Asymmetric Synergy Between Chiral Dienes and Diphosphines in Cationic Rh(I)-Catalyzed Intramolecular [4 + 2] Cycloaddition
High enantioselective [4 + 2] cycloaddition can be achieved by cationic Rh complexes bearing not only chiral phosphine but also chiral diene. This is the first example of asymmetric synergy between chiral dienes and diphosphines.
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