Abstract - Identifying non-toxic, cost-effective, and durable materials is crucial for sustainable economic development. Among candidate materials, iron nitrides exhibit many phases with striking properties and which span a wide range of potential applications, especially at the nanoscale. However, current synthesis methods for iron nitrides rely on high-temperature processes, which are not
... [Show full abstract] conducive to sustainable production and prevent a precise control of their composition and structure. This study reports on an alternative low temperature synthesis approach. It involves the preparation of ligand coated zerovalent iron nanoparticles (FeNPs), which are activated at moderate temperatures under hydrogen and nitridated by exposure to ammonia. The effects of ammonia partial pressure, temperature, and flow rate were studied. The synthesized nanomaterials were characterized using transmission electron microscopy (TEM), inductively coupled plasma (ICP) analysis, X-ray diffraction (XRD), and magnetic measurements. We demonstrate that the Fe2N phase can be synthesized in a pure form, and key parameters for tuning the nitrogen content in the NPs are identified.