Following the development of the space electric propulsion, using of various propellants to be collected in the region where the mission is intended has been actively sought. Here we address such a technology for Solar System missions, focusing on the Earth and on the Mars vicinity with nitrogen/oxygen mixtures and CO2 as propellants correspondingly. The adequate Detailed Global Models, 4CDGM in case of using N2, N, O2 and O mixtures as propellant and CO2DGM in case of using CO2 have been extensively applied, allowing for theoretical evaluation of the considered thrusters functioning and for optical emission spectroscopy insuring their diagnostics and monitoring.