by phyllites, porphyroids and metandesites, deriving from Palaeozoic volcano-sedimentary successions, equilibrated under low greenschists facies metamorphic conditions [62][63][64]. ...

L'Unita superiore dell'Aspromonte. Studio geologica e petrografico.
  • Citing Article
  • January 1982

... At this last phase are related the structures that delimit the crystalline building (Taormina Line to the south and Sangineto Line to the north) and divide it into a southern and a northern sectors by means of the Catanzaro Trough (Brutto et al. 2016) (Fig. 2). The Sila represents one of the horsts in the northern sector of Calabria and it is configured as a junction area between the Pliocene-Pleistocene Graben of the Crati (Barone et al. 2008;Zecchin et al. 2020;Civile et al. 2022) (Fig. 3).The Sila orogen is made up of the Paleozoic basement of the Sila Unit (Messina et al. 1991(Messina et al. , 1994, formed by a large plutonic complex, the Sila Batolith, and by three distinct metamorphic complexes of Gariglione (medium-high metamorphic grade), Mandatoriccio (medium-low grade) and Bocchigliero (low grade complex), locally covered by the Longobucco Mesozoic sedimentary succession (Fig. 3). Middle-Miocene to Pleistocene sedimentary successions unconformably overlap both sedimentary cover and basement rocks of the eastern side of Sila (Critelli 1999). ...

Geological and petrochemical study of the Sila Massif Plutonic rocks (Northern Calabria, Italy)
  • Citing Article
  • January 1981

... It consists of a thick pile of Paleozoic polymetamorphic nappes including Hercynian crystalline basement rocks superimposed on Jurassic to Early-Cretaceous ophiolite-bearing units and together overthrusted upon Triassic-Miocene sedimentary succession of the Appennine chain https://doi.org/10.1016/j.marpetgeo.2020.104386 Received 9 January 2020; Accepted 3 April 2020 during Miocene (Amodio Morelli et al., 1976;Bonardi et al., 2001;Butler et al., 2004;Iannace et al., 2007). The Calabrian Arc migrated south-eastward from mid-Miocene onwards in response to roll-back of a NW-dipping subduction of the Ionian oceanic slab, which led to the opening of the Vavilov and Marsili sub-basins in the Tyrrhenian backarc Basin (Malinverno and Ryan, 1986;Patacca et al., 1990;Sartori, 1990;Gueguen et al., 1998;Faccenna et al., 2001Faccenna et al., , 2004 (Fig. 2). ...

The carbonate tectonic units of northern Calabria (Italy): a record of Apulian palaeomargin evolution and Miocene convergence, continental crust subduction, and exhumation of HP–LT rocks

Journal of the Geological Society

... In each diagram data from the analysed samples (black dots) are plotted together with those from Sardinia and Calabria basement rocks (coloured shaded areas). The latter geochemical data have been taken from Ferla (1978), Ioppolo & Puglisi (1980), D'Amico et al. (1981, Messina et al. (1988Messina et al. ( , 1991, Messina, Russo & Lima (1993) and Fiannacca et al. (2015) in the case of the calabrian rocks and from Di Simplicio et al. (1974), Del Moro et al. (1975), Traversa & Vaccaro (1992, Di Vincenzo, Andriessen & Ghezzo (1996), Cortesogno et al. (1998), Barbey et al. (2008), Cruciani et al. (2013) in the case of Sardinia. ...

Calc-alkaline Late Variscan two micacordierite-Al silicate-bearing intrusion of the Sila batholith (northern sector of the Calabrian Arc, Italy)
  • Citing Article
  • January 1991

... comm. of Agustin Martin-Algarra). It may be of interest that similar rocks are typical Variscan metamorphites belonging to the Benamocarra Unit in the Betic Cordillera (Spain) [55]. The source areas could be different and complex to identify, because the studied metamorphic lithics could be also cannibalized clasts deriving from different Miocene to Pleistocene siliciclastic sequences of the Calabria-Peloritani Arc. ...

Transformation of kyanite to andalusite in the Benamocarra Unit (Betic Cordillera, S. Spain). Kinetics and petrological significance
  • Citing Article
  • March 2016

European Journal of Mineralogy

... Sicilide Complex of Ogniben, 1960;Roure et al. 1990; Barbera, Critelli & Mazzoleni, 2011). This interpretation conflicts with the evidence of a diffuse Alpine metamorphic overprint that is detectable along large portions of the Variscan basement units as well as part of the Mesozoic sediments (Ferla & Azzaro, 1976;Cirrincione & Pezzino, 1991Messina et al. 1992;Pezzino et al. 2008;Fazio et al. 2010;Cirrincione et al. 2011), thus implying the syn-tectonic exhumation of deep crustal levels, similarly to the northern part of the orocline. ...

Alpine metamorphic overprint in the Aspromonte nappe of the northeastern Peloritani Mts (Calabria-Peloritani Arc, southern Italy)
  • Citing Article
  • January 1990

... The Peloritan terrane is a SSW-verging nappe stack including an Upper Complex made by high-grade (amphibolite facies) metamorphic nappes and isolated plutons (Aspromonte and Mela Units) stacked over medium grade (greenschist-lower amphibolite facies) rocks (Mandanici, Alì-Montagnareale), in turn overriding an external Lower Complex (San Marco d'Alunzio, San Pietro-Castelmola, Longi-Taormina, and Capo S. Andrea Units) made by very low grade metamorphic basement covered by un-metamorphosed Meso-Cenozoic sedimentary sequences (Cirrincione et al., 1999(Cirrincione et al., , 2015Figure 4). Metamorphism affecting all units, except Lower Complex sediments, is both pre-Hercynian (Fiannacca et al., 2013) and Hercynian in age (314 Ma from Rb/Sr dating, Bonardi et al., 2001), with a 28-22 Ma (Oligocene) Alpine metamorphic overprint documented in the Aspromonte, Mandanici and Ali-Montagnareale Units (Atzori et al., 1994;Bonardi et al., 1987Bonardi et al., , 1992Catalano et al., 2018;Cirrincione et al., 2012Cirrincione et al., , 2015 (Figures 6a-6c). During Late Cretaceous-Eocene, whitish, reddish and greenish pelagic limestones, marls, and siltstones containing chert ("Scaglia" facies, widespread in all coeval Tethyan pelagic sequences) deposited throughout (Figures 6d and 6e). ...

Sovrimpronta metamorfica alpina nell'Unità dell'Aspromonte (settore meridionale dell'Arco Calabro-Peloritano)
  • Citing Article
  • January 1992

... The upper units (Aspromonte and Mela Units) are affected by a Variscan high-to medium-grade metamorphism, whereas the lower units (Mandanici-Piraino, Fondachelli, and Longi-Taormina Units) are affected by a Variscan medium-to very low-grade metamorphism, from top to base of the thrust pile [17,31,32]. An Alpine overprint was also recognized in the Aspromonte and Mandanici-Piraino Units [33][34][35], whereas an anchizone metamorphism affected the post-Varican sedimentary sequence of the Alì-Montagnareale Unit [36]. ...

Rb-Sr age constraints on the Alpine metamorphic overprint in the Aspromonte Nappe (Calabria-Peloritani Composite Terrane, southern Italy)

Bollettino della Societa Geologica Italiana

... The Río Pliego Fm is a thick turbiditic succession with yellow, brown and reddish brown micaceous sandstones, mudstones, calcarenites and conglomerates whose clasts come, mainly, from the Piar Group and the Saladilla Fm and, less frequently, from the Maláguide cover and other sources (Mac Gillavry et al. 1963;Geel 1973;Hermes 1984;Martín-Algarra 1987). The upper part of the Ciudad Granada Group, in particular, is characterized by polymictic, coarse-grained debris flow conglomerates with well-rounded clasts, among them cobbles and boulders eroded from Variscan granitoids and orthogneisses that show identical features to those of the Kabylia and Calabria-Peloritan basements Careri et al. 2004), although possible Iberia-related sources have also been proposed by Gigliuto et al. (2004). ...

Petrography and geochemistry of granitoid pebbles from the Oligocene-Miocene deposits of the Internal Rifian Chain (Morocco): A possible new hypothesis of provenance and paleogeographical implications - Discussion