Over the past few years, lead halide perovskites have demonstrated significant potential in the field of solar cells, light-emitting diodes, and field-effect transistors. We investigated the transient photoconductivity and temperature-induced phase transitions in
thin films, using ultrabroadband optical pump-terahertz probe spectroscopy with varying excitation fluences and
... [Show full abstract] temperature conditions. As the temperature drops from 293 to 123 K, undergoes two phase transitions, resulting in a significant extension of exciton lifetime in the tetragonal phase near 150 K, where exhibits a longer exciton lifetime. Our research contributes to a better understanding of the temperature-induced phase transition mechanism of , enhancing its potential applications in optoelectronic devices.