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Improving Compressed Laterite Bricks using Powdered Eggshells Improving Compressed Laterite Bricks using Powdered Eggshells

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3 WASH Engineer, Global Communities, Ghana-ABSTRACT-Eggshells are notable agricultural wastes indiscriminately disposed on the environment. Coupled with their foul smell they tend to create an unpleasant environment wherever they could be found. As a way of improving this situation, an alternative use for these products have found identified by using it to improve the engineering properties of compressed laterite bricks for masonry purposes. This paper reports the results of a study evaluating the use of powdered eggshells on the compressive strength and durability characteristics of compressed laterite bricks. Laterite bricks were produced with varying quantities of eggshells which comprised of 0%, 10%, 20%, 30% and 40% by weight of laterite. Compressed laterite bricks showed improvements in all the tests conducted after the inclusion of the powdered eggshells. Powdered eggshells were deemed appropriate for improving the general characteristics for compressed bricks although the optimum quantity was attained at 30%.
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Improving Compressed Laterite
Bricks using Powdered Eggshells
Peter Paa-Kofi Yalley
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The International Journal Of Engineering And Science (IJES)
|| Volume || 5 || Issue || 4 || Pages || PP -65-70|| 2016 ||
ISSN (e): 2319 1813 ISSN (p): 2319 1805
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Improving Compressed Laterite Bricks using Powdered Eggshells
Francis Adogla1, Peter Paa Kofi Yalley2, Moses Arkoh3
1Project Engineer/Supervisor, Wilhelm Building and Civil Works Limited
2Department of Design and Technology Education, University of Education, Kumasi
3WASH Engineer, Global Communities, Ghana
--------------------------------------------------------ABSTRACT-----------------------------------------------------------
Eggshells are notable agricultural wastes indiscriminately disposed on the environment. Coupled with their foul
smell they tend to create an unpleasant environment wherever they could be found. As a way of improving this
situation, an alternative use for these products have found identified by using it to improve the engineering
properties of compressed laterite bricks for masonry purposes. This paper reports the results of a study
evaluating the use of powdered eggshells on the compressive strength and durability characteristics of
compressed laterite bricks. Laterite bricks were produced with varying quantities of eggshells which comprised
of 0%, 10%, 20%, 30% and 40% by weight of laterite. Compressed laterite bricks showed improvements in all
the tests conducted after the inclusion of the powdered eggshells. Powdered eggshells were deemed appropriate
for improving the general characteristics for compressed bricks although the optimum quantity was attained at
30%.
Keywords Compressed bricks, laterite, powdered eggshells, soil improvement.
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Date of Submission: 01 April 2016 Date of Accepted: 14 April 2016
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I. INTRODUCTION
The focus of a good national development is to look inward with the intent of mobilizing all natural resources for
economic purposes. Although, one of the policy thrusts of governments over the years in Ghana has been to
provide affordable housing for the citizenry. Studies have indicated that, this has hardly materialized due to the
billowing prices of conventional building materials. Due to this, studies and researches have been focused on
indigenous materials which can adequately wholly or partially replace conventional walling units such as
sandcrete blocks and bricks in the building construction industry.
Such indigenous alternative is the use of laterite which for years has been a dependable building material for
various types of houses with notable advantages especially in Sub-Saharan Africa. Although, laterite is one of
the naturally occurring building materials in Ghana it potentials are yet to be fully exploited. Major hindrances to
its use for building purposes have been attributed to its low compressive strength and its vulnerability to
moisture especially in its compressed (unburnt) state.
Although, laterites used for producing bricks for masonry walls have been improved by the use of cement,
bitumen or lime the quest for alternative cost effective replacement materials cannot be underrated due to their
price hikes. Studies (King’ori, 2011 Gowsika et al., 2014; Karthick et al., 2014; Bashir and Manusamy, 2015)
have over the years revealed that the chemical composition of lime is relatively similar to the of poultry
eggshells indicating the potential that they could also be effectively recycled to improve the engineering
properties of laterites. Eggshells are residues from the poultry industry and more specifically a popular waste
found in homes, restaurants and fast foods industries. These residues possess environmental nuisance as they
increase the cost of managing disposal sites, creates foul smell and flies in areas where they are found in large
quantities. The shells of poultry eggs according to Murakami and Rodrigues (2007) are approximately 11% of
the total weight of the egg. Studies (Hassan et al., 2012; Dhaliwal et al., 2013) conducted on eggshells shows
high calcium contents ranging between 94% and 98% whiles the reminder consists of other micro elements such
as sodium, magnesium, phosphorus, boron and carbon in traced amounts. King’ori (2011) reiterated that the
calcium content found in eggshells is more absorbable than those from limestone or coral sources.
The concept of utilizing eggshells to improve compressed laterites bricks tends not only to improve the
engineering properties of the bricks but also reduce wastes and associated costs and lessen landfills.
Strategically, this alternative use of eggshells could create substantial revenue for both potential recyclers and
communities where poultry farming is their priority. Even though, eggshells are common wastes materials in
Ghana, its suitability as a laterite improving material have not been fully investigated. This study sorts to explore
the feasibility of utilizing powdered eggshells to improve the properties of compressed laterite bricks for
masonry purposes.
Improving Compressed Laterite Bricks using...
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II. EXPERIMENTAL MATERIALS AND METHODS
The main materials used in this study were laterite and eggshells whiles water was used for mixing. The various
materials have been discussed in this section.
2.1 Processing of Laterite
The laterite samples used in the study were sourced from an excavation pit in Cape Coast where laterites are
obtained on commercial basis for construction purposes. Laterite samples were bagged and taken to the
laboratory before processing. The materials were sieved using 10mm mesh to eliminate stones and gravels which
tend to bond poorly when producing compressed bricks Oshodi (2004). The index properties of the laterite were
investigated according to BS 1377 (1990) before bricks production.
2.2 Processing of Eggshells
The empty broken eggshells were procured from local restaurants and fast food vendors within the Cape Coast
municipality. The broken eggshells (as shown in Fig. 1) were boiled in water to remove any egg residue which
might still be attached onto the surface of the shells membrane before drying them in the sun. Dried eggshells
were milled into fine particles using a laboratory milling machine (grinder) as depicted in Figure 1.
Figure 1 Processing of Eggshells (Before and after powdering)
2.3 Water
Drinkable water without dirt or deleterious materials was used in the mixing.
2.4 Chemical Composition of Powdered Eggshells
The Oxides present in the powdered eggshells were analysed using the X-ray Fluorescence technique. This was
done by mixing 4.0g of the ash sample homogenously with 0.9 grams of Hoechst wax in a mill before pressing
with a hydraulic press at 15 tons to a 32mm pellet. Multi-element determinations from the prepared pellet were
carried out using an energy-dispersive polarizing X-ray Fluorescence Spectrometer (Manu et al., 2015). The
compositions of the powdered eggshells have been presented in Table 3.
2.5 Preparation of Compressed bricks Specimen
Batching of materials was done by weight. The powdered eggshells and laterite samples were thoroughly mixed
together in different proportions by varying the eggshells contents. The powdered eggshells were added in stages
of 10%; thus ranging from 0% (being the least) to the highest of 40%. This was done to determine the influence
of the powdered eggshells on the compressed bricks so that other higher quantities could be predicted.
Mixing of materials was done in a clean tray before a predetermined water content (attained after conducting the
compaction test) was added. Table 1 demonstrates the quantity of each sample used in the production of each
batch. The carefully batched materials were initially mixed before adding water. Further, mixing was done until a
wet homogenous material was obtained. The moist specimen was placed in a metal mould box with dimension;
200mm × 100mm × 75mm after which it was compressed using a manually operated moulding machine.
After compacting, the compressed bricks were covered with plastic sheets under ambient conditions with the sole
aim of reducing rapid evaporation of moisture which could cause dry shrinkage, cracks and other undesirable
defects on the bricks. The compressed bricks were cured for 28days before investigating their properties and
suitability for masonry applications.
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Table 1 Quantity of Materials used for moulding each Batch
Variations
Laterite (kg)
Eggshells (kg)
Laterite with 0% PES (Control batch)
7.88
0
Laterite with 10% PES
7.88
0.79
Laterite with 20% PES
7.88
1.58
Laterite with 30% PES
7.88
2.36
Laterite with 40% PES
7.88
3.15
2.6 Testing of Compressed bricks
The study sorts to determine the suitability of using eggshells to improve the properties of compressed bricks.
Tests conducted comprised of the crushing tests, water absorption by capillarity rise and abrasion resistances
characteristics. The dry density of the bricks was also explored. In all, five bricks specimens with good
appearance were randomly selected from each batch for each test as stipulated by most standards. All
experimental studies were conducted after curing the compressed bricks for 28 days.
The dry densities of the compressed bricks were taken after drying the specimen in the oven for 24 hours at a
temperature of 105ºC. The compressive strength of the bricks were conducted as per GS 297-1 (2000)
specification. The durability properties studied which included the water absorption and abrasion resistance
characteristics were investigated as specified by the African Regional Standards for Compressed Earth Blocks
(Adam and Agip, 2004).
III. EXPERIMENTAL RESULTS AND DISCUSSIONS
Preliminary tests on the laterite revealed the following (as presented in Table 2) as the index properties.
Generally, the laterite used was found suitable for construction and other engineering applications as it had
sufficient amount of clay content to ensure effective bonding between the various particles within the soil matrix.
Calcium oxide (CaO) was detected as the highest oxide in the powdered eggshells as seen in other studies
(Karthick et al., 2014; Gowsika, 2014).
Table 2: Properties of Laterite used
Properties
Results
Particle size Classification
Cu = 2.60: Cc = 0.83
Plasticity Chart Classification
Organic clay of high plasticity
Colour
Reddish-Brown
Natural moisture content
5.1%
Organic Matter
1.10%
Free Swell Index
10.7%
Specific Gravity
2.58
Linear Shrinkage
8.4%
Liquid Limit
54.5%
Plastic Limit
37.5%
Plasticity index
17%
Clay Content
14.8%
Silt Content
29.6%
Sand / Gravel content
55.6%
Maximum Dry Density
2088g/cm3
Optimum Moisture Content
7.1%
Table 3 Oxide present in the Powdered Eggshells
Oxides Present
Result
Calcium Oxide (CaO)
64.83%
Sodium Dioxide (Na2o)
1.48%
Silicon Dioxide (SiO2)
0.79%
Magnesia Oxide (MgO)
0.29%
Aluminium (Al2O3)
0.13%
Chlorine (Cl)
0.09%
Potassium (K2O)
0.08%
Sulphate (SO3)
0.06%
Ferrous Oxide (Fe203)
0.06%
% Retained in 425um
14.4%
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Table 4: Properties of Compressed Laterites samples with Powdered Eggshells
Batch
Density
Compressive
Strength (N/mm2)
Water absorption
Abrasion
resistance
(Kg/m3)
28 days
56 days
(g/cm2min)
(cm2/g)
Laterite + 0% PES
1976.44
1.79
1.84
16.89
0.32
Laterite +10% PES
2001.12
2.36
2.67
15.54
0.50
Laterite +20% PES
2014.6
2.74
3.01
6.06
0.97
Laterite +30% PES
2043.2
2.87
3.05
3.94
1.56
Laterite +40% PES
2044.2
1.82
2.72
7.23
0.53
Compressive Strength: The test was to determine the strength development of specimens with varying
eggshells at both primary and secondary curing ages (28 and 56 days curing ages). Compressive strength is
arguably the most important requirement a walling unit for both load and non-load bearing walls must have. The
compressive strengths of brick specimens generally increased as the eggshells contents increased. Data also
showed an increase as the curing ages increased from 28 days to 56 days a phenomenon common with materials
used as binders such as cement, lime, fly ash etc.
After 28 days curing age, only compressed laterite bricks with 20% and 30% eggshell content met the
acceptability limit for masonry purposes as stipulated by GS 297-1 (2000). As the curing age increased, only
laterite without eggshells failed to meet the recommended minimum compressive strength of 2.5N/mm2.
The increase in the strength characteristics with increasing eggshells was attributed to the calcium ions which
react with the clay to form cementitious matrix thus improving the bond between the soil particles.
Density: Bricks used in the study had their densities within the range of 1500kg/m3 2400kg/m3 as specified by
BS 6073 for dense aggregates masonry units. The mean dry density of the ricks increased steadily as the
eggshells content increased as depicted in Table 4. The increase in the dry density of the bricks could be
attributed to the increasing eggshell content which influenced the overall density of the batch as the quantity
increased.
Water Absorption by Capillarity: This test investigated the ability of the bricks specimen to absorb water after
partially immersing them in water for 10 minutes. Generally, specimen with high coefficients indicates high
absorption rate thus high porosity whiles specimen with low coefficients are less porous thus absorbing lesser
amount of water. Data as presented in Table 4 shows a gradual dip as the eggshells increased from 0% to 30%
before rising slightly. This phenomenon associated with increasing eggshells could be attributed to the
decreasing volume of voids which have been filled with the eggshell particles therefore minimising the
permeability of the bricks. It could also be affiliated to the increasing calcium ions which tend to improve the
cementing properties within the soil matrix similar to that of conventional lime.
Abrasion Resistance: Bricks specimens were subjected to abrasion by brushing for 60 continuous cycles using
a wire brush. Higher abrasion resistance coefficients showed higher bond strength between particles whereas
specimen exhibiting lower coefficients showed weaker bonds. Data derived from the study (in Table 4) showed
that bricks with 30% eggshells exhibited higher resistance to abrasion (wear) whiles the control batch (without
eggshells) were showed the least resistance to wear.
IV. CONCLUSION
The results of the study showed that the powdered eggshells has substantial amount of Calcium compounds
(64.8%). At 28 days curing age, compressive strength of the bricks increased by 31.8%, 53.7%, 60.3% and 1.6%
as the eggshells content were 10%, 20%, 30% and 40% respectively. The powdered eggshells significantly
improved the density, compressive strength and durability characteristics of the laterite bricks when compared
with the conventional compressed laterite bricks. Data from the study revealed that the optimum amount of
powdered eggshells was attained after 30% addition. Furthermore, the use of powdered eggshells for
construction applications could reduce environmental pollution, and improve the quality of compressed laterite
bricks. This can also help to effectively manage this agro-waste material by turning it into an additive or
stabilizer.
Further studies are recommended to be conducted using eggshells ash as a stabilizer for soils with different
properties for masonry purposes.
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[2]. I. Y., Manu, E., Asiedu, P. P. K., Yalley, K. S., Denutsui, Feasibility of using cocoa pod husk ash as a stabilizer in the production
of compressed earth bricks. International Journal of Engineering Research and General Science, 3(6), 2015, 514 524.
[3]. J. S. Dhaliwal, G. S. Kapur and S. Shashikant, Chicken Eggshell as a Bio filler, Polypropylene Composites Society of Plastics
Engineers, 2013.
[4]. S. B., Hassan, V. S. Aigbodion, and S. N. Patrick, Development of polyester/eggshell particulate composites. Tribology in Industry.
34(4), 2012, 217-225.
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27(3), 2007, 658 662.
[6]. J. Karthick, R. Jeyanthi, and M. Petchiyammal, Experimental Study on Usage of Eggshell as Partial Replacement for Sand in
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[7]. D., Gowsika, , S. Sarankokila, K. Sargunan, Experimental investigation of eggshell powder as partial replacement with cement in
concrete. International Journal of Engineering Trends and Technology, 14(2), 2014, 65 68.
[8]. Ghana Standard Authority, Building and construction materials-specification for blocks. Part 1: Precast sandcrete blocks (GS 297-
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[9]. E. A. Adam, and A. R. A. Agip, Compressed stabilized earth blocks manufactured in Sudan (United Nations Education Scientific
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[11]. A, S. M. Bashir, and Y. Manusamy, Characterization of raw eggshell powder as a good bio-filler. Journal of Engineering Research
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[12]. O. R. Oshodi, Techniques of producing and dry stacking interlocking blocks (Nigerian Building and Road Research Institute
Workshop on local Building Materials. Ota, Ogun State Nigeria, 2004).
... Abrasion resistance also known as durability test was performed in order to determine the lifetime of specimens according to NF EN 530 [43] standard. This resistance is calculated by using the formula of Eq. (2). ...
... But globally, the decrease of water absorption after adding of cement can be explained by the fact that cement binds laterites and sand particles together and thereby reduces the size of the voids or pores through water could enter into the blocks [24]. Moreover, the presence of oxides tends to improve the cementing properties within soil matrix [2]. However, the NC 102-115 [40] standard recommends absorption rates lower than 15%. ...
... However, taking into account the minimum resistance of 4 MPa prescribed by CRATerre [13] and NC 102-115 [40], all cement-stabilized materials above 4% cement meet the minimum requirements except for TH materials. The high compressive strength values can be explained by the increased proportion of cement, which ensures good cohesion between the different fractions by reducing the volume of voids [2]. The secondary oxides then react with the cement to increase its binding properties [65]. ...
... Abrasion resistance also known as durability test was performed in order to determine the lifetime of specimens according to NF EN 530 [43] standard. This resistance is calculated by using the formula of Eq. (2). ...
... But globally, the decrease of water absorption after adding of cement can be explained by the fact that cement binds laterites and sand particles together and thereby reduces the size of the voids or pores through water could enter into the blocks [24]. Moreover, the presence of oxides tends to improve the cementing properties within soil matrix [2]. However, the NC 102-115 [40] standard recommends absorption rates lower than 15%. ...
... However, taking into account the minimum resistance of 4 MPa prescribed by CRATerre [13] and NC 102-115 [40], all cement-stabilized materials above 4% cement meet the minimum requirements except for TH materials. The high compressive strength values can be explained by the increased proportion of cement, which ensures good cohesion between the different fractions by reducing the volume of voids [2]. The secondary oxides then react with the cement to increase its binding properties [65]. ...
... The improper disposal of eggshell debris is an intractable problem that is made worse by the noxious stench it emits [28]. One possible solution to this issue is to use eggshell powder (ESP) in construction materials [29][30][31][32][33]. Limited investigations have been carried out to examine the impact of ESP-modified cementitious composites in an aggressive environment. ...
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The effectiveness of cementitious composites in an aggressive environment is the primary issue since their performance deteriorates when exposed to harmful elements. Also, to promote sustainable building materials, waste materials are gaining popularity. This work employed testing followed by machine learning (ML) modeling to study the impact of eggshell powder (ESP) in cement mortar exposed to an acidic environment. The ESP was used to partially replace cement and sand, and the samples were subjected to a 5% H2SO4 solution. The dataset obtained through experimentation was utilized to construct ML-based predictive models for the reduction in compressive strength (CS) of cement mortar. According to the test results, the integration of ESP controlled the loss of cement mortar when used at lower substitutional levels. The lowest reduction in CS was seen when ESP was used as a cement substitute of 5%, which was up to 7.71% lower, and as a sand substitute of 7.5%, which was up to 7.03% lower than the same mix placed in plain water as a reference. Furthermore, the developed ML models exhibited a satisfactory level of concurrence with the experimental findings, thereby indicating their potential applicability in assessing the CS reduction percentage in cement mortar that incorporates ESP subsequent to an acid attack.
... Taking this postulation into account, it is envisaged that calcined eggshell powder (ESP) can be used as a fat clay ameliorator similar to lime and cement. Considering the chemical composition of eggshell, some research has been carried out to use ESP as a partial replacement of cement in concrete, as an additive for the enhancement of concrete properties, as a soil stabilizer and as an alternative recycled material to be used in soil-cement brick to improve its mechanical properties (Amaral et al. 2013;Pliya and Cree 2015;Etim et al. 2017;Parthasarathi et al. 2017;Tan et al. 2017;Adogla et al. 2016;Ahmed et al. 2016;Bensaifi et al. 2019;Oluwatuyi et al. 2018;Singh and Arora 2019). A detailed study is still required to investigate the impact of ESP on different physical properties, chemical properties and macro-geotechnical vulnerabilities of fat clay, i.e., consistency, compaction, strength, stiffness and volumetric change response. ...
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This study explores the potential of using eggshell food waste by valorizing it through calcination in the form of eggshell powder (ESP) to mitigate the geotechnical vulnerabilities of the fat clay. The physical, mechanical, volumetric change and micro-stabilization responses of treated soil samples were examined considering varying ESP content and curing periods (kc). The present study observed a 62% and 17% decrease in the plasticity index (PI) and liquid limit (LL) of the fat clay with 10% ESP content, respectively. Meanwhile, a significant increase was noted in unconfined compressive strength (qu), elastic modulus (E50), and California bearing ratio (CBR) with the augmentation of ESP in the fat clay. Furthermore, the increase in strength parameters became much more prominent when samples were subjected to prolonged kc. In addition, the ESP-treated fat clay conspicuously demonstrated a reduced deformation, swelling potential and compressibility due to the formation of a hardened soil skeleton. Moreover, the optimal dosage of ESP for the selected soil was established to be 10% as it was observed that the strength and compressibility responses improved significantly up to this ESP concentration in soil, while beyond this threshold, any further improvement in these properties almost ceased. Furthermore, the mineralogical and microstructural analyses revealed the formation of cementitious content in fat clay, namely the hydrates of calcium silicate (CSH) and calcium aluminate (CAH), resulting from a pozzolanic reaction between the silica and calcium oxide present in the fat clay and the calcined ESP, respectively.
... Inappropriate dumping of eggshell waste presents an intractable difficulty and exacerbates the situation due to its offensive odor [17]. The application of eggshell powder (ESP) in building materials might aid in mitigating this problem [18,19]. CaCO 3 is an essential constituent of eggshells [20] and is essential for the growth of calcium-silicate-hydrate (CeSeH) gel in cementitious composites. ...
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... Adapting and complying with the standard characteristic of the burnt clay bricks allow for According to studies preference, and discrimination in using earth-based materials for construction and building projects were observed to cut across the end-users and the builders [10,13]. Some challenges associated with their use include lack of compressive strength, having low resistance to abrasion and highly susceptible to water ingress [14][15]. Beamish and Donovan [12] highlighted form, size and quality as factors contributing to the preference and discrimination of locally made burnt clay bricks. ...
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... Adapting and complying with the standard characteristic of the burnt clay bricks allow for According to studies preference, and discrimination in using earth-based materials for construction and building projects were observed to cut across the end-users and the builders [10,13]. Some challenges associated with their use include lack of compressive strength, having low resistance to abrasion and highly susceptible to water ingress [14][15]. Beamish and Donovan [12] highlighted form, size and quality as factors contributing to the preference and discrimination of locally made burnt clay bricks. ...
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The acceptability of fundamental features of burnt clay bricks is a control course obtained during the production process. The applied knowledge and skills in production technology of burnt clay bricks were subjectively evaluated and quantified. Multi-method research approaches were adopted which included questionnaire instruments and experimental analysis. Assessing the source of knowledge and skill, the experience of labour and team capacity showed that most of the participants have been in the burnt brick production business for 6-10 years (37.3%) through the tutelage of their friends (72.9%) and participated in the groups of 4-5 people (25.4%). There was a deficiency in knowledge and skills needed for forming and firing stages for standard quality burnt clay brick but only effective in the extraction and preparation stage but deficient in shaping, drying, building the field kiln and firing the field kiln. The independent-sample t-test showed that the mean of the measured water absorption value of the locally produced burnt clay brick was statistically higher (mean ± SD = 29.51±0.58) than the minimum allowable standard water absorption value (mean ± SD = 20.00±0.0) significant at p = 0.00. A similar observation was made for compressive strength as the measured mean compressive strength value for the locally produced burnt clay brick was 3.98±0.30 N/mm² which was statistically higher than 3.5 N/mm². However, the dimensions of the burnt clay bricks were with the tolerance of approximately 5% for locally produced bricks. Considering the importance of good quality burnt clay bricks in construction local producers need a training.
... The granulometric curve of the subjected soil has been given in Fig. 1. Being a waste, Eggshells were used in powdery form in this study and its typical chemical compositions proposed by Adogla et al. [25] have been given in Table 2. 425µ sieved ESP was used to maintain a uniform distribution and homogeneity in matrix. Local vendor-provided product properties of alkali activator (NaCl) have been tabulated in Table 3. ...
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Transport facilities are the backbone of the economy of any country. So, the roads and rail tracks must be capable to perform accordingly. At a high altitude of hilly areas -25C is a usual temperature and this can happen once every year. This freezing temperature deteriorates the soil properties beneath a pavement at a premature age. Among a series of experiments conducted on the consequences of stabilizers, waste materials, and/or different fibers on various engineering properties of different soils; only a few claims the quantification of the durability properties under harsh weather conditions. The current research article represents the rational evaluation of stabilized fine-grained soil and encouragescorrelation-based equations. Taguchi method was used to design the experiments and a standard L9 orthogonal array (OA) was formed using three factors having three degrees of each supplement. 3%-9% eggshell powder (ESP), 0.05%-0.15% polypropylene fiber (PPF), and 2%-6% sodium chloride (NaCl) by total dry weight of soil were used to prepare the specimens. Experiments were conducted on both parent and treated soil specimens. Experimental results were used to develop a correlation between UCS and mass loss (ML). Results showed an insignificant correlation between strength and durability properties of soil specimens under harsh conditions. But the additives showed a greater resistance against FT effect with minimum mass loss in stabilized soil samples. Additives produced almost 90%-98% resistance against mass loss after 10 FT cycles. Results obtained from this study might be used for subgrade improvement during pavement construction in cold regions. All the stabilizers used in the current study were non-hazardous so, the research promises an environment-friendly and economic solution for the soil strength and durability-related problems associated with cold regions.
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Though the European Commission classifies eggshell as a hazardous material, using eggshell powder in place of cement can aid in waste reduction and contribute to sustainability initiatives. Eggshell powder replaces cement in concrete manufacturing due to its high calcium content. Eggshell is impermeable in nature, so it helps in reducing the permeability of concrete. Eggshell powder fastens the process of hydration of cement by the formation of monocarboaluminate during the mixing of material at the time of casting. This paper includes a detailed study of the process production of eggshell powder, the properties of eggshell powder concrete, and the relationship between different properties has been determined. In addition, Artifical Neural Network approach has been used to predict the strength of eggshell powder concrete to reduce the labour cost and experimental time. In the end, microstructure of eggshell powder and its application in various engineering products have been reviewed. After analyzing the qualities of eggshell powder concrete, it was determined that replacing up to 20% of the cement in concrete with eggshell powder increases the material's strength. The ANN model's results also demonstrate its effectiveness in forecasting the strength of eggshell powder concrete, with an R2 value of 0.96. So, it clearly shows that eggshell powder can be used to replace cement to improve the properties of concrete and reduce the percentage of cement usage. Finally, the conclusions and discussion of this study addressed the eco-friendly utilization of eggshell powder in construction applications.
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The development of Polyester/Eggshell particulate composites has been carried out. Uncarbonized and carbonized eggshell particles were used as reinforcement in polyester matrix. 10 to 50 wt% eggshell particles at intervals of 10 wt% were added to polyester as reinforcement. The microstructural analyses of the polyester/eggshell particulate composites were carried out using SEM and EDS. The mechanical properties and density were carried out by standard methods. The results showed that the density and hardness values of the polyester/eggshell particulate composite increased steadily with increasing eggshell addition. The tensile strength increased from 15.182 N/mm2 at 0 wt% eggshell addition to a maximum of 23.4 N/mm2 at 40 wt% eggshell addition for uncarbonized eggshell; while it increased to a maximum of 28.378 N/mm2 at 20 wt% eggshell addition for carbonized eggshell. Compressive strength increased steadily from 90.3 N/mm2 at 0 wt% eggshell additions to a maximum of 103.6 at 50 wt% eggshell addition for uncarbonized eggshell and 116.5 N/mm2 at 50 % eggshell addition for carbonized eggshell. Hardness value increased from 91 HRF at 0 % eggshell addition to a maximum of 120.05 HRF at 50 wt% eggshell addition for uncarbonized eggshell and 149.45 HRF at 50 wt% eggshell for the carbonized eggshell. Flexural strength increased from 76.06 N/mm2 at 0 wt% eggshell addition to a maximum of 97.06 N/mm2 at 40 wt% eggshell addition for uncarbonized eggshell; however, it increased to a maximum of 106.66 N/mm2 at 20 wt% eggshell addition for the carbonized eggshell. The impact energy also increased from 0.1 Joules at 0 wt% eggshell addition to a maximum of 0.35 Joules at 30 wt% eggshell addition for uncarbonized eggshell; it however increased to a maximum of 0.45 Joules at 20 wt% eggshell addition for the carbonized eggshell. Hence the development of polyester/eggshell particulate composites material with good mechanical properties and light weight which is relevant to the electronics, auto and building industries has been achieved.
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Calcium carbonate, a pharmaceutical excipient, is widely used as diluent in solid dosage forms. It is also used as a base for medicinal and dental preparations, a buffering and dissolution aid for dispersible tablets, a food additive and a calcium supplement. Egg shells are a rich source of mineral salts, mainly calcium carbonate, which corresponds to about 94% of the shell. Layer farms produce large amounts of shells, whose final disposal poses a challenge from the environmental standpoint. This work was designed to evaluate the physicochemical and thermal properties of calcium carbonate obtained from egg shells. The findings indicated that calcium carbonate from egg shells can be used as an alternative pharmaceutical excipient.
Methods of test for soils for civil engineering properties
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E. A. Adam, and A. R. A. Agip, Compressed stabilized earth blocks manufactured in Sudan (United Nations Education Scientific and Cultural Organization, 2001)
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