Article

Aqua-{N,N-dimethyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II).

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
Acta Crystallographica Section E Structure Reports Online (Impact Factor: 0.35). 04/2011; 67(Pt 4):m513. DOI: 10.1107/S1600536811011512
Source: PubMed

ABSTRACT

In the title compound, [Ni(NCS)(2)(C(11)H(17)N(3))(H(2)O)], the Ni(II) ion is six-coordinated by the N,N',N"-tridentate Schiff base N atoms, two cis-positioned N-bound isothio-cyanate groups and one water mol-ecule. In the crystal, O-H⋯S hydrogen bonds link adjacent mol-ecules into infinite layers parallel to the ac plane. The layers are further connected into a three-dimensional network via C-H⋯π inter-actions. The -CH(2)-N(CH(3))(2) fragment is disordered over two sets of sites in a 0.556 (5):0.444 (5) ratio.

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