Shao-Huan Zhang

Shanghai University, Shanghai, Shanghai Shi, China

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Publications (4)7.79 Total impact

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    ABSTRACT: A total of 175 samples of 18 types of food were collected from markets in Shanghai, China, and the concentrations and bioaccessibility of 15 priority-controlled polycyclic aromatic hydrocarbons (PAHs) in these samples were determined. The mean concentrations of PAHs varied between 2.4 and 47.1 ng g(-1) wet weight, with the highest being observed in snail and lowest in chicken. The concentrations were lower than the maximum levels of PAH allowed for food per EU regulations. Among the PAHs measured, phenanthrene was the predominant one. Most of the PAHs originated from pyrogenic sources, analysed using molecular indices. The mean bioaccessibility of PAHs varied from 29.0% to 61.2% as measured by simulating the human gastrointestinal digestion process. Linear relationships between the bioaccessibility and lipid contents were observed for most PAH congeners. The daily intake of PAHs by an average Shanghai resident was 848 ng day(-1) and decreased to 297 ng day(-1) when the bioaccessibility of PAHs were considered, demonstrating that most intake might have been overestimated. According to the potency equivalent concentrations and screening values of PAHs, consumption of snail and clam, especially snail, should be limited.
    No preview · Article · Jul 2012 · Food Additives and Contaminants - Part A Chemistry, Analysis, Control, Exposure and Risk Assessment
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    ABSTRACT: The investigation of biomagnification of polycyclic aromatic hydrocarbons (PAHs) and endosulfan, an organochlorine pesticide (OCP) and a new persistent organic pollutant, has been limited in freshwater food chains. The objective of the present study was to investigate the levels with focus on the sources and biomagnification of PAHs and OCPs in fish from Taihu Lake, China. In 193 samples of 24 species investigated, the concentrations ranged from 289 to 9 500 ng/g lipid weight (lw) for PAHs, and from 121 to 904 ng/g lw for OCPs, indicating that the fish in the lake was moderately contaminated. The PAHs mainly originated from both unburned petroleum and combustion of fossil fuels, and the OCPs from aged residues. It was unlikely that most of the PAHs and OCPs were biodiluted through the food chain because their trophic magnification factors were higher than one nevertheless the P-values >0.05. Aldrin, dieldrin, p,p'-DDE, p,p'-DDD, and endosulfan sulfate were significantly biomagnified through the food chain.
    Full-text · Article · Jun 2012 · Ecotoxicology and Environmental Safety
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    ABSTRACT: Polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs), two types of persistent organic pollutants that have been used widely, can be released into the environment and accumulate in organisms. To obtain a better understanding of the biomagnification of PBDEs and PCBs in fish, as well as the influences on biomagnification by fish size and physical properties of PBDEs and PCBs, a total of 200 samples of 24 fish species were collected and analyzed from Taihu Lake, the second largest freshwater lake in China. The concentrations of PBDEs and PCBs ranged from 8.59 to 74.28 ng/g lipid weight (lw) and from 10.30 to 165.20 ng/g lw, respectively. Trophic magnification factors (TMFs) were used to estimate the PBDE and PCB biomagnification potentials. The TMF values of PBDEs and PCBs ranged from 0.78 to 2.95 and from 0.92 to 2.60, respectively. Most of the TMFs were greater than 1, indicating that these contaminants were biomagnified in food chains. Fish size might influence the biomagnification evaluation, because different sized fish had different lipid content, leading to different lipid-based concentrations of PBDEs and PCBs. Parabolic relationships were observed between the TMFs and logK(OW) , as well as between the TMFs and the molecular volumes of PBDE and PCB congeners. The congeners with logK(OW) values of approximately 7 or molecular volumes of approximately 8 × 10⁻⁵  nm³ had the greatest biomagnification potentials. Compared to molecular weight, molecular volume seems to be the better standard for analyzing the influence of molecular size on biomagnification.
    No preview · Article · Mar 2012 · Environmental Toxicology and Chemistry
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    ABSTRACT: Levels of polybrominated diphenyl ethers (PBDEs), polychlorinated biphenyls (PCBs), organochlorine pesticides (OCPs), and polycyclic aromatic hydrocarbons (PAHs) in fish and shellfish collected in Taihu Lake, China, were determined. All the chemicals were detected in the samples. The concentrations of PBDEs (31.7 - 4303.3 pg/g) and PCBs (82.4 - 437.7 pg/g) were about two orders of magnitude lower than those of OCPs (1505.8 - 23278.4 pg/g) and PAHs (4062.8 - 22710.0 pg/g). BDE47, CB153, p,p'-DDE, and phenanthrene were predominant for PBDEs, PCBs, OCPs and PAHs, respectively. Compared with other studies in fish and shellfish in China, the contaminant levels were comparable with those of sample in modest contaminated freshwater systems, but much lower than those of fish in highly contaminated water bodies.
    No preview · Article · Jan 2011