A well-defined silica-supported dinuclear tungsten(III) amido species: synthesis, characterization and reactivity

Unité de Catalyse et de Chimie du Solide, UMR 8181 CNRS, ENSCL, BP 90108, 59652 Villeneuve d'Ascq Cedex, France.
Dalton Transactions (Impact Factor: 4.2). 09/2007; DOI: 10.1039/b708356b
Source: PubMed


Grafting of [W(2)(NMe(2))(6)] onto dehydroxylated silica affords the well-defined surface species [([triple bond, length as m-dash]Si-O)W(2)(NMe(2))(5)], characterized by elemental analysis, and infrared, Raman and NMR spectroscopies, and the catalytic reactivity of this supported tungsten(III) d(3)-d(3) dimer and of its alkoxide derivatives towards alkynes has been probed.

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