Active commuting (e.g., walking and cycling to work) is beneficial for the population and environmental health and therefore can help to tackle current challenges of humanity, which are recognised in the 2030 Agenda for Sustainable Development. For planning public health interventions and active travel policies, it is necessary to identify correlates and determinants of active commuting. Currently, it is unknown whether specific personality traits are related to commuting behaviours. This study investigated the relationship between active commuting and several personal and environmental correlates, including broad personality traits. Therefore, cross-sectional data from the ‘Healthy On The way’ (HOTway) study were analysed. Information about correlates and commuting modes (active: walking, cycling; passive: car, motorbike, public transport) were collected via an online survey. Potential correlates were: socio-demographics (age, gender, education, student status, income, marital status), body mass index, physical activity, and psychological (extraversion, neuroticism, conscientiousness, well-being, perceived stress, attitudes towards commuting modes), and environmental (commuting time, traffic volume, perceived built environment) variables. Logistic regression models were used to test the association between each correlate and active commuting. In the multivariable model, a positive attitude towards cycling [odds ratio (OR) = 1.04, 95% confidence interval (CI): 1.02–1.06] was linked to higher odds of active commuting while older age (OR = 0.93, 95% CI: 0.88–0.98), a positive attitude towards car use (OR = 0.97, 95% CI: 0.95–0.99), greater commuting time (OR = 0.89, 95% CI: 0.84–0.94), being more affected by traffic volume (OR = 0.72, 95% CI: 0.58–0.89) and greater pleasantness of the neighbourhood environment (OR = 0.74, 95% CI: 0.57–0.97) were linked to lower odds of active commuting. Several correlates were identified but personality traits were not related to active commuting. This might indicate that major socio-demographic and environmental factors are more relevant for differences in commuting behaviours. The identified correlates can help in the design of future public health interventions and active travel policies to reduce environmental degradation and improve population health.