Synthetic Studies on the Taxane Skeleton: Construction of Eight-Membered Carbocyclic Rings by the Intramolecular B -Alkyl Suzuki−Miyaura Cross-Coupling Reaction
Construction of eight-membered carbocyclic rings via the intramolecular B-alkyl Suzuki-Miyaura cross-coupling reaction has been studied. This protocol proved its potency through the formation of the eight-membered ring possessing a quaternary carbon on its ring in high yield, affording promise of a new access to the eight-membered ring of Taxol. [reaction: see text]
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