Available via license: CC BY
Content may be subject to copyright.
Article Not peer-reviewed version
Thermal Deformation Behavior and
Consitutive Equation of Uranium-
50wt.%Zirconium Nuclear Fuel
Yanfeng Li * , Guo Hong , Li Mingyang , Hu Bingkun , Liu Jiancheng
Posted Date: 30 September 2024
doi: 10.20944/preprints202409.2394.v1
Keywords: U-50wt.%Zr metallic fuel; hot compression deformation; constitutive equation; hot working
diagram
Preprints.org is a free multidiscipline platform providing preprint service that
is dedicated to making early versions of research outputs permanently
available and citable. Preprints posted at Preprints.org appear in Web of
Science, Crossref, Google Scholar, Scilit, Europe PMC.
Copyright: This is an open access article distributed under the Creative Commons
Attribution License which permits unrestricted use, distribution, and reproduction in any
medium, provided the original work is properly cited.
Article
Thermal Deformation Behavior and Consitutive
Equation of Uranium-50wt.%Zirconium Nuclear Fuel
Li Yanfeng 1, Guo Hong 2,*, Li Mingyang 3, Hu Bingkun 4 and Liu Jiancheng 5
1 CNNC North Company; 66525850@qq.com
2 Chief Expert of CNNC North Company;
3 Deputy Director of the Laboratory of Depleted Uranium
4 Technician of the Laboratory of Depleted Uranium
5 Director of the Laboratory of Depleted Uranium
* Correspondence: yystcsys@cnnfc202.com; Tel.: +086-18686163441
Abstract: In order to study the thermal deformation behavior of uranium-50wt.%zirconium, used
Gleeble 3800 thermal simulation testing machine to carry out compression deformation experiments
at different temperatures for this material. The effects of deformation temperature and strain rate
on the alloy were studied. The results show that the peak stress of U-50wt.%Zr metallic fuel
decreases with the increase of deformation temperature after thermal deformation at 500°C~600°C,
especially at 600°C compared with that at 500°C and 550°C. At the same temperature, the peak stress
increases with the increase of strain rate, especially the peak stress at strain rate 0.1s-1 and 1s-1 is
significantly higher than that at strain rate 0.01s-1, and then the microstructure and diffraction results
of U-50wt.%Zr metal-type fuel after thermal deformation are compared and analyzed, and the
Arrhenius-type constitutive equation and thermal proces550℃,έ=1s-1 diagram of U-50wt.%Zr
metal-type fuel are established based on the peak stress.
Keywords: U-50wt.%Zr metallic fuel; hot compression deformation; constitutive equation; hot
working diagram
1. Introduction
There are two major types of fast reactor fuel forms used internationally: ceramic fuel and metal
fuel. Metal fuel is characterized by high thermal conductivity, low fuel temperature, and high safety
margin. Research and development of metal fuel mainly focus on U-Zr alloy and U-Pu-Zr alloy,
which are widely used in reactors. Advanced technology fuel (ATF) helps to increase the heat transfer
rate and reduce the stored energy in the reactor core. For the use of light water reactors (LWR), the
design goal is to develop a high thermal conductivity fuel alternative to the currently used uranium
dioxide (UO2) ceramic fuel form in LWR. Although UO2 has many attractive characteristics as nuclear
fuel, its biggest drawback is its extremely low thermal conductivity. Therefore, when the fuel operates
at high temperatures, it requires a significant amount of time to remove the residual heat after the
reactor shutdown. This can be a particularly prominent issue in the event of core cooling failure.
Therefore, there is a strong incentive to develop high thermal conductivity fuels. Generally, metal
alloy fuels have excellent thermal properties. However, irradiation of metal fuels often leads to severe
volume expansion and significant release of fission gases. In these aspects, U-50wt.%Zr alloy stands
as an exception. This specific alloy, U-50wt.%Zr, exists in a δ-UZr2 phase structure below 600℃.
Utilizing the δ-UZr2 phase, a high thermal conductivity nuclear fuel form can be developed that
operates at low temperatures (below 600℃) and can easily remove residual heat. Adopting this fuel
form in commercial LWR systems will enhance the safety threshold and reduce the likelihood of
serious accidents due to insufficient fuel cooling. Currently, the failure mode impact and analysis for
LWR is based on limited performance data from UO2 fuel in LWR and the metal fuel form U-
10wt.%Zr used in sodium-cooled fast reactors. However, knowledge about U-50wt.%Zr fuel is
Disclaimer/Publisher’s Note: The statements, opinions, and data contained in all publications are solely those of the individual author(s) and
contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting
from any ideas, methods, instructions, or products referred to in the content.
Preprints.org (www.preprints.org) | NOT PEER-REVIEWED | Posted: 30 September 2024 doi:10.20944/preprints202409.2394.v1
© 2024 by the author(s). Distributed under a Creative Commons CC BY license.
2
insufficient for failure mode impact and quantitative analysis. Therefore, studying the model of
temperature, stress, and strain distribution of U-50wt.%Zr alloy over time is crucial for evaluating
the reliability of metal fuel performance and accelerating the engineering application of new nuclear
fuel technologies—e.g., [1].
Internationally, in order to safely and effectively utilize the U-Zr alloy system as nuclear fuel,
extensive research has been conducted on its phase stability and microstructure across various
temperatures and compositions. Depending on temperature and composition, the U-Zr alloy system
exhibits a multitude of stable intermetallic phases. Specifically, U-10wt.%Zr fuel comprises a dual-
phase structure of orthorhombic α-U and hexagonal δ-UZr2, while U-80wt.%Zr features a dual-phase
structure of hexagonal α-Zr and δ-UZr2. U-50wt.%Zr metal-type fuel can achieve a δ-UZr2 structure.
In response to the δ-UZr2 structure, the Idaho National Laboratory has conducted research on various
thermophysical and mechanical properties of as-cast U-50wt.%Zr metal-type fuel, including phase
transition temperature, thermal diffusivity, specific heat, thermal expansion, thermal conductivity,
hardness, elastic modulus, yield strength, and preliminary creep rate—e.g., [2]. The study found that
compared to other U-Zr alloy systems, the δ-UZr2 structure exhibits very small volume expansion
and fission gas release. The quantitative results of this study are shown in Table 1 below, with the
last row of data (sample Zr1) corresponding to the δ-UZr2 phase sample —e.g., [3].
Table 1. Fission gas release (FGR) and volumetric swelling data for various U-Zr alloys ir radiated at
approximately 600℃.
sample
at% Zr
FGR/%
ΔV/V/(%)
Zr12 alloy
30
7.7
40
Zr14 alloy
30
7.2
46
Zr6
10
9.7
61
Zr7
30
12.5
67
Zr10 alloy
30
10.5
42
Zr5 alloy
10
15.7
—
Zr1(δ-UZr
2
)
70
0.02
3
The degree of fission gas release and volume expansion in δ-UZr2 samples is significantly lower
than that exhibited by other U-Zr compositions. Due to its excellent thermal conductivity and low
expansion rate, it is being considered as a nuclear fuel for sodium-cooled fast reactors—e.g.,[4]. In
fast reactors, nuclear fuel operates in an environment of high neutron flux (>1015 n/cm2) and stress
(100MPa) at peak cladding temperatures (600℃). In this environment, various thermomechanical
phenomena such as cladding thermal creep, nuclear fuel expansion, and thermomechanical effects
on the core and cladding occur. At the same time, metal fuel is subjected to extreme conditions such
as compressive deformation and large temperature gradients in the reactor, which can lead to
complex thermal deformation of the fuel. This deformation can affect fuel performance—e.g., [5].
Therefore, optimizing the processing technology of nuclear fuel is of great significance for the
operation and design of reactors. In order to prepare samples of different sizes, it is necessary to
explore pressure processing techniques, but there are few research reports on the rheological stress
of U-50wt.%Zr metal-type fuel during thermal compression.
This article utilizes the Gleeble3800 thermal simulator to conduct thermal compression tests on
δ-UZr2 samples of U-50wt.%Zr metallic fuel. It analyzes the effects of temperature and strain rate on
its true stress-true strain curve, studies the thermal deformation behavior and microstructure of the
samples after thermal deformation, and establishes the constitutive equation and thermal processing
diagram of the δ-UZr2 phase of U-50wt.%Zr metallic fuel.
2. Materials and Methods
1.1. Experimental Materials
Preprints.org (www.preprints.org) | NOT PEER-REVIEWED | Posted: 30 September 2024 doi:10.20944/preprints202409.2394.v1
3
Under vacuum, U-50wt.%Zr (U-72at%Zr) metal-type fuel was prepared using high-frequency
induction melting furnace, utilizing metal uranium and zirconium metal with a purity of 99.9%.
Figure 1 shows the crucible system of the high-frequency induction furnace, the ingot after melting,
and the cut-open ingot. From the figure, it can be observed that the ingot exhibits metallic luster,
indicating good melting. The ingot after melting was cut open along the diameter direction.
Figure 1. High-frequency induction furnace used for casting U-50wt.%Zr metal fuel, along with
photos of the melting ingot and its cross-sectional and longitudinal cuts.
1.2. Test Method
This experiment conducted a hot compression test on U-50wt.%Zr metallic fuel using a
Gleeble3800 thermal simulator to study the hot deformation behavior of U-50wt.%Zr at temperatures
ranging from 500℃ to 600℃. The upper end of the ingot was cut into a cylinder by wire cutting and
machined into a φ6×10mm cylindrical specimen, as shown in Figure 2. A K-type thermocouple was
welded at the center of the side surface of the cylindrical sample for measurement and temperature
control. Subsequently, graphite sheets were placed on both ends of the sample and coated with high-
temperature lubricant before being installed in the middle of the equipment ram to reduce the effect
of friction. The hot compression rheological stress behavior under the conditions of a strain rate of
0.01s-1 ~1s-1 and a true strain of 0.2 was investigated. The hot compression test process is shown in
Figure 3. First, the test was conducted using a heating rate of 5℃/s and held for 60s to ensure stable
internal temperature of the specimen. The entire test was carried out under a vacuum degree of less
than 50Pa, and the sample was cooled in the furnace after the test.
The microstructure morphology of the ingot before and after compression was observed using
an Olympus metallurgical microscope and a VEGA 3 XMUX scanning electron microscope.
The D8 ADVANCE XRD diffractometer was used to determine the phase of the alloy before and
after ingot compression, with a voltage of 40kV, current of 40mA, step size of 0.02º, and scanning
range of 20-90º.
Figure 2. U-50wt.%Zr alloy processed into a cylindrical for sample of Φ6×10mm.
Preprints.org (www.preprints.org) | NOT PEER-REVIEWED | Posted: 30 September 2024 doi:10.20944/preprints202409.2394.v1
4
Figure 3. Schematic diagram isothermal compression of test simple.
3. Results
2.1. Microstructure of U-50wt.%Zr Metallic Fuel Prepared
Before the experiment, scanning electron microscopy (SEM) and X-ray diffraction (XRD) tests
were conducted on the U-50wt.%Zr metal-type fuel ingot. Figure 4 shows the SEM and XRD
diffraction results, and the energy spectrum results indicate that the Zr content is 49.59wt.%. Figure
5 shows the metallographic photograph of U-50wt.%Zr metal-type fuel. No undissolved substances
were observed in the sample. The XRD results show that the phase of U-50wt.%Zr metal-type fuel is
UZr2, which is identified as δ phase based on the phase diagram.
Figure 4. Scanning Electron Microscope (SEM) and XRD testing results of U-50wt.%Zr metal-type fuel
ingots.
100× 200×
Figure 5. Metallographic examination results of U-50wt.%Zr metal-type fuel ingots.
2.2. Analysis of True Stress-True Strain Curve of U-50wt.%Zr Metal Fuel during Thermal Deformation
The true stress-true strain data obtained from the experiment were processed to obtain the true
stress-true strain relationship curves at different temperatures under various strain rates, as shown
Preprints.org (www.preprints.org) | NOT PEER-REVIEWED | Posted: 30 September 2024 doi:10.20944/preprints202409.2394.v1
5
in Figure 6. It can be observed from the figure that the deformation temperature, strain rate, and true
strain have a significant impact on the rheological stress of the sample. In the initial stage of thermal
deformation, the rheological stress increases rapidly with the increase of true strain. During this
deformation stage, as the true strain increases, dislocations proliferate rapidly, and a large number
of dislocations entangle and accumulate with each other, leading to a significant increase in work
hardening. Therefore, the work hardening mechanism is the main reason for the increase in
rheological stress in the initial stage of thermal deformation—e.g., [6,7].
At the same strain rate, the peak stress decreases with increasing deformation temperature. The
peak stress reaches a maximum of 740MPa at deformation temperatures of 500℃ and 550℃, while it
is around 200MPa at 600℃. As shown in Figure 6(a), the peak stress at a strain rate of 0.01 s-1
decreases by 10% at 550℃ compared to 500℃, and decreases by 59% at 600℃ compared to 550℃. As
shown in Figure 6(b), the peak stress at a strain rate of 0.1 s-1 decreases by 24% at 550℃ compared to
500℃, and decreases by 54% at 600℃ compared to 550℃. As shown in Figure 6(c), the peak stress at
a strain rate of 1 s-1 decreases by 25% at 550℃ compared to 500℃, and decreases by 44% at 600℃
compared to 550℃. From the above results, it can be seen that there is only a 50℃ difference between
550℃ and 600℃, but the peak stress difference is about 50%. Therefore, the U-50wt.%Zr metal-type
fuel should undergo microstructural changes at 600℃.
(a)έ=0.01s-1
(b)έ=0.1s-1
Preprints.org (www.preprints.org) | NOT PEER-REVIEWED | Posted: 30 September 2024 doi:10.20944/preprints202409.2394.v1
6
(c)έ=1s-1
Figure 6. True stress-strain curves of U-50wt.%Zr metal fuel under different temperatures and strain
rates.
Under the same deformation temperature, the peak stress increases with the increase of strain
rate. At 500℃, the peak stress at a strain rate of 1s-1 increased by 48% compared to that at a strain
rate of 0.01s-1. At 550℃, the peak stress at a strain rate of 1s-1 increased by 24% compared to that at
a strain rate of 0.01s-1. At 600℃, the peak stress at a strain rate of 1s-1 increased by 68% compared to
that at a strain rate of 0.01s-1. From the above results, it can be seen that the peak stress increases
significantly with the increase of strain rate, mainly due to the sufficient time for dynamic
recrystallization of U-50wt.%Zr metal fuel during thermal deformation, resulting in a significant
decrease in peak stress at a strain rate of 0.01s-1 compared to that at strain rates of 0.1s-1 and 1s-1.
Based on the above analysis, it can be observed that the thermal deformation behavior of U-
50wt.%Zr metal-type fuel at 600℃ with a strain rate of 0.01s-1 exhibits significant dynamic
recrystallization. However, at 500℃ and 550℃ with higher strain rates, the dynamic recrystallization
phenomenon is not evident, and the thermal deformation behavior is dominated by work hardening.
Therefore, the true stress-strain curve of U-50wt.%Zr metal-type fuel can be divided into two types:
one is the dynamic recrystallization type curve, as shown in the true stress-strain curves at different
strain rates at 600℃ in the figure. Specifically, as the true strain increases, the flow stress gradually
decreases until reaching a steady-state stress. This phenomenon weakens with an increase in strain
rate. When the strain rate is 1s-1, the time of dynamic softening effect is shortened, and the stress
curve exhibits severe fluctuations. The other type is the work hardening type curve, as shown in the
true stress-strain curves at different strain rates at 500℃ and 550℃. The true stress increases with the
increase of strain, showing an overall work hardening state without reaching steady-state flow.[8,9]
Figure 7 illustrates the 3D peak stress diagram of U-50wt.%Zr metal fuel under various
deformation conditions. It can be observed that the peak stress decreases with increasing temperature
and decreases with decreasing strain rate.
Preprints.org (www.preprints.org) | NOT PEER-REVIEWED | Posted: 30 September 2024 doi:10.20944/preprints202409.2394.v1
7
Figure 7. 3D peak stress diagram of U-50wt.%Zr metal fuel under different deformation conditions.
2.3. Microstructural Analysis of U-50wt.%Zr Metal-Type Fuel
Metallographic examination was conducted on the cross-section of the deformed area of the
thermally compressed sample. The results are shown in Figure 8. It was observed from the figure that
under the same strain rate conditions, the thermal deformation temperature had an impact on its
metallographic microstructure. At strain rates of 0.1s-1 and 1s-1, the grain size changes were not
significant at 500℃ and 550℃, with grain sizes around 250μm. At 600℃, the grain size reached
493μm, indicating grain growth after thermal deformation at this temperature. As the strain rate
increased, there were no significant changes in the shape and structure of the grain boundaries and
grains of U-50wt.%Zr metal-type fuel at the same temperature.
(a)500℃,έ=0.1s-1
(b) 500℃,έ=1s-1
Preprints.org (www.preprints.org) | NOT PEER-REVIEWED | Posted: 30 September 2024 doi:10.20944/preprints202409.2394.v1
8
Figure 8. Metallographic images (200×) of U-50wt.%Zr metal fuel after thermal deformation at
different temperatures.
The samples after the experiment were subjected to X-ray diffraction testing, and their phases
were identified through a database. The phase results of U-50wt.%Zr metal-type fuel subjected to
compression experiments at different strain rates and temperatures are shown in Figure 9. After
thermal deformation, the U-50wt.%Zr metal-type fuel maintains the UZr2 phase, which is known as
the δ phase according to the phase diagram —e.g., [10]. After thermal deformation at 500℃, 550℃,
and 600℃, the U-50wt.%Zr metal-type fuel is in the δ-UZr2 phase.
(a)έ=0.01s
-1
(b)έ=0.1s
-1
(c)έ=1s
-1
Figure 9. XRD results of U-50wt.%Zr alloy after thermal deformation at different temperatures.
2.4. Construction of Arrhenius Constitutive Equation for U-50wt.%Zr Metal-Type Fuel
Based on the results of the hot deformation test, the relationship between peak stress, strain rate,
and temperature of U-50wt.%Zr metal-type fuel was fitted using the Arrhenius equation. The study
focused on the relationship between temperature, deformation rate, and deformation resistance of U-
50wt.%Zr metal-type fuel within a strain rate range of 0.01~1s-1 —e.g., [11–14].
=AF()exp (
) (1)
In the formula: represents the strain rate, s-1; Ais a constant; F()is a function related to ;
Qdenotes the activation energy for thermal deformation, J/mol; represents the Rgas constant, which
is 8.314J/(mol·K); Tstands for the thermodynamic temperature, K; and represents the peak stress,
MPa.
F()=
; < 1.2
exp() ; > 1.2
[sinh ()]
;
(2)
(c)550℃,έ=0.1s-1 (d) 550℃,έ=1s-1
(e)600℃,έ=0.1s-1 (f) 600℃,έ=1s-1
Preprints.org (www.preprints.org) | NOT PEER-REVIEWED | Posted: 30 September 2024 doi:10.20944/preprints202409.2394.v1
9
In the formulan, n, , and are constants, where=
。
Taking the natural logarithm on both sides of equation (1), we can obtain equations (3), (4), and
(5) after rearranging.
ln=lnA+ nln
Q
RT
(3)
ln=lnA+
Q
RT
(4)
ln=lnA
+nln[sinh()]
Q
RT
(5)
Where AA, and Aare constants.
Assuming that the peak stress, strain rate, and temperature have lnminimal influence on the
activation energy of thermal deformation and remain constantlnln [sinh()], it can be observed
from equations (3) and (4) that if we use lnand as the horizontal coordinates and as the vertical
coordinate for fitting, and employ the least squares method for linear regression to determine the
slope of the straight line, we can obtain and. As shown in Figures 10(a) and (b), by calculating the
average values of the slopes of the fitted straight lines, we obtain n=13.6035, =0.03215, and =
=0.00236. Substituting the values of into equation (5) and performing a linear fitting, as shown in
Figure 10(c). Zener and Hollomon proposed a Zparametric equation that can be used to represent the
relationship between the strain rate and temperature during high-temperature plastic deformation
of materials, as shown in equation (6). [15]
Z = exp
Q
RT
= A[sinh ()] (6)
Taking the natural logarithm of both sides of equation (6) and rearranging, we obtain equation
(7).
ln[sinh()] =
Q
1000nR
·
1000
T
+
ln
n
lnA (7)
From equation (7), it can be observed that under a constant strain rate
ln[sinh()]
,
a linear fit can be applied to Q, with the slope representing the nvalue of. Through further
calculations, the thermal deformation activation energy can be determined. The slope of the straight
line in Figure 10(d) Qis, and its average value is 9.8638. The average slope of the three fitted straight
lines is 8.4734, and the thermal deformation activation energy is calculated to be 694.9 kJ/mol.
(a) lnέ-
(b) lnέ-ln
Preprints.org (www.preprints.org) | NOT PEER-REVIEWED | Posted: 30 September 2024 doi:10.20944/preprints202409.2394.v1
10
(c) lnέ-ln[sinh()] (d) ln[sinh()]
Figure 10. The relationship between strain rate and peak strain under different temperature
conditions.
Taking the natural logarithm of both sides of equation (6) and rearranging, we can obtain
equation (8).
lnZ =lnA +nln
[
sinh
(
)]
(8)
Substitute the corresponding strain rate, temperature, and thermal deformation activation
energy into equation (6) Zto calculate the corresponding values, and then lnZ ln[sinh()]perform
fitting. The slope nof the fitted line is , and the intercept of the line with the vertical axis is lnA.
The slope Aof the fitted straight line in Figure 11 is 8.9236, with an intercept of 97.527 and a
lnZ ln[sinh()]fitted value of 8.9236. The ncalculated value is 2.267×10^42.
Figure 11. The relationship between lnZ ln[sinh()].
By Rsubstituting n , , A,Qand into formula (1), we can obtain the constitutive equation (9) for
U-50wt.%Zr metal-type fuel.
= 2.267 ×10[sin (0.00236 ×)].exp
83579.923
T
(9)
By varying (9), we can obtain the relationship between peak stress, temperature, and strain rate
(10).
Preprints.org (www.preprints.org) | NOT PEER-REVIEWED | Posted: 30 September 2024 doi:10.20944/preprints202409.2394.v1
11
=1
0.00236 ln Z
2.267 ×10
.
+Z
2.267 ×10
.+ 1
(10)
Among them:
Z =έ exp .×
To verify the accuracy of the constitutive equation, the experimental results obtained under
different temperatures and strain rates were substituted into equation (10) to theoretically calculate
the peak stress. The calculated theoretical values were then compared with the measured peak
stresses.
The theoretical and measured values of peak stress in Figure 12 are relatively close, indicating
that the constitutive equation can effectively describe the relationship between temperature,
deformation rate, and deformation resistance of U-50wt.%Zr metal-type fuel within the temperature
range of 500℃~600℃ and strain rate range of 0.01s-1~1s-1.
Figure 12. Comparison of theoretical and measured values calculated by constitutive equations.
2.5. Establishment of Hot Working Diagram
This article utilizes the DMM dynamic material model [16] to process experimental data from
the Gleeble3800 thermal simulator, constructing a thermal processing diagram for U-50wt.%Zr metal-
type fuel. During thermal deformation of the material, the total energy Pcan be calculated using
equation (11).
P = G + J
(11)
In the formula: Grepresents the Jenergy consumed by plastic deformation (dissipation);
represents the energy consumed by structural changes (dissipation).
During the deformation process of materials, the deformation stress and strain rate follow a
power-law relationship, with the exponent being the strain rate sensitivity coefficient, which can be
calculated using equation (12).
m =
J
G
=
ln
ln
(12)
JCalculate Gusing formulas (13) and (14).
G = d
=
m + 1
(13)
J = d
=
m
m + 1
(14)
lnέ
Stress (Mpa)
Preprints.org (www.preprints.org) | NOT PEER-REVIEWED | Posted: 30 September 2024 doi:10.20944/preprints202409.2394.v1
12
When m=1, the dissipation state of material thermal deformation is optimal, Jreaching its
maximum value, as shown in Jequation (15).
J=
2
(15)
The energy dissipation efficiency of microstructural changes in materials during hot
deformation can be calculated using equation (16).
=
J
J
=
2m
m + 1
(16)
The instability of U-50wt.%Zr metal fuel during thermal deformation can be judged using
criterion (17).
()=ln
m
m + 1
ln + m < 0 (17)
Using Origin, power dissipation diagrams and instability diagrams were plotted after arranging
the data in a matrix. These diagrams were then superimposed to establish a thermal processing
diagram for U-50wt.%Zr metal-type fuel. Figure 13 shows the thermal processing diagram for U-
50wt.%Zr metal-type fuel, where the contour lines represent the power dissipation factor. The gray
area indicates the processing instability zone, while the white area represents the zone suitable for
pressure processing. In the white zone, a higher power dissipation factor is beneficial for thermal
pressure processing.
Figure 13. Thermal processing diagram of U-50wt.%Zr metal-type fuel.
3. Conclusion
(1)The thermal deformation behavior of U-50wt.%Zr metal-type fuel at 600℃ under varying
strain rates exhibits a pronounced dynamic recrystallization phenomenon. However, at 500℃ and
550℃, the dynamic recrystallization is less evident when the strain rate is high, with the thermal
deformation behavior primarily characterized by work hardening. Under the same strain rate
conditions, the higher the temperature, the lower the peak stress of deformation for U-50wt.%Zr
metal-type fuel; conversely, at the same temperature, the faster the strain rate, the higher the peak
stress of deformation for U-50wt.%Zr metal-type fuel.
(2) The microstructure of U-50wt.%Zr metal-type fuel was analyzed using a metallurgical
microscope and an X-ray diffractometer. Under the same strain rate, the hot deformation temperature
had an impact on its metallographic microstructure, such as changes in grain size. Overall, there were
no significant changes in the shape and structure of grain boundaries and grains, and no phase
transformation occurred in the microstructure. The XRD diffraction results showed that the phase of
U-50wt.%Zr metal-type fuel after hot deformation was δ-UZr2 phase.
Preprints.org (www.preprints.org) | NOT PEER-REVIEWED | Posted: 30 September 2024 doi:10.20944/preprints202409.2394.v1
13
(3) During the thermal compression deformation of U-50wt.%Zr metal fuel, its peak stress,
temperature, and strain rate basically satisfy the empirical Arrhenius hyperbolic sine equation. The
constitutive equation fitted for U-50wt.%Zr metal fuel obtained through regression analysis method
has a good agreement with the measured values at 600℃ during the experiment. Based on the
dynamic material model, a thermal processing diagram for U-50wt.%Zr metal fuel was constructed.
Through the thermal processing diagram, the instability zone and suitable temperature and strain
rate parameters for pressure processing of U-50wt.%Zr metal fuel during processing were
determined.
References
1. Li Guanxing, Zhou Bangxin, Xiao Min. Research on the Overall Development Strategy of China’s New
Generation Nuclear Energy and Nuclear Fuel [J]. China Engineering Science, 2019, 21(1): 6-11
2. Beausoleil G L, Cinbiz M N, Yao T, et al. U-50Zr Microstructure and Property Assessment for LWR
Applications[R]. Idaho National Lab. (INL), Idaho Falls, No. INL/EXT-21-64614
3. (United States), 2021.
4. Akabori, M, et al. 1995. “The Lattice Stability and Structure of δ-UZr2 at Elevated Temperatures.” Journal
of Physics: Condensed Matter 7: 8249.
5. Raj S B. Light water reactor (LWR) safety [J]. Nuclear Engineering and Technology, 2006, 38(8): 697-732.
6. Huber Z F, Conte E R, Lavender C A, et al. Casting and Characterization of U-50Zr[R]. Pacific Northwest
National Lab.(PNNL), Richland, WA (United States), 2023.
7. Li Ning, Wang Chuanqi, Sun Zhenlin,et al.Hot Deformation Behavior and Constitutive Equation of an
Ultralow-carbon Mircroalloyed Steel.[J/OL].Hot Wording Technology,2023,DOI:10.14158/j.
8. Zhou Jialin, Tang Li, Ren Yong,et al.A Study on Behavior of Hot Deformation of Ultralow-carbon Nb-V-Ti
Microalloyed Steel.[J].SPECIAL STEEL,2005,(03):15-18.
9. Lu Yunjie, Liang Neng, Wu Shuai,et al.Hot deformation behavior and constitutive equation of low-carbon
martensitic stainless steel.[J].Metallic Functional Materials , 2023, 30 (03) :41-49.
10. Zhang Xuemin, Cao Fuyang, Yue Hongyan, et al. Establishment of constitutive equations of tc11 alloy
during hot deformation [J]. Rare Metal Materials and Engineering, 2013, 42(5): 937-941.
11. Eichel D. Atomic Diffusion in the Uranium-50wt. % Zirconium Nuclear Fuel System [D]. , 2013.
12. Qing-song DAI, Yun-lai DENG, Jian-guo TANG, et al. Deformation characteristics and strain-compensated
constitutive equation for AA5083 aluminum alloy under hot compression [J]. Transactions of Nonferrous
Metals Society of China (English Version), 2019, 29(11): 2252-2261.
13. TIAN wei, LI Hong-bin, XU Shu-cheng, et al. Construction of material’s constitutive equation based on
gleeble fast compression test[C]. //Proceedings of the 7th Annual Youth Academic Conference of China
Metallurgy Society in 2014. 2014: 88-91.
14. Lun Jianwei, Liu Wei,Yang Yang, et al. High temperature plastic deformation behavior and constitutive
equation establishment of 35CrMoV steel[J]. Forging Technology, 2021, 46(3): 216-220.
15. Zener C, Hollomon J H.Effect of strain-rate upon the plastic flow of steel[J]. Journal of Physics D-Applied
Physics. 1944, 15(1): 22-32.
16. Yao Zhihao, Dong Jianxin, Zhang Maicang, et al. Hot deformation behaviour of superalloy GH738[J]. Rare
Metal Materials and Engineering, 2013, 42(6): 1199-1204.
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those
of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s)
disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or
products referred to in the content.
Preprints.org (www.preprints.org) | NOT PEER-REVIEWED | Posted: 30 September 2024 doi:10.20944/preprints202409.2394.v1