January 2025
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11 Reads
Planetary and Space Science
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January 2025
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11 Reads
Planetary and Space Science
July 2023
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13 Reads
March 2023
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103 Reads
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6 Citations
March 2021
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28 Reads
March 2021
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29 Reads
March 2021
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57 Reads
March 2020
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617 Reads
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46 Citations
Geochimica et Cosmochimica Acta
We report partition coefficients for Sr, Sc, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Y, and Th for plagioclase, pigeonite, and olivine experimentally grown from a lunar basaltic liquid at 1 bar and two different oxygen fugacities (fO2; fayalite-magnetite-quartz (FMQ) and the iron-wüstite (IW) oxygen buffers) at temperatures (Ts) of 1100 to 1125°C. These results expand the partitioning database for plagioclase-silicate melt partitioning at lunar relevant conditions and compositions. Variations of partition coefficients for rare earth elements (REEs) are highly systematic with respect to ionic radii, in agreement with lattice strain theory. We use the lattice strain model to evaluate partition coefficients for highly incompatible elements such as the light (or in the case of plagioclase, heavy) REEs, for which direct determinations are experimentally and analytically difficult. Our experiments suggest that within analytical and experimental uncertainty, over the range of explored fO2 (FMQ to IW) , T (1100-1125°C) and An# conditions (An# >94.5, where An#=Ca/(Ca+Na)×100, in moles), fO2 exerts an important but secondary control on Eu partitioning in anorthitic plagioclase. In contrast, the global plagioclase-melt partitioning dataset highlights the first-order role of fO2 in determining plagioclase-melt Eu partition coefficients over a wide range of An#s. Using experimental results and predictive models for divalent and trivalent element plagioclase-melt partitioning in the plagioclase ring site, we parameterized an fO2-dependent plagioclase-melt Eu partitioning model. Within a factor of two, the model reproduces measured Eu partition coefficients for a wide range of experimental conditions (750-1400ºC) and compositional systems (basalts to dacites) over >15 orders of magnitude variation in fO2. When equilibrium partitioning of Eu between plagioclase and melt can be established, the model may be applied as a plagioclase-melt oxybarometer. Preliminary application to plagioclase-hosted melt inclusions in mid-ocean ridge basalts suggests they equilibrated near the FMQ buffer. We used the new Eu partitioning model to evaluate the petrogenesis of a lunar anorthositic impactite that hosts plagioclase with both positive and negative Eu anomalies. Our investigation suggests the distribution of REEs and Eu in this sample is consistent with subsolidus reequilibration after impact-induced heating.
March 2020
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34 Reads
March 2020
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12 Reads
January 2018
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15 Reads
... Likewise, thanks to the extremely low temperatures in the lunar south pole (below 110 K) [8], PSRs can act as cold traps capable of storing both volatile compounds and water ice over time [9][10][11]. Obviously, both the main objectives and other experimental scientific tests on the lunar surface must be carried out without posing a risk to astronauts [12,13]. ...
March 2023
... We performed P-T grid calculations from 0.2 to 1.8 GPa, with pressure increments of 0.06 GPa and temperature ranges from 1,100°C to 1,600°C, with increments of 5°C. Oxygen fugacity (logfO 2 ) is kept at IW 2 (IW represents iron-wüstite thermodynamic equilibrium), which is the general fO 2 estimate for the lunar mantle (e.g., Cartier & Wood, 2019;Dygert et al., 2020;Ji & Dygert, 2024;Karner et al., 2006). We note that varying logfO 2 from IW 2 to IW has negligible effect on the calculation. ...
March 2020
Geochimica et Cosmochimica Acta
... One of the two major regions on the moon, Highlands, the bright areas, are entirely composed of anorthosites, which are rich in aluminum, calcium, and extremely widespread KREEP rocks enriched in K (potassium), P (phosphorous), and REE (rare earth element). Anorthosites have calcium-rich plagioclase and low calcium pyroxene (in significantly less amount), olivine, clinopyroxene, and Mg-rich rocks, which further have dunite, norite, spinel troctonite, troctonite, and gabbro anorthosite (Burke 1986;Papike et al. 1991;Warren 2005;Fagan 2016;Heiken et al. 1991). ...
July 2016
... The breccia and mixed lithology REE profiles are the most distinct from the basalts in the LREE. The overall depletion of REE in the mixed lithology subsamples relative to the breccia matrix can be explained by the incorporation of varying amounts of plagioclase into an amalgamation of the average 60639 basalt component and the average of the two separate breccia matrix components from Clasts 2 and 3. A plagioclase composition from an Apollo 16 cataclastic anorthosite (60618,4;Fagan, 2012) is selected as a typical highlands plagioclase with most chondrite-normalized REE concentrations of 6 or less, a large positive Eu anomaly, and An 97 . By combining $20% average 60639 basalt + 56% average Clast 2 breccia + 24% plagioclase, the calculated REE profile is a near perfect match to the average mixed lithology (Table 8). ...
January 2015
... We collected 125 sets of lunar sample data from the Apollo and Luna missions (Fagan & Neal, 2016;Wieczorek, 2006;Zeigler et al., 2006), and 30 sets of lunar meteorite sample data (Day et al., 2006;Elardo et al., 2014;Gnos et al., 2004;Greshake et al., 2008;Haloda et al., 2006Haloda et al., , 2009Warren, 1993;Zeigler et al., 2005). These data sets were filtered to include only valid FeO and TiO 2 content data. ...
August 2015
Geochimica et Cosmochimica Acta
... As a result, a refined understanding of impacts into the lunar regolith will yield greater insight into the geologic history and evolution of the Moon (e.g., Joy et al., 2012;McKay et al., 1986), and the production and processing of potentially accessible resources, such as hydroxyl (e.g., Liu et al., 2012;Pieters et al., 2009). Lunar regolith is mostly formed by impact processing (e.g., Fagan et al., 2014;McKay et al., 1991) and has been extensively studied in samples returned by the Apollo, Luna, and Chang'e Programs (e.g., Fruland, 1983;Li et al., 2021;Lucey et al., 2006). Impacts can also deliver surface material from planetary objects to Earth by ejecting shock-compacted regolith. ...
August 2014
Earth Moon and Planets
... The bulk chemistry and petrography of NCB-01 are consistent with other CE-5 basalts (endogenic basalts). However, it is worth noting that basaltic impact melt rocks with similar textures and chemistries are well known from the Moon (Fagan et al., 2013;Neal et al., 2015). Previous studies have proposed non-destructive methods to distinguish between endogenic basalts and basaltic impact melt rocks, mainly focusing on (a) geochemical characteristics of olivine and (b) textural characteristics of plagioclase (Fagan et al., 2013;Neal et al., 2015). ...
January 2015
Geochimica et Cosmochimica Acta
... We collected 125 sets of lunar sample data from the Apollo and Luna missions (Fagan & Neal, 2016;Wieczorek, 2006;Zeigler et al., 2006), and 30 sets of lunar meteorite sample data (Day et al., 2006;Elardo et al., 2014;Gnos et al., 2004;Greshake et al., 2008;Haloda et al., 2006Haloda et al., , 2009Warren, 1993;Zeigler et al., 2005). These data sets were filtered to include only valid FeO and TiO 2 content data. ...
February 2014
Meteoritics & Planetary Science
... Melt rock 3.879 ± 0.022 Ga (67095,124;Fagan et al., 2013) 67095,125 (this study) 68416 ...
March 2013
... This paper presents a quantitative petrographic method that distinguishes basaltic samples formed through endogenic processes from those formed by impacts using olivine and plagioclase crystal size distributions (CSDs). Comparison of the slopes and y-axis intercepts of these CSDs allows the distinction to be made between the two petrogeneses and builds upon the work of several recent contributions (Oshrin, 2009;Oshrin and Neal, 2009;Hui et al., 2011;Fagan, 2012;O'Sullivan, 2012;Fagan et al., 2013a;and Fagan and Neal, 2012;Donohue, 2013). During these studies, it has been demonstrated that phenocrysts can be distinguished from xenocrysts in impact melts by texture and composition (e.g., Figs. ...
March 2012