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Recycling of contaminated waste glass in ultra-high performance concrete: Impurities impact

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... Owing to this, various researchers, recommended the utilization of recycled coarse aggregate [22][23][24][25][26][27][28][29][30][31][32][33], steel slag aggregate [34][35][36][37][38][39], waste glass aggregates [40][41][42][43][44][45][46], ceramic waste aggregates [47][48][49][50], waste brick aggregate [51][52][53][54][55][56], E-waste aggregate [57][58][59][60], oil palm shell aggregate [61][62][63], coconut shell aggregate [64][65][66][67][68][69], Expanded Polystyrene aggregate [70][71][72][73][74][75][76], sawdust ash [77], waste rubber tire aggregate [78][79][80][81][82][83][84], and lightweight aggregates [85][86][87][88][89][90], as a substitution material of natural aggregate. ...
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Traditional waste management faces significant environmental, social, and economic challenges, while concrete’s high resource consumption highlights the need for improved, low�density alternatives. Consequently, lightweight concrete (LWC) has emerged as a favored solution. Recent interest in using pumice aggregate in concrete arises from its advantageous properties, such as low unit weight, which enables the construction of lighter buildings and reduces the load on structural elements. This study aimed to create lightweight, sustainable concrete using underutilized waste pumice aggregate (WPA). Concrete specimens with waste pumice aggregate ratios of 20%, 40%, 60%, 80%, and 100% were analyzed at 7 and 28 days, with results contrasted against the virgin sample. The testing protocol encompassed detailed laboratory evaluations of concrete properties, including workability, density, strength, impact energy, ultrasonic velocity, water absorption, and cost analysis. Experimental results indicated that the inclusion of Waste pumice aggregate as a lightweight aggregate in concrete, in contrast to conventional aggregates, results in reduced workability, density, and strength metrics, as well as heightened water absorption, diminished impact energy, and lower ultrasonic pulse velocity. Sustainable or green concrete from M-20 to M-60 along strength ≥17 MPa is for load�bearing applications, while M-80 and M-100 whose strength is <17 MPa are for non-load�bearing uses.
... Research has thus shown that fillers exhibit some physical-chemical activity, which promotes the acceleration of clinker hydration and contributes to a pozzolanic reaction (Zhu & Gibbs, 2005;Diederich et al., 2013). The valorization of glass waste in the field of materials could be an interesting ecological and economical solution (Zhao et al., 2024). Glass powder (GP) has now become an effective addition to the field of building materials. ...
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Nano-silica (NS) as a non-conductive nanofiller was utilized to promote performance improvement of conductive seawater cementitious composite (NS-CSWCC) manufactured by ohmic heating (OH) curing at −20 °C. NS exhibited great advantage on improving the heating efficiency of OH cured sample. The peak temperature and temperature-increase rate of NS-CSWCC samples increased from 52.7 °C and 0.27 °C/min to 73.4 °C and 0.43 °C/min with NS contents varying from 0 to 0.8 wt%. The enhanced mechanism of NS on heating efficiency was thoroughly clarified. The mechanical property results showed that NS-CSWCC sample with 0.8 wt% NS addition endowed the compressive strength of 83.5 MPa, meeting an increase of 36.4% comparing with that of the sample with no NS addition, indicating the advantage of NS addition on improving the mechanical properties. Besides, NS could also lead to higher Cl⁻ binding ratio of OH cured samples. To be specific, the Cl⁻ binding ratio of the sample with 0.8 wt% NS addition met an increase of 35.1% comparing with the sample incorporating no NS. Detailed micro-physicochemical analyses were conducted to reveal the mechanism behind increased Cl⁻ binding efficiency.
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Supplementary cementitious materials (SCMs) have attracted increasing research interests due to the energy-intensive process and high greenhouse gases emissions of conventional cement. Meanwhile, large amounts of domestic wastes such as waste glass are causing serious environmental issues due to their nonbiodegradable characteristic. Thus, recycling waste glass is a sustainable way to mitigate the environmental problem, conserve natural materials, minimize landfill spaces, and save energy during the recycling production process. This paper experimentally studied the effect of using waste glass powder (WGP) as an ordinary Portland cement (OPC) supplementary material on the paste specimens at ambient temperature and after exposure to high temperatures (800 °C, 1000 °C, and 1200 °C). The physical-mechanical properties such as workability, setting time, compressive strength, and bonding strength of the OPC paste samples containing different mass contents of WGP (0%, 10%, 20%, and 30%) were investigated and discussed. The potential alkaline aggregate reaction (ASR) effect of WGP on OPC was investigated by the accelerated mortar-bar method. The results show that the addition of WGP contributed to the workability but led to prolonged setting time of the OPC paste. On the other hand, the introduction of WGP in OPC mitigated the degradation of the OPC matrix under high temperatures and could reduce the ASR effect. Therefore, the WGP could be regarded as a feasible SCM to OPC to improve the safety of OPC-based structures both at ambient and under high temperatures.
Article
Waste glass stockpiling is a significant issue in Australia with approximately 66 kilo tonnes of uneconomic and contaminated waste glass fines being produced each year in Victoria alone. The high level of contaminants in waste glass fines could be harmful to concrete while washing glass is not economical and sustainable. Limited research has investigated the effect of contaminants in waste glass fines on the performance of concrete, which has hampered its broader acceptance as a substitution for natural sand aggregate. In this study, the feasibility of utilising unwashed waste glass fines as a sand replacement at 10 wt. % was comprehensively investigated, under both laboratory and on-site conditions. Minor differences were observed in both mechanical and durability properties between concrete with and without waste glass fines at 10 wt. % replacement. Overall, this study found that the effect of contaminants in waste glass fines can be neglected when being used as a replacement for natural sand at 10 wt. %.
Article
This paper reports the long-term field and laboratory-tested performance of concrete produced with 20 wt.% replacement of cement with powder waste glass (WG). Field investigations of WG concrete were carried out in a large-scale field project comprising of various segments subjected to harsh weathering conditions and service load over a period of about three years. While laboratory cured WG concrete and normal concrete specimens were tested in compression and flexure at various concrete ages ranging from 3 days to 300 days. After about three years of field exposure, concrete cores were extracted from various segments of the project and tested for compressive strength, moisture sorption, and abrasion resistance. A detailed survey of the various segments of the project was carried out to physically examine the state of WG concrete after three years of service. Test results of the field WG concrete showed enhanced compressive strength, up to 57% reduction in moisture sorption and up to 61% reduction in abrasion weight loss in comparison to normal concrete at 300 days of concrete age. Similarly, the laboratory tests showed 43% gain in compressive strength and 28% gain in flexural strength of WG concrete in comparison to that of normal concrete at 90 days of concrete age. Detailed physical examination of various project segments showed no signs of deterioration or material failure after three years of service. The field project also demonstrated the constructability of WG concrete similar to that of normal concrete.
Article
This work presented an enhanced ohmic heating (OH) curing method to promote the ultra-high strength of conductive hybrid carbon fibers reinforced RPC (HCF-RPC). This novel curing method was conducted at normal pressure and temperature, but its curing performance was comparable to the autoclave (AC) curing that required strict equipment to provide high pressure and temperature. Hybrid carbon fibers (CFs) and carbon nanofibers (CNFs) were synergistically applied to enhance electric conductivity and heating efficiency of HCF-RPC. Effects of enhanced OH curing on the multi-structural evolution of RPC were clarified and further compared with AC and high temperature stream (HTS) curing. The results showed that enhanced OH curing endowed the curing temperature of ∼180 °C to stimulate the compressive strength of HCF-RPC to 104.5 MPa with ultrashort curing duration of 3 h. XRD and TG analyses demonstrated the promoted hydration effect of enhanced OH curing, additional hydration products (tobermorite and xonotlite) were only detected in the enhanced OH and AC cured samples. Furthermore, ²⁹Si NMR data revealed longer average chain length in the enhanced OH cured sample than that of the AC cured sample. Additionally, a refined micro- and meso-scale pore structure was observed in the enhanced OH cured samples from MIP and BET analyses. This work presents enhanced OH curing as an effective method to replace traditional heat treatment methods to rapidly prepare RPC structure.
Article
Recently, with the rapid development of artificial intelligence (AI) techniques, there is a strong motivation to promote the intelligent development of the Ultra-High Performance Concrete (UHPC). To achieve this goal, this paper addresses an approach for precise design and characteristics prediction of UHPC by employing the Modified Andreasen and Andersen (MAA) model and Genetic Algorithm based Artificial Neural Network (GA-ANN) technique. Herein, 80 mixtures in total are conducted as a training dataset, and then a GA-ANN model is created for characteristics prediction of UHPC, which exhibits significant superiorities in fitting goodness and prediction accuracy compared to other classical prediction models. Furthermore, a prediction software based on GA-ANN technology with an efficient Graphical User Interface (GUI) is developed. Finally, a novel method for mix-design of UHPC by the use of MAA and GA-ANN models is proposed as follows: 1) conduct preliminary mixture design by MAA model; 2) further optimize the mixture by GA-ANN according to the property requirements. In general, a new UHPC with dense particle packing skeleton can be precisely designed by this method, which effectively verifies the feasibility of the application of AI technique in the UHPC field.
Article
The behavior of concrete containing waste glass as a replacement of cement or aggregate was studied previously in the most of researches, but the present investigation focuses on the recycling of waste glass powder as a substitute for silica fume in high strength concrete (HSC). This endeavor deals with the efficiency of using waste glass powder, as an alternative for silica fume, in the flexural capacity of HSC beam. Thirteen members with dimensions of 0.3 m width, 0.15 m depth and 0.9 m span length were utilized in this work. A comparison study was performed considering HSC members and hybrid beams fabricated by HSC and conventional normal concrete (CC). In addition to the experiments on the influence of glass powder on flexural behavior, numerical analysis was implemented using nonlinear finite element approach to simulate the structural performance of the beams. Same constitutive relationships were selected to model the behavior of HSC with waste glass powder or silica fume to show the matching between the modeling outputs for beams made with these powders. The results showed that the loading capacity and ductility index of the HSC beams with waste glass powder demonstrated enhancing ultimate load and ductility compared with those of HSC specimens with silica fume. The study deduced that the recycled waste glass powder is a good alternative to the pozzolanic powder of silica fume.
Article
Mechanically more performant ultra-high-performance concrete (UHPC) was developed by incorporating waste liquid–crystal display (LCD) glass powder and modifying steel fiber geometry. For this purpose, 50% of inert silica flour was replaced by LCD glass powder, and five steel fiber types with various cross-sectional shapes (circular or triangular) and twisting rates were considered. Results suggest that the glass powder was effective in enhancing the tensile and flexural performance of UHPC with straight steel fibers due to the increased frictional shear resistance at the fiber/matrix interface. However, its effectiveness was diminished when the fibers were twisted. Better tensile and flexural performances were reported for the circular fibers than that reported for triangular fibers due to the minor matrix damage and higher pullout energy. Such performance and cracking behavior of the latter could also be improved by twisting the fibers through the torsional action. The single twisting of triangular fiber improved the performance of UHPC, and no further improvement was observed by increasing the number of twisting. Synthetically, the circular fiber or singly twisted triangular fiber was considered as the most appropriate reinforcing type of UHPC.
Article
Concrete waste slurries coming from the washing of concrete mixer trucks in the manufacture of ready-mix concrete generate high costs and environmental impacts. In this work, we examined the consumption of raw materials, water, and generation of wastes for three Brazilian ready-mix concrete plants (that used different waste management strategies). The reuse of concrete slurry fines was also investigated in new concretes considering the waste management scenarios, production and operational costs. The strategy to recover fresh concrete provided the best scenario since it reduced significantly operational costs, despite the inclusion of new production cost, i.e. the hydration stabilizer additive. The replacement of sand with 1 vol.% concrete slurry provided adequate rheological conditions for concretes, when the water content increased up to 6 wt.% or added 0.3 % m.c. of polycarboxylate-based additive. The marginal increase in the production cost can also be compensated by the reduction of the disposal operational costs. The reuse strategy was not enough for the total elimination of concrete fines, requiring market diversification (e.g. precast concrete products); but fines availability can be very limited.
Article
This paper presents the effect of various glass aggregates on plastic and drying shrinkage and alkali silica reaction (ASR) expansion of cement mortar. The study was done by substituting a portion of sand with expanded glass, crushed glass, and glass bead aggregates. The low absorption capacity of glass, except expanded glass, enhanced the dimensional stability of the mixtures, minimizing volumetric contraction associated with shrinkage. Presence of finer glass particles in the mortar resulted in a large benefit in ASR expansion. The study found that cement mortar with glass aggregates can be beneficial if aggregate type and amount is chosen appropriately.
Article
This study investigates the rheological behaviour of ultra-high performance cementitious composite mortars containing 15–25 % of silica fume. The utilization of two Portland cements with different mineralogical compositions and their influence on yield stress of mortar was monitored. The coaxial rheometer was used for determination of flow curves of tested samples. It was found that besides the relation between flow and water-to-binder ratio, there is also a substantial relationship with the mortar composition, in particular with the content of silica fume. The yield stress can be described by an exponential function of volume content of solids in the mortar. Such a function can describe not only the influence of granulometry but also the impact of structure formation on early age Portland cement hydration. It was found that the estimation of yield stress can be done even by a simple modular in-field technique such as a spread flow test.
Article
The rheology is an effective tool to characterize workability, consistency, flowability, and predict stability, pumpability, shootability, pressure of formwork, multi-layer casting. This paper presents a critical review on the rheological properties of fresh concrete in recent publications. The applicable rheological models for the flow of concrete are revealed. The effects of constituents of fresh concrete, including cement, supplementary cementitious materials (fly ash, ground blast furnace slag, and silica fume), limestone powder, coarse and fine aggregates, and chemical admixtures (superplasticizer, viscosity modifying agent and air-entraining agent) on the rheological properties are discussed in detail. The applications of rheograph and workability boxes in mixture proportioning and quality control are also illustrated.
Article
Autogenous shrinkage is a major concern in early age cracking of high performance concrete (HPC). Low water-to-binder ratio and incorporation of supplementary cementitious materials (SCMs) can remarkably affect the pore structure, relative humidity, self-stress, degree of hydration, and interface structure; hence, increase the shrinkage in the matrix. In this paper, the mechanism of autogenous shrinkage of HPC and influential factors in its development are discussed. In general, autogenous shrinkage is more pronounced in HPC, albeit, using low heat cement, fly ash, shrinkage reducing agents, lightweight aggregates, and fibers can effectively reduce it. The effects of SCMs on autogenous shrinkage, relationship between different types of shrinkage and autogenous shrinkage as well as the effect of internal curing on autogenous shrinkage need to be further studied.
Article
Ultra-high-performance concrete (UHPC) is characterized by a dense microstructure that yields ultra-high strength and durability properties. Quartz sand (QS) with maximum particle sizes of 600 μm represents the coarse particles in (UHPC). The QS with optimum grading curve is obtained from crushing coarse sand or rocks, however this is a time-consuming, costly, and polluting process. This paper reports on a study to determine the possibility of producing and using glass sand (GS) for partial or total replacement of QS in UHPC. The results show that GS with a mean particle size (d50) of 275 µm could be recommended as an optimal PSD to replace QS particles. The results demonstrate that compressive strength values of about 196 and 182 MPa after two days of hot curing can be achieved when replacing 50% and 100% of QS with GS, respectively, compared to 204 MPa for reference UHPC containing 100% QS. Incorporating higher replacement rates of GS was shown to produce UHPC of accepted flowability and dense microstructure that mitigated the aggregate alkali–silica reaction
Article
In this study potential synergistic role of a finely ground glass powder in binary and ternary cementitious blends with conventional SCMs such as meta-kaolin, fly ash and slag was evaluated. Strength activity index, thermo-gravimetric analysis (TGA) and mortar bar tests were conducted to study the pozzolanic behavior and ASR mitigation ability. The results from this study showed that ternary mixtures consisting of finely ground soda glass with either slag or Class C fly ash out-performed binary mixtures consisting of each of these SCMs at an equivalent dosage level. Binary mixtures consisting of meta-kaolin out-performed ternary mixtures consisting of ground glass powder with meta-kaolin at equivalent dosage level. Among all the binary and ternary mixtures that contained 30% level of SCMs, the maximum strength activity index and the most efficient ASR mitigation was obtained in ternary mixtures consisting of at least 10% glass powder. The results from TGA studies supported these findings.
Article
Recycling construction demolition waste such as concrete rubbles has become more important for preventing resource depletion and reducing environmental burden. However, recycled aggregate from demolished concrete waste can bring about several problems due to the various impurities included in concrete waste, when recycled aggregates are used for recycled aggregate concrete. Therefore, it is significantly important not only to investigate the influence of impurities on properties of recycled aggregate concrete but also to examine the safety of recycled aggregate.The objective of this study is to investigate the properties of concrete containing two types of metal impurities, of which limit content is not specified in standards. To achieve this purpose, experimental works were conducted for concrete containing metal impurities with various size and content and it was found that aluminum, contained in recycled aggregate, caused performance degradation in both mechanical property and durability of recycled aggregate concrete even with very low content less than 0.1%. This paper also suggested a convenient inspection method for aluminum impurity utilized at plants to confirm the safety use of recycled aggregate and to reduce the risk of using recycled aggregate.
Article
The effects of replacement percentages and particle size distribution of recycled fine glass (FG) aggregates on the properties of dry–mixed concrete blocks were investigated. All the mixtures were proportioned with a fixed total aggregate/cement ratio of 4% and 50% of the total aggregate was fine aggregate. A total of 17 concrete block mixes, including a control (0% of glass) mix, were produced using four different particle sizes of FG (un-sieved, <2.36 mm, <1.18 mm and <600 μm) as replacements of sand. The replacement ratios were 25%, 50%, 75% and 100%. Properties such as packing density, hardened density and water absorption, as well as the effects of air and water curing upon 7 and 28-day compressive strength were studied.The results show that the water demand of the mix increased with decreasing fineness modulus of the fine aggregate. All concrete blocks containing FG showed higher water absorption and lower hardened density than the control concrete block. For FG with particle size less than 600 μm, this was more pronounced. Slight reductions in compressive strength were observed with the use of coarser FG, while significant increases in compressive strength occurred when the particle size of FG was reduced to less than 600 μm. This indicates that finer FG exhibited appreciable pozzolanic reactivity.
Article
The aim of this paper is to assess the performance of self-compacting glass concrete (SCGC) after exposure to four elevated temperatures of 300°C, 500°C, 600°C and 800°C. The influence of curing conditions on the high temperature performance of SCGC was also investigated. For each curing regime, five SCGC mixtures were prepared with recycled glass (RG) which was used to replace natural fine aggregate at the level of 0%, 25%, 50%, 75% and 100%. After exposure to the elevated temperatures, concrete mass loss, density, water porosity, ultrasonic pulse velocity (UPV) and water sorptivity were determined and then a compressive strength test was conducted. The test results indicate that regardless of the exposure temperature, all the water cured specimens had higher residual strengths and mass losses while the water porosity and water sorptivity values were lower as compared to the corresponding air cured specimens. The incorporation of RG in the concrete mixes helped to maintain the concrete properties after the high temperature exposure due to the melting and resolidification of the recycled glass in the concrete matrix.
Article
There is a growing interest of using recycled crushed glass (RCG) as an aggregate in construction materials especially for non-structural applications. Although the recycled crushed glass is able to reduce the water absorption and drying shrinkage in concrete products due to its near to zero water absorption characteristics, the potential detrimental effect of using glass due to alkali–silica reaction (ASR) in cementitious materials is a real concern. The extent of ASR and its effect on concrete paving blocks produced with partial replacement of natural aggregates by crushed glass cullet are investigated in this study. This study is comprised of two parts. The first part quantified the extent of the ASR expansion and determined the adequate amount of mineral admixtures that was needed to reduce the ASR expansion for concrete paving blocks prepared with different recycled crushed glass contents using an accelerated mortar bar test in accordance with ASTM C 1260 (80 °C, 1 N NaOH solution). In the second part, concrete paving blocks were produced using the optimal mix proportion derived in the first part of this study and the corresponding mechanical properties were determined.It was found from the mortar bar test that the incorporation of 25% or less RCG induced negligible ASR expansion after a testing period of 28 days. For mixes with a glass content of higher than 25%, the incorporation of mineral admixtures such as pulverized fuel ash and metakaolin was able to suppress the ASR expansion within the stipulated limit but the results need to be confirmed by other test methods such as the concrete prism test.The study concluded that the optimal mix formulation for utilizing crushed waste glass in concrete paving blocks should contain at least 10% PFA by weight of the total aggregates used.
Article
A large proportion of the postconsumer glass is recycled into the packaging stream again, and some smaller proportions are used for a variety of purposes, including concrete aggregate. However, a significant proportion, which does not meet the strict criteria for packaging glass, is sent to landfill, taking the space that could be allocated to more urgent uses. Glass is unstable in the alkaline environment of concrete and could cause deleterious alkali-silica reaction (ASR) problems. This property has been used to advantage by grinding it into a fine glass powder (GLP) for incorporation into concrete as a pozzolanic material. In laboratory experiments, it can suppress the alkali reactivity of coarser glass particles as well as that of natural reactive aggregates. It undergoes beneficial pozzolanic reactions in the concrete and could replace up to 30% of cement in some concrete mixes with satisfactory strength development. The drying shrinkage of the concrete containing GLP was acceptable.
Article
The possibility of using finely ground waste glass as partial cement replacement in concrete was examined through three sets of tests: the lime-glass tests to assess the pozzolanic activity of ground glass, the compressive strength tests of concrete having 30% cement replaced by ground glass to monitor the strength development, and the mortar bar tests to study the potential expansion. The results showed that ground glass having a particle size finer than 38 μm did exhibit a pozzolanic behavior. The compressive strength from lime-glass tests exceeded a threshold value of 4.1 MPa. The strength activity index was 91, 84, 96, and 108% at 3, 7, 28, and 90 days, respectively, exceeding 75% at all ages. The mortar bar tests demonstrated that the finely ground glass helped reduce the expansion by up to 50%. A size effect was observed; a smaller glass particle size led to a higher reactivity with lime, a higher compressive strength in concrete, and a lower expansion. Compared to fly ash concrete, concrete containing ground glass exhibited a higher strength at both early and late ages.
Article
Quantities of waste glass have been on the rise in recent years due to an increase in industrialization and the rapid improvement in the standard of living. Unfortunately, the majority of waste glass is not being recycled but rather abandoned, and is therefore the cause of certain serious problems such as the waste of natural resources and environmental pollution. For these reasons, this study has been conducted through basic experimental research in order to analyze the possibilities of recycling waste glasses (crushed waste glasses from Korea such as amber, emerald green, flint, and mixed glass) as fine aggregates for concrete. Test results of fresh concrete show that both slump and compacting factors are decreased due to angular grain shape and that air content is increased due to the involvement of numerous small-sized particles that are found in waste glasses. In addition the compressive, tensile and flexural strengths of concrete have been shown to decrease when the content of waste glass is increased. In conclusion, the results of this study indicate that emerald green waste glass when used below 30% in mixing concrete is practical along with usage of 10% SBR latex. In addition, the content of waste glasses below 30% is practical along with usage of a pertinent admixture that is necessary to obtain workability and air content.