Unlike the simpler and more limited vehicle automation systems of earlier generations, for which operation and safety could be defined by standards such as the Functional Safety Standard (ISO 26262), novel automated systems become increasingly complex to analyze due to the exploding number of possible Operational esign omain (O) configurations. To solve this problem, we propose a model-based validation framework that helps to build the safety argument for particular challenging scenarios. The proposed method combines a functional hierarchical decomposition approach that helps to understand the system's functioning principles and a dynamic probabilistic risk assessment algorithm to perform risk analysis. This methodology is tested in a complex system that consists of two automated vehicles that travel together as a platoon on a highway. Three relevant scenarios from this system are chosen and analyzed using the proposed method. Finally, we identify risks associated with the choice of acceleration/deceleration parameters, the presence of a communication link, and external vehicles interfering with the platoon.