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Correction: Iridium-(κ2-NSi) catalyzed dehydrogenation of formic acid: effect of auxiliary ligands on the catalytic performance

Authors:
  • Instituto de Síntesis Química y Catálisis Homogénea. CSIC- Universidad de Zaragoza

Abstract and Figures

Correction for 'Iridium-(κ2-NSi) catalyzed dehydrogenation of formic acid: effect of auxiliary ligands on the catalytic performance' by Alejandra Gomez-España et al., Dalton Trans., 2023, 52, 6722-6729, https://doi.org/10.1039/d3dt00744h.
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Dalton
Transactions
CORRECTION
Cite this: DOI: 10.1039/d3dt90139d
DOI: 10.1039/d3dt90139d
rsc.li/dalton
Correction: Iridium-(κ
2
-NSi) catalyzed dehydro-
genation of formic acid: eect of auxiliary ligands
on the catalytic performance
Alejandra Gomez-España,
a,b
Jorge L. Lopez-Morales,
a
Belinda Español-Sanchez,
a
Pilar García-Orduña,
a
Fernando J. Lahoz,
a
Manuel Iglesias
a
and
Francisco J. Fernández-Alvarez*
a
Correction for Iridium-(κ
2
-NSi) catalyzed dehydrogenation of formic acid: eect of auxiliary ligands on
the catalytic performanceby Alejandra Gomez-España et al.,Dalton Trans., 2023, 52, 67226729,
https://doi.org/10.1039/d3dt00744h.
Figures Fig. 4 and Fig. S17 contain mislabeling, where H
2
is indicated it should be CO
2
. The revised Fig. 4 and Fig. S17 are:
Fig. 4 FT-IR of the gas resulting from the 3-catalyzed (0.1 mol%) FADH in presence of Et
3
N (40 mol%) at 353 K.
a
Departamento de Química Inorgánica Instituto de Síntesis Química y Catálisis Homogénea (ISQCH). Universidad de Zaragoza-CSIC. Facultad de Ciencias 50009,
Zaragoza, Spain. E-mail: paco@unizar.es
b
Universidad Pedagógica Nacional Francisco Morazán-UPNFM, 11101 Tegucigalpa, Honduras
This journal is © The Royal Society of Chemistry 2023 Dalton Trans.
Open Access Article. Published on 07 August 2023. Downloaded on 8/8/2023 1:22:49 PM.
This article is licensed under a
Creative Commons Attribution 3.0 Unported Licence.
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Fig. S17 FT-IR spectrum of the gas resulting from the 3-catalyzed (0.1 mol%) FADH in presence of Et
3
N (40 mol%). Up reac-
tion at 353 K. Down reaction at 373 K.
The Royal Society of Chemistry apologises for these errors and any consequent inconvenience to authors and readers.
Correction Dalton Transactions
Dalton Trans. This journal is © The Royal Society of Chemistry 2023
Open Access Article. Published on 07 August 2023. Downloaded on 8/8/2023 1:22:49 PM.
This article is licensed under a
Creative Commons Attribution 3.0 Unported Licence.
View Article Online
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Full-text available
The chemistry of transition‐metal (TM) complexes with monoanionic bidentate (κ²‐L,Si) silyl ligands has considerably grown in recent years. This work summarizes the advances in the chemistry of TM‐(κ²‐L,Si) complexes (L=N‐heterocycle, phosphine, N‐heterocyclic carbene, thioether, ester, silylether or tetrylene). The most common synthetic method has been the oxidative addition of the Si−H bond to the metal center assisted by the coordination of L. The metal silicon bond distances in TM‐(κ²‐L,Si) complexes are in the range of metal‐silyl bond distances. TM‐(κ²‐L,Si) complexes have proven to be effective catalysts for hydrosilylation and/or hydrogenation of unsaturated molecules among other processes.
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