Fast catalytic and electrocatalytic oxidation of sodium borohydride on palladium nanoparticles and its application to ultrasensitive DNA detection

ArticleinChemical Communications · November 2009with13 Reads
Impact Factor: 6.83 · DOI: 10.1039/b912450k · Source: PubMed

    Abstract

    We report an ultrasensitive DNA sensor using the rapid enhancement of electrocatalytic activity of DNA-conjugated Pd nanoparticles (NPs); the rapid enhancement results from the fast catalytic hydrolysis of NaBH(4) on Pd NPs and subsequent fast hydrogen sorption into Pd NPs.