Implementation of a prototype water electrolysis system as an alternative to produce hydrogen

Abstract and Figures

The objective of the development of the prototype or scale model of production of hydrogen and oxygen through the electrolysis process of water is to generate an alternative with a sustainable approach, which proposes the supply or source of energy initially with a direct current power source. replaceable in the future by a photovoltaic solar system. For the development of the prototype, it began with the academic compilation of information, then the model was made in CAD, followed by the need to integrate an electronic control system and a mechanical system to obtain the final model, materials were selected and used premises for the development of the two systems, the electronic and physical schematization was carried out, chaired by the assembly and field experimentation. It is important to highlight that the constructed scale model generates hydrogen and oxygen with a low current consumption and a constant voltage, the maximum point of gas generation is the maximum point of energy consumption and its relationship is almost linear.
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Implementation of A System to Produce Hydrogen by
Electrolysis of Water from a Switched Power Source
B E Tarazona-Romero1, R E Páez-Castro 1, Miguel Landunez-Yomayusa1, J-G
Ascanio Villabona1 and C-L Sandoval-Rodríguez1
1 Automation and Control Energy Systems Research Group (GISEAC), Faculty of
Natural Sciences and Engineering, Electromechanical engineering, Unidades
Tecnologicas de Santander (UTS), Student Street No 9-82, 680005, Bucaramanga,
Abstract. The objective of the development of the prototype or scale model of
production of hydrogen and oxygen through the electrolysis process of water is to
generate an alternative with a sustainable approach, which proposes the supply or
source of energy initially with a direct current power source. replaceable in the future
by a photovoltaic solar system. For the development of the prototype, it began with the
academic compilation of information, then the model was made in CAD, followed by
the need to integrate an electronic control system and a mechanical system to obtain
the final model, materials were selected and used premises for the development of the
two systems, the electronic and physical schematization was carried out, chaired by
the assembly and field experimentation. It is important to highlight that the
constructed scale model generates hydrogen and oxygen with a low current
consumption and a constant voltage, the maximum point of gas generation is the
maximum point of energy consumption and its relationship is almost linear.
1 Introduction
Electrolysis[1] is an electrochemical process[2] that uses electrical conductivity [3] of some
substances or materials to generate a non-spontaneous oxidation-reduction reaction [4] . Electrolysis
derives from electrolytes that are on ionic conductors of positive or negative loads that have the
ability to carry electrical energy, generate electrical conductivity in materials and substances [5] .
Water electrolysis requires water not to be in its pure state, as pure water is not conductive so it must
have some concentrations of salts and some minerals [6]
Electrolysis consists of the chemical decomposition of a substance by means of electricity (electro-
electricity and lysis - destruction) [7] . Due to the electric current circulating from the cathode
causing reduction, towards the oxidation anode, provided that between them a conductive substance
(electrolyte)is present[8]. For the production of electrolysis in water you need a dissolved
electrolyte[9] (to increase its conductivity) to introduce two internal electrodes [10] (anode and
cathode) being connected to a DC source, the electrolyte transformation of water into hydrogen and
oxygen will occur requiring high energy consumption, so it is only used for practical purposes
exceptionally. [11]
It is important to define the term renewable energy[12]: they are clean, endless energy sources that
differ from fossil fuels[13] especially in their diversity, abundance and willingness potential anywhere
on the planet, but mainly in that they do not cause greenhouse gases[14], nor polluting emissions[15] ,
therefore, it is proposed in this Paper how to produce hydrogen[16] from a small-scale electrolyze that
is powered by the energy generated by a DC source that simulates power through photovoltaic solar
panels[17]. The direct current source, will allow the fractionation of water molecules in oxygen and
hydrogen, the latter, will be used as an energy vector or serve as an energy storage system.[18] [12]
Thus, the main objective of this document is to present a small-scale prototype as an alternative to the
production of hydrogen by water electrolysis[19]; simulating the power supply of a photovoltaic
system through a conventional direct current source[20]. The present technological development of an
investigative nature, performs in an exploratory and descriptive way, the methodological development
of the model[21], through the implementation of an electrolyze that takes the current of a switched
power supply, which in the future can be replaced by a load regulator to receive power through
photovoltaic solar panels[22].
Considering the This Paper begins with the methodological development[23] implemented for the
construction of the prototype, as well as the description of the implemented materials. Followed by the
experimentation presented in section 3 where tests of operability and operation of the prototype are
carried out[24]. Subsequently, in section 4 the results are described and the functional behavior of the
system is analyzed, and. Finally, the most significant conclusions of the development of the prototype
are presented. Finally, this document will present a scale prototype of a hydrogen production system
from the electrolysis of water[25], fed with a direct current source as an alternative of operation
through photovoltaic solar panels as a sustainable and scalable prototype.
2 Methods and Materials
2.1 Methodology
For the development of a prototype at scale, Figure 1 presents the methodological workflow diagram,
beginning with the system sizing process, which initially requires an academic information search
where the initial need to develop CAD modeling, with two integrated systems for the proper
functioning of the prototype: electronic control system and mechanical system. The first mentioned
system must satisfy the needs of the project and control the scale model, selected as the central axis to
carry out this task, the Atmega 328p microcontroller is identified, compatible with Arduino systems;
simply remove the original microcontroller from the card and mount the Atmega 328p, it also
highlights the flexibility to program the new microcontroller, since the free Arduino software allows
its configuration. Also, a PCB board that connects to the microcontroller is required to have all the
connections in one module.
Figure 1. Working diagram
On the other hand, it is necessary to build the mechanical section of the prototype that is
fundamentally responsible for carrying out the physical electrolysis process and consists in the
development of hydrogen cells (HHO); They are basically made up of two positive, three negative and
sixteen neutral plates separated from each other by a neoprene gasket that separates the anode and the
cathode, so that the gas generated in the anode (oxygen) does not mix with that generated in the
cathode (hydrogen). This system will be fed by a water tank, connected through hoses. The prototype
has temperature and level sensors, which send signals to the microcontroller, which in turn processes
them and transmits them to a visual indicator or LCD screen. After the electrolysis process is run and
the hydrogen and oxygen are obtained, all this will be deposited in a bubbling tank made of PVC. The
hydrogen and oxygen generated by the electrolysis process will be measured by rotameters, these will
be responsible for defining the flow generated
After developing the control system and mechanical system, the two are integrated into a compact
module built with 1-inch structural tubes. Additionally, a satin stainless-steel plate was installed for
mounting the aforementioned measuring instruments, indicator and two rotameters to measure flow.
After assembling the prototype, the sensors or measuring instruments are calibrated. Finally, field tests
or final experimentation are carried out, obtaining promising measurements of hydrogen and oxygen.
2.2 Materials
This section describes in detail the materials used for the development of the electronic control
systems and the mechanical system. It begins with the CAD modelling of the module, preceded by the
description of its components, to finally present the flow diagram of the development of the electronic
control system and the final connection of the physical components of the prototype.
2.2.1. CAD Modelling
The 3D schematization of the module was developed after the collection of information using the
CAD tool or SolidWorks Software, dimensioning it on a real scale in order to facilitate its
construction. Modeling integrates mechanical and electronic control systems; Basically, the elements
that compose it are: H2 cell, structure, water tank, instrument panel, power supply, control panel,
hydraulic and gas system, among others (See Figure 2).
Figure 2. CAD modelling of the model
2.2.2. Control System
The materials required for the development of the electronic control system are described below:
PCB board
A printed circuit board (PCB) as shown in Figure 3 is a sheet of rigid insulating material, covered by
copper tracks on one or both sides to serve as connections between the various components to be
mounted on it. Depending on the type of plate, copper can in turn be protected by a layer of
photosensitive resin.[26]. For our model it was necessary to develop it for integration with the
Figure 3. Printed circuit
Atmega 328-p microcontroller
Sensors and other electronic elements generate digital signals, these signals have to be received and
mapped to the required values. To solve this is used the Atmega 328-p microcontroller, shown in
Error: Reference source not found4, this on a PCB board previously designed for operation and easy
compatibility with its electronic components, simplifying connections and giving a better appearance
to the module. It is important to note that this microcontroller is compatible with the Arduino platform,
being thus easy to program.
Figure 4. Atmega 328P microcontroller.[27]
Programming IDE
The source code for the IDE is published under the GNU General Public License. The IDE supports C
and C++ languages using special code structuring rules. The IDE supplies a software library of the
Wiring project, which provides common I/O procedures, the user-written code requires only basic and
simple functions. The IDE uses the avrdude program to convert the executable code into a
hexadecimal-encoded text file that is loaded into board Atmega using a loading program into the board
Current Sensor to Arduino
The hydrogen gas flow of an electrolyte cell is directly proportional to the intensity of the consumed
current. In order to measure the current consuming the cell, it is necessary to implement the module an
ammeter to know that variable. The maximum current to be measured in the cell is 20 amps, little less
than the maximum current of the power supply. Therefore, the ACS712 current sensor of allegro (See
Error: Reference source not found5), which meets most requirements, will be used. This Hall effect
current sensor provides the most economical solution with a fairly acceptable accuracy to measure the
current intensity of the cell and with the appropriate size to adapt it to a PCB board being also
compatible with it.[29]
Figure 5. ACS712 current sensor for Arduino. [30]
MAX6675 module for thermocouple (type K)
The MAX6675 thermocouple sensor is a specialized analog-to-digital signal converter for type K
thermocouples. With this module it is possible to easily connect a thermocouple to any microcontroller
via a one-way SPI interface. Within this small circuit is the electronics needed to amplify, compensate
and convert to digital the voltage generated by the thermocouple, which makes it very easy to connect
a thermocouple to a microcontroller. The only problem is that this circuit is only achieved in SOIC
encapsulation, so it is not so easy to use it in the protoboard. However, in this module we find the
MAX6675 with all the necessary electronics and the appropriate terminals to facilitate its use. [31]
Figure 6. Max6675 module for thermocouple (type K) [31]
Type K thermocouple
This sensor supplies an electrical voltage depending on the temperature. A thermocouple doesn’t
directly measure temperatures, but the temperature difference between the hot end and the cold end.
The combination of different metals induces certain signals that allow effective temperature
measurement. Thermocouple probes vary depending on the requirements, in our case we opted for a
thermocouple with a 10 mm probe for the tank and a thermocouple with a 100 mm probe for the cell.
The rotameter or flowmeter is an industrial flow meter used to measure the flow of liquids and gases.
The rotameter consists of a tube and a float. The float's response to flow changes is linear, and a flow
range of 10 to 1 is standard[33]. Conclusively the ZEAST rotameter shown in Figure 77 is chosen, this
one with a measurement range of 3 LPM (liters per minute) being among the desired measurement
ranges for small-scale prototyping
Figure 7. Rotameters
2.2.3. Mechanical system
H2 cell
The cell, shown in Figure 88 consists of two positives exposed, three negative and sixteen neutral
ones separated from each other by neoprene packaging and a separating membrane, two connections
for liquid inlet and two for gas outlet, two 16 x 16 x 0.8 cm acrylic plates and two reinforcement
Figure 8. H2 Cell
Water tank
The tank shall be connected to the cell and the bubblers by means of a hose circuit. In addition, it will
have a temperature sensor and a level sensor that will send a signal to the microcontroller when the
water level is very low.
Deposit bubblers
The bubbling devices are the devices responsible for removing excess water that comes out of the cell,
as well as protecting it from possible gas combustion, which would cause a dangerous explosion. The
bubblers were manually made from PVC pipe as it is a corrosion-resistant and easy-to-machine
Power supply
This 300w power supply will be responsible for sending electrical energy to the cells, so that they can
perform the electrochemical electrolysis process.
Instrument panel
The instrument panel is where the flow meters, LCD display, LED indicators, control buttons and
power switch will go. The material of this is satin stainless steel, for greater durability.
Figure 9. Instrument panel
The frame or chassis where the elements that make up the system are housed in general consists
mainly of a 3/4-inch square tube (See Figure 10).
Figure 10. Structure
2.2.4. Flow diagram of electronic control system
The connection diagram shown in Figure 11. , is made taking into account the requirements for the
operation of the electronic system in general, this circuit is proposed that will connect the temperature
sensors, level sensor, LCD display and other elements, to the microcontroller atmega 328P, this for the
time of the assembly have a correct idea of what are the connection pins between the different devices
Figure 11. Flow diagram of electronic control system
2.2.5. Module connection diagram
After CAD modeling, the identification of the elements of the module, the development of the
electronic control system and its schematization, it is important to highlight the physical connection
diagram of the module presented in Figure 12, which allows the assembly to be known in detail. made
at the time of building the module.
It is important to highlight in the connection diagram, that in the H2 cell is where all the
electrochemical process happens. Which is powered by a water tank that integrates a level sensor. The
hydrogen and oxygen produced are deposited in a special container called "bubbling tank", being
essential to know the outflow of gases generated by the H2 cell through a pair of flowmeters or
rotameters, connected to the bubbling out.
Figure 12. Model connection diagram
3. Experimentation
The experimentation process involves the functional checking of the different sensors implemented in
the system, in order to guarantee that the measurements indicated on the module or LCD screen are
correct. Starting, with the level sensor, in which manual tests are carried out, checking its proper
operation. Subsequently, the tank and cell temperature sensors are verified, both must have the same or
very close values when the cell is empty; the sensors present similar measurements as evidenced in
figure x, corroborating their correct operation. (see Figure 13)
Figure 13. Deposit temperature and cells respectively
On the other hand, a crucial factor when carrying out the tests with the electrolysis module are the
electrical variables of voltage and current, since these will allow projecting the consumption of the
system and, based on this value, being able to determine the generation capacity of the photovoltaic
solar system for future implementation. To measure the values, a voltage and current divider can be
applied, or simply using Ohm's Law depending on the proposed electrical circuit. Figure 14 ... shows
the voltage and current values calculated by the developed algorithm, contrasted with the values
evidenced by a measuring instrument or multimeter.
Figure 14. Comparison of voltages and cell current
Finally, with the parameters of the sensors adjusted and the verification of the voltage and current
meters, a series of tests were performed on the module where the flow values were verified with
respect to the hydrogen and oxygen gases, with which determined the production of the developed
4. Results and analysis
Figure 15 shows the final result of the dimensioning process that included, modeling, component
selection, programming and module assembly. The final product is a scale model of an electrolysis
system based on the use of water, which is versatile and portable, and also has direct current power
source feeding in order to generate a sustainable system in the future.
Figure 15. Electrolysis module proposed
Once the module finishes its configuration and the measurement instruments are calibrated and / or
verified, we highlight the indication through the LCD display of real data. The module is put into
operation and a series of experimental tests are carried out that show production of hydrogen and
oxygen, measured through two flow indicators or rotameters as presented in Figure 16, with a
hydrogen flow of 2 liters per minute and an oxygen flow of 1 liter per minute. Hydrogen was produced
through the connection of the plates to the positive terminal of the source and oxygen in the plates
connected to the positive terminal.
Figure 16. Rotameters
The module produced 1 litter of oxygen per minute and 2 litters of hydrogen per minute with a current
draw of 16 amps at a constant voltage of 11.6 Volts. Figure 17 presents the values of hydrogen and
oxygen flow with current variation, where it was shown that the flow of gases varies with the flow of
current consumed by the cell, provided that the voltage remains constant. This increase in the flow of
gases may be the product of the electrolytic solution of the water, that is, of the amount of sodium
hydroxide that varies with respect to the electrical resistance of the water, generating the current
change or the temperature change, product of water heating for the production of hydrogen despite not
being a system designed to produce it in the vapor phase, which is usually more efficient.
Figure 17. flow (H2 ; O2) relative to the current
Additionally, the temperature reached by the cell with a current consumption of 16 amps is 65 ° C,
with respect to the tank temperature which is 26 ° C, with a temperature increase of 39 ° C. This incurs
a 150% increase compared to initial system temperature. Finally, the figure 18 shows the relationship
between the flows of hydrogen and oxygen gases with respect to temperature, where a significant
increase in temperature is evident as the gas is produced. If we compare it with the previous figure, the
current increase is linear and the temperature increase is not.
Figure 18 flow (H2; O2) from temperature
5. Conclusions
The flow of hydrogen and oxygen produced is related to the cell current h2, and this current depends
on the amount of dilute sodium hydroxide in the water, since it increases or decreases the electrical
conductivity of the water, obtaining a maximum current consumed from 16 amps for our case study
with a production of 2 liters per minute of hydrogen and one liter per minute of oxygen. Two aspects
are important to highlight; The first is that in the present study the composition of the water was not
analyzed, so the amount of sodium hydroxide present is unknown, and the second is that, depending
on the region where the equipment is used, production may be affected or benefited by the
composition of the water.
The temperature in the cell is another factor that directly influences the amount of production of
hydrogen and oxygen by the electrolysis module. In the system presented in this Paper, it was
observed that with the increase in the flow of gases, in the same way, the increase in temperature up to
60 ° C. It is important to highlight that the system benefits from the increase in temperature, it cannot
be compared with a Large-scale water vapor electrolysis system that handles temperatures up to 700 °
The current system presents losses due to convection, conduction and radiation; this is because the
increase in the temperature of the cell causes the water to evaporate, generating humidity present in
the exhaust gases. For the current model, saline gases were not measured, so their composition is
The current system is a functional module, capable of producing hydrogen and oxygen from the use of
a direct current source. The system was designed in such a way that the module can supply electrical
consumption through the power source for a photovoltaic solar system that generates the demand for
the prototype. The use of a 12v charge regulator and a system between two and three panels connected
in parallel is recommended. This recommendation is made from a manual estimation product of the
ampere hour method, for this reason it is important to validate the chosen system through a specialized
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The study of the effects produced by both, imbalance and misalignment in rotating machines, allow identifying the effects produced by these two phenomena under normal operating conditions of the equipment. Initially, an analysis is carried out using the wavelet transform, through the application of the LabVIEW and Matlab software; the goal was to compare these results with those obtained with the application of the Fourier transform. Additionally, a subsequent comparison of the results is carried out as a consequence of an initial comparison with an antecedent, where the Cepstrum-Fourier transformer and the Wavelet transform were applied to verify the existence of faults in a rotating machine. The present work is developed in order to determine which of these two studies represent these effects of misalignment and imbalance in a clear, specific, and/or significant way.
The research evaluates the performance and effectiveness of a solar-biomass hybrid prototype for drying cocoa beans, which takes advantage of solar energy in the application area and the calorific value of the dried cocoa pod shell, performing a continuous drying in 36 h, reducing the time by 70% compared to traditional drying. The experimental tests of this technology were carried out in the Department of Santander in northeast Colombia. The equipment has a cylindrical mesh drum, coupled to a rotation system that rotates in specific periods of time, allowing a homogeneous drying of the almonds deposited in it. The electrical and electronic systems are powered by photovoltaic energy. The programming carried out with LabView allows to control and maintain the thermodynamic conditions of the air (e.g. temperature below 60 °C) of drying, guaranteeing the final quality and a humidity of the grain that varies between 6.5 to 7.5%.
En este trabajo de investigación se plantea un análisis de cómo es el marco normativo vigente del sector eléctrico colombiano referente a la inclusión de energía renovables al sistema de distribución eléctrico, en especial los sistemas fotovoltaicos (SFV).Se consultó bases de datos acreditadas y sitios web de instituciones del sector eléctrico, se encuentra que en Colombia la nueva resolución es favorable, pues la ley 1715 permite vender los excedentes a la red y además hay beneficios tributarios, los comerciantes y empresarios han aprovechado estos beneficios, aunque en el sector residencial no se ha visto un impacto, debido a la barrera cultural al creer que la tecnología fotovoltaica es costosa.Con la inclusión de las FNCE (Fuentes no convencionales de energía), se logra ampliar la matriz energética, se empieza a cumplir los compromisos adquiridos en reducir las emisiones de gases de efecto de invernadero, se logra robustez al sistema eléctrico, garantiza el suministro en tiempos de sequía.
La tecnología en el control de emisiones de gases contaminantes se ha desarrollado notablemente en los últimos años ya que los efectos de estos residuos químicos son muy notables en el daño al ecosistema en general, ya que esto se ve reflejado en el calentamiento global y en el efecto invernadero, esto ha permitido que la industria automotriz se concentre en producir vehículos con bajo índice de emisiones para colaborar con el cuidado del medio ambiente, de la misma manera se han perfeccionado los sistemas para que cada vez sea inferior la contaminación en general, ya que de un sistema a carburación se desarrolló un sistema electrónico que redujo considerablemente las emisiones contaminantes. Cada vez se desarrolla más tecnología y la electrónica se impone más sobre ayudar al control de emisiones. El futuro en la industria automotriz para reducir la emisión de gases contaminantes son los vehículos híbridos. La ayuda de equipos sofisticados y especializados para determinar los valores exactos de emisiones de gases contaminantes cumplen un papel fundamental para ayudar al usuario o al técnico en controlar que estos gases no sobrepasen los valores establecidos por el organismo que controla dichos gases.