ChemInform Abstract: Iridium Terpyridine Complexes as Functional Assembling Units in Arrays for the Conversion of Light Energy

ArticleinAccounts of Chemical Research 41(7):857-71 · July 2008with19 Reads
Impact Factor: 22.32 · DOI: 10.1021/ar700282n · Source: PubMed


    In photosynthesis, sunlight energy is converted into a chemical potential by an electron transfer sequence that is started by an excited state and ultimately yields a long-lived charge-separated state. This process can be reproduced by carefully designed multicomponent artificial arrays of three or more components, and the stored energy can be used to oxidize or reduce molecules in solution, to inject electrons or holes, or to create an electron flow. Therefore, the process is important both for artificial-photosynthesis research and for photovoltaic and optoelectronic applications. Molecular arrays for photoinduced charge separation often use chromophores that resemble the natural ones. However, new synthetic components, including transition metal complexes, have had some success.