{2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-d imethylformamide)copper(II) bis(hexafluoridoantimonate)

Fakultät Chemie, Technische Universität Dortmund, Otto-Hahn-Strasse 6, 44221 Dortmund, Germany.
Acta Crystallographica Section E Structure Reports Online (Impact Factor: 0.35). 07/2009; 65(Pt 7):m737. DOI: 10.1107/S1600536809020364
Source: PubMed


In the title compound, [Cu(C(17)H(30)N(2)O(2))(C(3)H(7)NO)(2)][SbF(6)](2), which is a potential catalyst in the asymmetric Gosteli-Claisen rearrangement, the Cu atom adopts a distorted cis-CuN(2)O(2) square-planar geometry arising from N,N'-bidentate coordination by the chiral ligand and two O-bonded dimethylformamide molecules. Two short C-H center dot center dot center dot O contacts occur within the ligand and two weak intermolecular C-H center dot center dot center dot F bonds may help to establish the packing.

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