Dioxygen binding of water-soluble iron(II) porphyrins in phosphate buffer at room temperature

Université de Rennes1, Sciences Chimiques de Rennes, UMR CNRS 6226 (I.C.M.V.), 35042, Rennes Cedex, France.
Organic & Biomolecular Chemistry (Impact Factor: 3.56). 06/2007; 5(10):1601-4. DOI: 10.1039/b702998e
Source: PubMed


Two water-soluble tris(2-aminoethylamine) (tren) capped iron porphyrins were synthesized. The stability of their dioxygen adducts was studied in phosphate buffer, leading to half-life times around 7 min for the oxygenated species.

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Available from: Christian Ruzié, Aug 21, 2014