Cherno Jaye

Princeton University, Princeton, New Jersey, United States

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Publications (125)

  • Ch Ahrens · J I Flege · C Jaye · [...] · J Falta
    [Show abstract] [Hide abstract] ABSTRACT: The growth of 3, 4, 9, 10-perylene tetracarboxylic dianhydride (PTCDA) on the Ga-polar GaN(0 0 0 1) surface has been studied by x-ray photoelectron spectroscopy (XPS), spot profile analysis low-energy electron diffraction (SPA-LEED), near edge x-ray absorption fine structure (NEXAFS), and scanning tunneling microscopy (STM). The stoichiometric ratios derived from XPS indicate that the molecules remain intact upon adsorption on the surface. Furthermore, no chemical shifts can be observed in the C 1s and O 1s core levels with progressing deposition of PTCDA, suggesting none or only weak interactions between the molecules and the substrate. NEXAFS data indicate the PTCDA molecules being oriented with their molecular plane parallel to the surface. High-resolution STM shows PTCDA islands of irregular shape on the sub-micron scale, and together with corresponding SPA-LEED data reveals a lateral ordering of the molecules that is compatible with the presence of (1 0 2) oriented PTCDA nano-crystals. SPA-LEED moreover clearly shows the presence of homogeneously distributed rotational domains of two-dimensionally isotropic PTCDA.
    Article · Nov 2016 · Journal of Physics Condensed Matter
  • [Show abstract] [Hide abstract] ABSTRACT: It is shown that the self-assembly of diamagnetic molecule submonolayers on a surface can be influenced by magnetic stray field landscapes emerging from artificially fabricated magnetic domains and domain walls. The directed local chemisorption of diamagnetic subphthalocyaninatoboron molecules in relation to the artificially created domain pattern is proved by a combination of surface analytical methods: ToF-SIMS, X-PEEM, and NEXAFS imaging. Thereby, a new method to influence self-assembly processes and to produce patterned submonolayers is presented.
    Article · Oct 2016
  • [Show abstract] [Hide abstract] ABSTRACT: The dramatic colour and phase alteration with the solid-state, temperature-dependent reaction between squaric acid and 4,4'-bipyridine has been probed in situ with X-ray absorption spectroscopy. The electronic and chemical sensitivity to the local atomic environment through chemical shifts in the near-edge X-ray absorption fine structure (NEXAFS) reveals proton transfer from the acid to the bipyridine base through the change in nitrogen protonation state in the high-temperature form. Direct detection of proton transfer coupled with structural analysis elucidates the nature of the solid-state process, with intermolecular proton transfer occurring along an acid-base chain followed by a domino effect to the subsequent acid-base chains leading to the rapid migration along the length of the crystal. NEXAFS thereby conveys the ability to monitor the nature of solid-state chemical reactions in situ, without the need for a priori information or long-range order.
    Article · Aug 2016 · Chemistry - A European Journal
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    [Show abstract] [Hide abstract] ABSTRACT: As a model system to probe ligand-dependent charge transfer in complex composite heterostructures, we fabricated double-walled carbon nanotube (DWNT)-CdSe quantum dot (QD) composites. Whereas the average diameter of the QDs probed was kept fixed at ∼4.1 nm and the nanotubes analyzed were similarly oxidatively processed, by contrast, the ligands used to mediate the covalent attachment between the QDs and DWNTs were systematically varied to include p-phenylenediamine (PPD), 2-aminoethanethiol (AET), and 4-aminothiophenol (ATP). Herein, we have put forth a unique compilation of complementary data from experiment and theory, including results from transmission electron microscopy (TEM), near-edge X-ray absorption fine structure (NEXAFS) spectroscopy, Raman spectroscopy, electrical transport measurements, and theoretical modeling studies, in order to fundamentally assess the nature of the charge transfer between CdSe QDs and DWNTs, as a function of the structure of various, intervening bridging ligand molecules. Specifically, we correlated evidence of charge transfer as manifested by changes and shifts associated with NEXAFS intensities, Raman peak positions, and threshold voltages both before and after CdSe QD deposition onto the underlying DWNT surface. Importantly, for the first time ever in these types of nanoscale composite systems, we have sought to use theoretical modeling to justify and account for our experimental results. Our overall data suggest that (i) QD coverage density on the DWNTs varies, based upon the different ligand pendant groups used and that (ii) the presence of a π-conjugated carbon framework within the ligands themselves coupled with the electron affinity of their pendant groups collectively play important roles in the resulting charge transfer from QDs to the underlying CNTs.
    Full-text available · Article · Jul 2016 · Nanoscale
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    [Show abstract] [Hide abstract] ABSTRACT: The rapid insertion and extraction of Li ions from a cathode material is imperative for the functioning of a Li-ion battery. In many cathode materials such as LiCoO2, lithiation proceeds through solid-solution formation, whereas in other materials such as LiFePO4 lithiation/delithiation is accompanied by a phase transition between Li-rich and Li-poor phases. We demonstrate using scanning transmission X-ray microscopy (STXM) that in individual nanowires of layered V2O5, lithiation gradients observed on Li-ion intercalation arise from electron localization and local structural polarization. Electrons localized on the V2O5 framework couple to local structural distortions, giving rise to small polarons that serves as a bottleneck for further Li-ion insertion. The stabilization of this polaron impedes equilibration of charge density across the nanowire and gives rise to distinctive domains. The enhancement in charge/discharge rates for this material on nanostructuring can be attributed to circumventing challenges with charge transport from polaron formation.
    Full-text available · Article · Jun 2016 · Nature Communications
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    [Show abstract] [Hide abstract] ABSTRACT: Chemical doping has been demonstrated to be an effective method for producing high quality, large area graphene with controlled carrier concentrations and an atomically tailored work function. The emergent optoelectronic properties and surface reactivity of carbon nanostructures are dictated by the microstructure of atomic dopants. Co-doping of graphene with boron and nitrogen offers the possibility to further tune the electronic properties of graphene at the atomic level, potentially creating p- and n-type domains in a single carbon sheet, opening a gap between valence and conduction bands in the 2-D semi-metal. Using a suite of high-resolution synchrotron-based x-ray techniques, scanning tunneling microscopy (STM) and density functional theory (DFT)-based computation we visualize and characterize B-N dopant bond structures and their electronic effects at the atomic level in single layer graphene grown on a copper substrate. We find there is a thermodynamic driving force for B and N atoms to cluster into BNC structures in graphene, rather than randomly distribute into isolated B and N graphitic dopants, although under the present growth conditions, kinetics limit segregation of large B-N domains. We observe that the doping effect of these BNC structures, which open a small band gap in graphene, follows the B: N ratio (B>N, p-type; B<N, n-type; B=N, neutral). We attribute this to the comparable electron withdrawing and donating effects, respectively, of individual graphitic B and N dopants, although local electrostatics also play a role in the work function change.
    Full-text available · Article · Jun 2016 · ACS Nano
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    J S Stevens · A Gainar · C Jaye · [...] · S L M Schroeder
    [Show abstract] [Hide abstract] ABSTRACT: Nitrogen K-edge XPS and NEXAFS of the two polymorphic forms of para- aminobenzoic acid (PABA) are significantly different reflecting variation in hydrogen bonding. Alteration in hydrogen bonding at the amino group leads to a shift to high energy for both the XPS N 1s core level and the 3π* NEXAFS resonance with β-PABA. Participation of the amine group in the aromatic system causes the 1π* resonance to be sensitive to the nature of the intermolecular bonding at the para-carboxylic acid group, and a shift to low energy for α- PABA is observed due to hydrogen-bonded carboxylic acid dimer formation. FEFF calculations also successfully reproduce both the energy and intensity variations observed for the σ* shape resonance associated with the C-N bond, with the majority of the decrease in energy observed for b-PABA arising from the longer C-N bond.
    Full-text available · Article · May 2016 · Journal of Physics Conference Series
  • [Show abstract] [Hide abstract] ABSTRACT: Polydopamine coatings are of interest due to the fact that they can promote adhesion to a broad range of materials and can enable a variety of applications. However, the polydopamine-substrate interaction is often non-covalent. To broaden the potential applications of polydopamine, we show the incorporation of 3-aminopropyltriethoxysilane (APTES), a traditional coupling agent capable of covalent bonding to a broad range of organic and inorganic surfaces, into polydopamine coatings. High energy X-ray photoelectron spectroscopy (HE-XPS), conventional XPS, near-edge X-ray absorption fine structure (NEXAFS), Fourier transform infrared-attenuated total reflectance (FTIR-ATR), and ellipsometry measurements were used to investigate changes in coating chemistry and thickness, which suggest covalent incorporation of APTES into polydopamine. These coatings can be deposited either in Tris buffer or by using an aqueous APTES solution as a buffer without Tris. APTES-dopamine hydrochloride deposition from solutions with molar ratios between 0:1 and 10:1 allowed us to control the coating composition across a broad range.
    Article · Apr 2016 · Langmuir
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    [Show abstract] [Hide abstract] ABSTRACT: A range of different activated carbons was characterized and evaluated for promotion of the oxidative desulfurization (ODS) of JP-8 fuel using H2O2 oxidant and acetic acid. Wood-based carbons activated by acid treatment showed much higher effectiveness than all other carbon types, regardless of source or activation method. Under identical test conditions designed to differentiate material performance, the most effective carbon material yielded 69% oxidation of 2,3-dimethylbenzothiophene (2,3-DMBT) whereas the ineffective materials scarcely out-performed the control (10% oxidation). To understand the characteristics most associated with reaction promotion, the textural, chemical, and defect features of the carbon materials were examined using a battery of techniques. The effective promoters all shared in common high surface areas and high pore volumes; however, surface area and pore volume alone could not explain the observed trends in performance. Investigating surface chemistry, presence of strong acid sites was strongly related to ODS performance. Overall, long-range order was not required for high activity, yet neither were edge defect sites. These results suggest that carbon promotes ODS by formation of percarboxylic acid species at defect sites within the carbon basal planes. Post-reaction analysis of the carbon materials provided evidence to support this explanation.
    Full-text available · Article · Jan 2016
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    Joe E. Baio · Marlene Spinner · Cherno Jaye · [...] · Tobias Weidner
    [Show abstract] [Hide abstract] ABSTRACT: During slithering locomotion the ventral scales at a snake's belly are in direct mechanical interaction with the environment, while the dorsal scales provide optical camouflage and thermoregulation. Recent work has demonstrated that compared to dorsal scales, ventral scales provide improved lubrication and wear protection. While biomechanic adaption of snake motion is of growing interest in the fields of material science and robotics, the mechanism for how ventral scales influence the friction between the snake and substrate, at the molecular level, is unknown. In this study, we characterize the outermost surface of snake scales using sum frequency generation (SFG) spectra and near-edge X-ray absorption fine structure (NEXAFS) images collected from recently shed California kingsnake (Lampropeltis californiae) epidermis. SFG's nonlinear optical selection rules provide information about the outermost surface of materials; NEXAFS takes advantage of the shallow escape depth of the electrons to probe the molecular structure of surfaces. Our analysis of the data revealed the existence of a previously unknown lipid coating on both the ventral and dorsal scales. Additionally, the molecular structure of this lipid coating closely aligns to the biological function: lipids on ventral scales form a highly ordered layer which provides both lubrication and wear protection at the snake's ventral surface.
    Full-text available · Article · Dec 2015 · Journal of The Royal Society Interface
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    [Show abstract] [Hide abstract] ABSTRACT: As a model system for understanding charge transfer in novel architectural designs for solar cells, double-walled carbon nanotube (DWNT)-CdSe quantum dot (QD) (QDs with average diameters of 2.3, 3.0, and 4.1 nm) heterostructures have been fabricated. The individual nanoscale building blocks were successfully attached and combined using a hole-trapping thiol linker molecule, i.e., 4-mercaptophenol (MTH), through a facile, noncovalent stacking attachment strategy. Transmission electron microscopy confirmed the attachment of QDs onto the external surfaces of the DWNTs. We herein demonstrate a meaningful and unique combination of near-edge X-ray absorption fine structure (NEXAFS) and Raman spectroscopies bolstered by complementary electrical transport measurements in order to elucidate the synergistic interactions between CdSe QDs and DWNTs, which are facilitated by the bridging MTH molecules that can scavenge photoinduced holes and potentially mediate electron redistribution between the conduction bands in CdSe QDs and the C 2p-derived states of the DWNTs. Specifically, we correlated evidence of charge transfer as manifested by (i) changes in the NEXAFS intensities of resonance in the C K-edge and Cd M3-edge spectra, (ii) a perceptible outer tube G-band downshift in frequency in Raman spectra, as well as (iii) alterations in the threshold characteristics present in transport data as a function of CdSe QD deposition onto the DWNT surface. In particular, the separate effects of (i) varying QD sizes and (ii) QD coverage densities on the electron transfer were independently studied.
    Full-text available · Article · Nov 2015 · The Journal of Physical Chemistry C
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    Adrian Gainar · Joanna Sarah Stevens · Cherno Jaye · [...] · Sven L M Schroeder
    [Show abstract] [Hide abstract] ABSTRACT: Detailed analysis of the C K near-edge X-ray absorption fine structure (NEXAFS) spectra of a series of saccharides (fructose, xylose, glucose, galactose, maltose monohydrate, α-lactose monohydrate, anhydrous β-lactose, cellulose) indicates that the precise determination of IPs and σ* shape resonance energies is sensitive enough to distinguish different crystalline saccharides through the variations in their average C-OH bond lengths. Experimental data as well as FEFF8 calculations confirm that bond length variations in the organic solid state of 10─2 Å can be experimentally detected, opening up the possibility to use NEXAFS for obtaining incisive structural information for molecular materials, including non-crystalline systems without long-range order such as dissolved species in solutions, colloids, melts and similar amorphous phases. The observed bond length sensitivity is as good as that originally reported for gas phase and adsorbed molecular species. NEXAFS-derived molecular structure data for the condensed phase may therefore be used to guide molecular modelling as well as to validate computationally derived structure models for such systems. Some results indicate further analytical value, in that the σ* shape resonance analysis may distinguish hemiketals from hemiacetals (i.e. derived from ketoses and aldoses), as well as α from β forms of otherwise identical saccharides.
    Full-text available · Article · Oct 2015 · The Journal of Physical Chemistry B
  • Joanna S. Stevens · Adrian Gainar · Cherno Jaye · [...] · Sven L. M. Schroeder
    [Show abstract] [Hide abstract] ABSTRACT: Nitrogen K-edge XPS and NEXAFS of the two polymorphic forms of para-aminobenzoic acid (PABA) are significantly different reflecting variation in hydrogen bonding. Alteration in hydrogen bonding at the amino group leads to a shift to high energy for both the XPS N 1s core level and the 3p* NEXAFS resonance with b-PABA. Participation of the amine group in the aromatic system causes the 1p* resonance to be sensitive to the nature of the intermolecular bonding at the para-carboxylic acid group, and a shift to low energy for a-PABA is observed due to hydrogen-bonded carboxylic acid dimer formation. FEFF calculations also successfully reproduce both the energy and intensity variations observed for the s* shape resonance associated with the C-N bond, with the majority of the decrease in energy observed for b-PABA arising from the longer C-N bond.
    Conference Paper · Aug 2015
  • [Show abstract] [Hide abstract] ABSTRACT: In this paper, we examine the effects of excessive sonication during surfactant-assisted multiwall carbon nanotubes (MWCNT) dispersion in ethylene vinyl acetate (EVA) by way of monitoring molecular arrangements upon progressive straining. Aberration-corrected transmission electron microscopy confirms the structural damage on the graphitic layers upon prolonged sonication. The resulting lack on MWCNT alignment is shown by atomic force microscopy. Further, molecular interface dynamics in progressively strained EVA|MWCNT composites have been studied through Raman and NEXAFS spectroscopies. NEXAFS spectra have identified graphitic amorphization and further C-vacancy rehybridization by way of hydrogen passivation as the damage mechanism to the graphitic structure upon sonication. In this scheme, MWCNTs did not align despite the range of composite strains discussed due to stick and slip dynamics of surrounding EVA. Ultimately, damaged MWCNTs rendered the necessary dispersant π–π interactions suboptimal and insufficient for nanomechanically interlocked polymer–filler interactions. Remarkably, upon large strains, polymer chains are seen to unlatch from the MWCNT and undergo mechanically induced backbone twisting. The possibility of mechanically induced backbone twisting might offer alternative processing routes in photovoltaic systems, where chemically induced conjugated backbone twisting yields increased power conversion efficiency.
    Article · Aug 2015 · The Journal of Physical Chemistry C
  • [Show abstract] [Hide abstract] ABSTRACT: Interfacing graphene with metal oxides is of considerable technological importance for modulating carrier density through electrostatic gating as well as for the design of earth-abundant electrocatalysts. Herein, we probe the early stages of the atomic layer deposition (ALD) of HfO2 on graphene oxide using a combination of C and O K-edge near-edge X-ray absorption fine structure spectroscopies and X-ray photoelectron spectroscopy. Dosing with water is observed to promote defunctionalization of graphene oxide as a result of the reaction between water and hydroxyl/epoxide species, which yields carbonyl groups that further react with migratory epoxide species to release CO2 . The carboxylates formed by the reaction of carbonyl and epoxide species facilitate binding of Hf precursors to graphene oxide surfaces. The ALD process is accompanied by recovery of the π-conjugated framework of graphene. The delineation of binding modes provides a means to rationally assemble 2D heterostructures. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
    Article · Jul 2015 · ChemPhysChem
  • Allen Douglas Winter · Eduardo Larios · Cherno Jaye · [...] · Eva M. Campo
    Chapter · Jul 2015
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    File available · Data · Jun 2015
  • [Show abstract] [Hide abstract] ABSTRACT: Graphene (Gr)–polystyrene (PS) and graphene (Gr)–ultra-high molecular weight polyethylene (UHMW PE) laminates were fabricated using a transfer print approach that relies on differential adhesion to remove graphene from Cu foil without chemical etching. The polymer surfaces were prepared using plasma functionalization followed by N-ethylamino-4-azidotetrafluorobenzoate (TFPA) deposition. Then, the graphene on Cu foil and the TFPA coated polymers were pressed at elevated temperature and mild pressure. Finally, they were separated by mechanical peeling. No additional processing was applied. Detailed chemical, structural, and morphological characterization of PS and UHMW PE before and after graphene transfer print was performed using a suite of complementary surface analysis techniques including X-ray Photoelectron Spectroscopy (XPS), Near Edge X-ray Absorption Fine Structure Spectroscopy (NEXAFS), Raman Spectroscopy, and Atomic Force Microscopy (AFM). The charge carrier density and charge carrier mobility of the transferred graphene were determined using Hall effect measurements. We found that graphene’s electrical properties were preserved and comparable to those of graphene on SiO2/Si. Furthermore, modulation of TFPA attachment to PS and UHMW PE led to different TFPA-layer microstructure and therefore to a different amount of functional azide groups available to form carbene bonds with graphene causing changes in graphene’s compressive strain, doping and mobility.
    Article · May 2015 · Carbon
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    [Show abstract] [Hide abstract] ABSTRACT: X-ray emission spectroscopy (XES) is a powerful element-selective tool to analyze the oxidation states of atoms in complex compounds, determine their electronic configuration, and identify unknown compounds in challenging environments. Until now the low efficiency of wavelength-dispersive X-ray spectrometer technology has limited the use of XES, especially in combination with weaker laboratory X-ray sources. More efficient energy-dispersive detectors have either insufficient energy resolution because of the statistical limits described by Fano or too low counting rates to be of practical use. This paper updates an approach to high-resolution X-ray emission spectroscopy that uses a microcalorimeter detector array of superconducting transition-edge sensors (TESs). TES arrays are discussed and compared with conventional methods, and shown under which circumstances they are superior. It is also shown that a TES array can be integrated into a table-top time-resolved X-ray source and a soft X-ray synchrotron beamline to perform emission spectroscopy with good chemical sensitivity over a very wide range of energies.
    Full-text available · Article · May 2015 · Journal of Synchrotron Radiation
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    [Show abstract] [Hide abstract] ABSTRACT: A two-step method consisting of solid-state microwave irradiation and heat treatment under NH3 gas was used to prepare nitrogen-doped reduced graphene oxide (N-RGO) with a high specific surface area (1007 m(2) g(-1) ), high electrical conductivity (1532 S m(-1) ), and low oxygen content (1.5 wt %) for electrical double-layer capacitor applications. The specific capacitance of N-RGO was 291 F g(-1) at a current density of 1 A g(-1) , and a capacitance of 261 F g(-1) was retained at 50 A g(-1) , which indicated a very good rate capability. N-RGO also showed excellent cycling stability and preserved 96 % of the initial specific capacitance after 100 000 cycles. Near-edge X-ray absorption fine-structure spectroscopy results provided evidenced for the recovery of π conjugation in the carbon networks with the removal of oxygenated groups and revealed chemical bonding of the nitrogen atoms in N-RGO. The good electrochemical performance of N-RGO is attributed to its high surface area, high electrical conductivity, and low oxygen content. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
    Full-text available · Article · Apr 2015 · ChemSusChem

Publication Stats

2k Citations


  • 2011
    • Princeton University
      • Department of Electrical Engineering
      Princeton, New Jersey, United States
  • 2010
    • University of Houston
      • Department of Electrical & Computer Engineering
      Houston, Texas, United States
  • 2004
    • North Carolina State University
      • Department of Physics
      Raleigh, North Carolina, United States