The magnetic dipole moments of the spin-\(\frac{3}{2}\) doubly charmed, bottom and charmed-bottom baryons are obtained by means of the light-cone QCD sum rule. The magnetic dipole moments of these baryons encode essential knowledge of their inner structure and shape deformations. The numerical results are given by \(\mu _{\Xi _{cc}^{*++}} = 2.94 \pm 0.95\), \(\mu _{\Xi _{cc}^{*+}} = - 0.67 \pm 0.11\), \(\mu _{\Omega _{cc}^{*+}} =- 0.52 \pm 0.07\), \(\mu _{\Xi _{bb}^{*0}} = 2.30 \pm 0.55\), \(\mu _{\Xi _{bb}^{*-}} = -1.39 \pm 0.32\), \(\mu _{\Omega _{bb}^{*-}} = -1.56 \pm 0.33\), \(\mu _{\Xi _{bc}^{*+}} = 2.63 \pm 0.82\), \(\mu _{\Xi _{bc}^{*0}} = - 0.96 \pm 0.32\) and \(\mu _{\Omega _{bc}^{*+}} =- 1.11 \pm 0.33\), respectively.