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Sports balls made of nanocomposite investigating how soccer balls motion and impact

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Abstract

The incorporation of nanoplatelets in composite and polymeric materials represents a recent and innovative approach, holding substantial promise for diverse property enhancements. This study focuses on the application of nanocomposites in the production of sports equipment, particularly soccer balls, aiming to bridge the gap between theoretical advancements and practical implications. Addressing the longstanding challenge of suboptimal interaction between carbon nanofillers and epoxy resin in epoxy composites, this research pioneers inventive solutions. Furthermore, the investigation extends into unexplored territory, examining the integration of glass fiber/epoxy composites with nanoparticles. The incorporation of nanomaterials, specifically expanded graphite and graphene, at a concentration of 25.0% by weight in both the epoxy structure and the composite with glass fibers demonstrates a marked increase in impact resistance compared to their nanomaterial-free counterparts. The research transcends laboratory experiments to explore the practical applications of nanocomposites in the design and production of sports equipment, with a particular emphasis on soccer balls. Analytical techniques such as infrared spectroscopy and scanning electron microscopy are employed to scrutinize the surface chemical structure and morphology of the epoxy nanocomposites. Additionally, an in-depth examination of the thermal, mechanical, viscoelastic, and conductive properties of these materials is conducted. Noteworthy findings include the efficacy of surface modification of carbon nanotubes in preventing accumulation and enhancing their distribution within the epoxy matrix. This optimization results in improved interfacial interactions, heightened thermal stability, superior mechanical properties, and enhanced electrical conductivity in the nanocomposite.

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Physical exercise, especially intense exercise and high intensity interval training (HIIT) by trampoline, can lead to muscle injuries. These effects can be reduced with intelligent products made of nanocomposite materials. Most of these nanocomposites are polymers reinforced with silicon dioxide, alumina, and titanium dioxide nanoparticles. This study presents a polymer nanocomposite reinforced with silica. As a result of the rapid reaction between tetraethyl orthosilicate and ammonia in the presence of citric acid and other agents, silica nanostructures were synthesized. By substituting bis (4-amino phenoxy) phenyl-triptycene in N, N-dimethylformamide with potassium carbonate, followed by catalytic reduction with hydrazine and Pd/C, the diamine monomer bis (4-amino phenoxy) phenyl-triptycene is prepared. We synthesized a new polyaromatic (imide) with triptycene unit by sol-gel method from aromatic diamines and dianhydride using pyridine as a condensation reagent in NMP. PI readily dissolves in solvents and forms robust and tough polymer films in situ. The FTIR and NMR techniques were used to determine the effects of SiO2 on the sol-gel process and the structure of the synthesized nanocomposites. By using a simultaneous thermal analysis (DTA-TG) method, the appropriate thermal operation temperature was also determined. Through SEM analysis, the structure, shape, size, and specific surface area of pores were determined. Analysis of XRD results is used to determine how SiO2 affects the crystallization of phases and the activation energy of crystallization.
Article
Achieving superior reusable energy absorption and mitigation properties under repeated impact loadings with high strain rates, yet maintaining the lightweight design feature, is still a challenge for thin-walled structure design. In this work, combined with the concept of mechanical metamaterial, several kinds of negative-stiffness meta-sandwich structures (NSMSs) are developed and their dynamic responses under repeated high strain-rate impacts are systematically investigated. The 3D printing technique of selective laser sintering (SLS) is applied to fabricate the composite NSMSs with glass fiber reinforced (GFR) Nylon. The bistability of the double curved-beam topology and the remarkable impact resistance to the repeated impact loadings are theoretically, numerically, and experimentally analyzed. An analytical model based on the Gibson-Ashby framework is presented to predict the mechanical behavior of NSMSs, and a series of evaluation indicators are developed to quantitatively describe the energy absorption performance. Compared with a conventional honeycomb structure, the unique layer-by-layer failure mode for NSMSs, leading to a significant improvement in the capacity of multiple-impact resistance, is unambiguously demonstrated. This new type of artificial structure paves a feasible way to achieve superior energy absorption and impact resistance features under repeated impacts.
Article
Material extrusion (MEX) 3D printing fabricates cost-effective functional polymeric parts, while a new class of materials, such as polylactic acid/carbon nanotubes (PLA/CNTs) nanocomposites, have great potential for use in MEX due to their multi-functional performance. MEX advantages include the construction of lightweight specimens with complex geometry, in minimum time and with minimum waste, while its drawbacks are related to the parts' surface roughness, anisotropic behavior, and shape accuracy. To improve the properties of parts, build with MEX, thus extending their applicability in areas such as biomedical, aeronautics, automotive, printing electronics , and others, the 3D printing parameters need to be controlled, while post-processing further and significantly improve their performance. Combining 3D printing with laser as a post-processing technology highly improves the efficiency of the nanocomposites. In this work, new data are reported on PLA/CNT nano-composites in thin plates form, manufactured with MEX and pro-processed with low-cost CO 2 laser cutting, for the improvement of their shape accuracy and their surface roughness, making them eligible for use in innovative nanocomposite-based applications.
Article
The emission of CO2 from human activities is the principal reason for global warming. Membrane separation technology has been extensively regarded as a tremendous potential option for mitigating CO2 emissions when utilizing fossil fuels as a major source of energy. As an important group of CO2 separation membranes, the fixed CO2 carrier-facilitated transport membrane guided by π-complexation reactions is a rising research field and has attracted much attention in the last ten years due to its desirable CO2 separation performance in the dry state and high resistance to oxidation. In this review, facilitated transport theories derived from π-complexation reactions are discussed for an in-depth understanding, rational design and tunable fabrication of facilitated transport membranes. According to the different fixation methods of metal ions (CO2 active carrier), polymer electrolyte membranes and mixed matrix membranes are discussed in detail as two strategies for fabricating CO2-facilitated transport membranes. Future perspectives toward π-complexation reaction-facilitated transport membranes are proposed.
Article
Using nanocarriers to load antimicrobial agent instead of direct incorporating into film matrix could avoid burst release. Halloysite nanotubes (HNTs) are natural clays with a unique tubular structure; therefore in many studies it served as carriers to achieve a controlled release of active agents. However, when HNTs biocomposites were loaded into packaging film, the antimicrobial activity was reduced too seriously to preserve the packaged food. This study aimed to improving preservation properties of the fabricated films from two perspectives: enlarging the loading capacity of the carrier, and increasing the concentration of HNTs biocomposites. Brunauer, Emmett, Teller's test (BET) and thermogravimetric analysis (TGA) were conducted to evaluate the performance of acid treated nanocomposites. Results showed that acid treatment expanded the lumen of HNTs, increasing the loading capacity of cinnamaldehyde (Cin) from 14.6 wt% to 25.0 wt%. Active packaging films were then fabricated by incorporating Cin loaded HNTs into poly(lactic acid) matrix, and it revealed bionanocomposites at 30 wt% achieved the optimum film, considering the mechanical performance and controlled release of Cin. Cumulative release rate of the films were further verified by the fumigant antimicrobial activity. This study demonstrates a solution for improving the antimicrobial properties of packaging film without comprising mechanical strength.
Article
1Abstract Mechanical and tribological performances of Ti-16 wt.%Ni alloy-based components were analyzed to extend their application scopes while retaining their longevity and high accuracy. Accordingly, the frictional surface was integrated with important parameters and the configurable sine-shaped channels through finite element analysis. Further, tensile and compression stresses were determined for Ti-16 wt.%Ni composites using Gleeble 3800. In a ball-on-flat tribopair system, a MA: (AO-GN) (MgAl: (Al2O3-graphene)) ratio of 8.5: 1.0 enhanced the deformation, and facilitated excellent self-rehabilitation to improve the tribological behaviors. Further optimization of the MA: (AO-GN) ratio, i.e., 8.5:(1.2:0.3), helped in formation of the tribo-film. Sliding friction resistance and surface material loss were reduced. Thus, the best tribological behavior among the selected matching ratios was obtained. This was attributed to the cooperative functions of load extrusion and low friction heating, which caused low-temperature MA lubricants to cooperate with AO and GN, resulted in their migration from microcosmic channels (microchannels) to the frictional interface. Subsequently, they spread to form the tribo-film, and repaired the interface, thus facilitating an excellent tribological behavior.
Article
To avoid the additional damage caused by conductive films embedded between layers of composites and to decrease the complexity of sensing structure manufacturing, a novel conductive smart coating for structural health monitoring is developed. This coating can be applied onto the surface of composite products. Also, a design principle for conductive coatings is proposed to provide design guidelines for sensor materials. A conductive coating with multiwall carbon nanotubes and carbon black is fabricated to verify the design principles. Besides, coating-related properties such as resistance change, conductivity, and failure strain are characterized through experiments. The damage to composite laminates with various thicknesses at tensile and different impact loads is analyzed to verify the monitoring effect of the coating. Additionally, to determine the damage location, a damage localization prototype is proposed. The results of this paper provide a reference and a design method for the engineering application of coated sensors and damage monitoring.
Article
The power electronics tend to become miniaturized and multifunctionalized, such as thermal rotators, circuit breakers, and microchips, which have necessitated creating instruments for investigating thermal mechanisms and enhancing thermal conductivity. In this paper, we construct the heat flow network of spherical boron nitride (BN) and used multiscale spherical BN to improve the thermal conductivity of the composite synergistically. The multiscale spherical filler ratio optimization model based on the Dinger-Funk particle stacking theory is established, which obtained the optimal volume ratio of 0.224:0.374:0.402 with D50 of 20, 70, and 160 μm. Meanwhile, the effects of multiscale filler ratio, morphology, filler content, and temperature are investigated. The thermal conductivity of composites can reach up to 1.84 W/(m·K) at 20 vol %. Significantly, the thermal conductivity of composites is 4.82 W/(m·K) at 30 vol %, which is achieved by optimizing the multiscale filler and particle size distribution.
Article
This research studies the nonlinear buckling of two-dimensional functionally graded (2D-FG) nanotubes with porosity based on the Zhang-Fu theory of tubes, Timoshenko beam theory, and the nonlocal gradient strain theory (NSGT) as well as Von-Karmen nonlinear theory. In this paper, the formulation of the problem for various boundary conditions is generated according to the energy method. Then, the results are extracted by incorporating the generalized differential quadrature method (GDQM) coupled with the iteration method. The accuracy of the results is proven through comparative studies, and finally, the impact of different parameters, which influence the buckling of the nanotube, is investigated.
Article
Background DNA N6-methyladenine plays an important role in the restriction-modification system to isolate invasion from adventive DNA. The shortcomings of the high time-consumption and high costs of experimental methods have been exposed, and some computational methods have emerged. The support vector machine theory has received extensive attention in the bioinformatics field due to its solid theoretical foundation and many good characteristics. Objective General machine learning methods include an important step of extracting features. The research has omitted this step and replaced with easy-to-obtain sequence distances matrix to obtain better results Method First sequence alignment technology was used to achieve the similarity matrix. Then a novel transformation turned the similarity matrix into a distance matrix. Next, the similarity-distance matrix is made positive semi-definite so that it can be used in the kernel matrix. Finally, the LIBSVM software was applied to solve the support vector machine. Results The five-fold cross-validation of this model on rice and mouse data has achieved excellent accuracy rates of 92.04% and 96.51%, respectively. This shows that the DB-SVM method has obvious advantages compared with traditional machine learning methods. Meanwhile this model achieved 0.943,0.982 and 0.818 accuracy,0.944, 0.982, and 0.838 Matthews correlation coefficient and 0.942, 0.982 and 0.840 F1 scores for the rice, M. musculus and cross-species genome datasets, respectively. Conclusion These outcomes show that this model outperforms the iIM-CNN and csDMA in the prediction of DNA 6mA modification, which are the lastest research on DNA 6mA.
Article
Despite the importance of natural fractures in shales, few techniques are currently available to examine their formation mechanism and effects on shale oil accumulation directly. The Middle Permian Lucaogou Formation in the Jimsar Sag of the Junggar Basin is a typical fractured shale. The Jimsar Sag has experienced multiple phases of tectonic movement since the Paleozoic Era, forming numerous natural fractures. However, controversy still surrounds the timing of formation, genetic mechanisms, and effects on shale oil accumulation of these fractures. Based on C-O-Nd isotopes, rare earth elements, fluid inclusions, SmNd isochron dating of fracture cements, rock acoustic emission, and triaxial rheological experiment, this study precisely define the fracture formation time, trace the provenances of fluids filling the fractures, elucidate the genetic mechanism of fractures and their effects on shale oil accumulation. The results suggest that these fractures were mainly formed in the Late Permian, Late Jurassic, and Early Cretaceous. Palaeotectonic stress field simulations further show that the tectonic movements in the Late Permian formed nearly N-S-trending fractures due to severe north-south extrusion. High-temperature fluids originating from the post-collision mantle intruded the Lucaogou Formation between ~258.1 Ma and ~ 257.6 Ma. Subsequently, tectonic movements in the Tianshan Mountains during the Late Jurassic resulted in extrusion from southwest to northeast, forming NEE-trending fractures. During this tectonic event, basin fluids intruded the Lucaogou Formation between ~150.2 Ma and ~ 146.5 Ma. The persistent fold rollback that occurred in the Bogda piedmont foreland sag in the Early Cretaceous subjected the Jimsar Sag to severe extrusion, forming NNW-trending fractures. This tectonic event influenced the intrusion of basin fluids into the Lucaogou Formation between ~123.0 Ma and ~ 120.3 Ma. The Late Jurassic and Early Cretaceous fractures coincided with the peak of oil generation and expulsion in the Lucaogou shale and created conduits and reservoir volumes for the migration and accumulation of shale oil. Our study introduces a new approach that integrates geophysical and geochemical data to investigate the formation processes of fracture and their impact on shale oil accumulation.
Article
Biochar(BC)-photocatalyst nanocomposites have emerged as appealing water and wastewater treatment technology. Such nanocomposite materials benefit from the synergistic effect of adsorption and photocatalysis to attain improved removal of pollutants from water and wastewater. Under this review, three BC-based nanocomposite photocatalysts such as BC-TiO2, BC-ZnO, and BC-spinel ferrites were considered. These nanocomposites acquire intrinsic properties to improve the practical limitations of the pristine BC and photocatalysts. The BC-based nanocomposites attained high photocatalytic activity, mechanical hardness, thermal stability, chemically non-reactive, magnetically permeable, reduced energy band gaps, improved reusability, and simplified recovery. Moreover, BC-based photocatalytic nanocomposites showed reduced recombination rates of the electron-hole pairs which are desirable for photocatalytic applications. However, the surface areas of the composites are usually smaller than that of the BC but higher than those of the pristine photocatalysts. Practically, the performances of the nanocomposites are much superior to those of the corresponding pristine components. This hybrid treatment technology is an emerging field and its industrial application is still at an early stage of the investigation. Therefore, exploring the full potential and practical applications of this technology is highly encouraging. Hence, this review focused on the critical evaluation of the most recent research on the synthesis, characterization, and photocatalytic treatment efficiency of the BC photocatalyst nanocomposites towards emerging pollutants in the aqueous medium. Moreover, the influence of various sources of BC feedstocks and their limitations on adsorption and photodegradation activities are discussed in detail. Finally, concluding remarks and future research directions are given to assist and shape the exploration of BC-based nanocomposite photocatalysts in water treatment.
Article
In recent years, carbon materials reinforced composites have aroused widespread interests owing to their remarkable physicochemical performances and important biological potentials. But, their enhanced applications in multidimensional fields of mechanics, thermology, electricity, tribology and the biomedicine are rarely reported. Systematacially, this review discusses typical micro/nano-structures, main properties and multidimensional applications from carbon nanotubes and graphite to fullerenes, subsequently to graphene and nanodiamonds, next to carbon fibers, finally to the amorphous carbons. After introduction of micro/nano-structures and absorbing properties of carbon materials, which are subsequently analyzed in the multi-scaled mechanics. Afterward, important discussions on thermal enhancements and electrical contributions of carbon materials are respectively reported in 3 Thermal enhancement effects of carbon materials, 4 Electrical contributions of carbon materials. Subsequently, their mechanisms for achieving friction-reduction and antiwear are summarized. Advanced progress of biomedical adhibition of carbon material is further elaborated. Finally, this review is concluded with the outlooks on crucial challenge and future opportunity for widening multidimensional applications.
Article
Light-driven photocatalysis might address many global energy concerns due to its implications for hydrogen production and the imperative need to reduce fossil fuel dependency. Polydopamine (PDA) is a popular mussel-inspired material with extensive applicability in biomedical and drug delivery fields, which has recently been gathering attention in the fields of catalysis and photocatalysis. PDA is highly attractive for catalysis due to its large number of functional groups and its easy polymerization on virtually any surface. In photocatalysis, however, its properties have not been well described and strongly depend on the generation of heterojunctions (PDA/Semiconductor). In this review, we summarize the latest developments and studies on photocatalytic nanocomposites based on PDA. We will introduce general aspects such as structure and polymerization control. Then, we will focus on aspects of relevance for photoactive materials, such as chromatic control and electrical properties. We will present and discuss the recent literature on metal oxides and metal sulphides and some emergent materials focusing on photoactive and photocatalytic applications. Finally, we will outline some of the opportunities in the field. We hope this review serves as a reference for researchers and allows the growing community to focus on future developments for PDA-based photocatalytic nanocomposites.
Article
Eutrophication caused by excessive phosphate has become a global environmental issue that urgently needs to be solved due to its destructive effect on the ecosystem and adverse effect on human health. In this study, a novel lanthanum carbonate-grafted ZSM-5 zeolite (LC-ZSM-5) was developed to effectively achieve highly selective phosphate removal from wastewater. The LC-ZSM-5 adsorbent shows high adsorption capacity (highest at over 45 mg-PO4³⁻/g) in the pH range of 3–6 with a fast adsorption rate (reaching 80% of the maximum adsorption capacity within 150 min and equilibrium at 350 min). High stability can be observed with less than 0.3 mg/L La leakage during the adsorption process. Four kinetic models are used to describe the adsorption process. The pseudo second order model and the Elovich model are found to fit the data best with a high correlation coefficient (r² = 0.99), showing that the adsorption process is influenced simultaneously by the phosphate concentration and interaction between adsorbent and adsorbate. The change of curve slope from 4.0 to 0.89 and intercept from 0.76 to 27.6 in intra-particle model indicates that the adsorption process is controlled by a combination of intra-particle diffusion and film surface diffusion. The maximum phosphate adsorption capacity calculated from the Langmuir model is 47.7 mg-PO4³⁻/g, and the adsorption isotherm data are fitted well by the Freundlich model (r² = 0.95) and the Koble-Corrigan model (r² = 0.95), suggesting that the phosphate adsorption process is dominated by nonregular multilayer adsorption with the coexistence of monolayer adsorption. The ionic strength and co-existing anions have little impact on the adsorption capacity of LC-ZSM-5, proving the adsorption selectivity of phosphate onto LC-ZSM-5. Characterization results show that spindle-like lanthanum carbonate particles are fabricated on ZSM-5. Combining the adsorption process and the characterization, it can be derived that phosphate is adsorbed by LC-ZSM-5 mainly through electric attraction and ligand exchange. Our study demonstrates the great potential application value of LC-ZSM-5 in commonly seen phosphate-containing wastewater.
Article
Modulation of electronic properties in spintronic interfaces (spinterfaces) can give rise to the optimization and even emergence of abundant spintronic effects. However, a proof-of-concept demonstration of such a strategy has rarely been achieved. In this paper, we study the interlayer exchange coupling effect in a synthetic magnetic multilayer system [Pt/Co]2/VO2/[Co/Pt]2, where atomically thin phase-change material VO2 is adopted as a spinterface with reversible metal-to-insulator transition. Repeatable switching from antiferromagnetic coupling through insulating spinterface to ferromagnetic coupling through metallic spinterface is observed in this multilayer system. Further analyses indicate that such an evolution originates from two distinct coupling mechanisms of spin-dependent tunneling and Rudermann-Kittel-Kasuya-Yosida interaction determined by the electronic states of VO2. As an experimental demonstration of VO2-tailored interlayer exchange coupling effect, this work highlights the great potential of spinterface as a magic building block in beyond-CMOS electronic devices.