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Aerosol Jet Printing of Conductive Patterns on Paper Substrate

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Abstract

Aerosol jet printing (AJP) is a promising method for microscale digital additive manufacturing for printed electronics. However, it requires a high sintering temperature (280 ° C) and a long sintering time (e.g. 12 hours on a glass substrate) to guarantee a highly conductive metallic structure, which confined AJP to limited types of substrates and applicati ons. In this paper, a fabrication method to use cellulose fiber paper as substrates for AJP printing is proposed. With the proposed approach, the sintering temperature is reduced to 80 ° C and the sintering time is shortened to 220 minutes for the printing on printing papers. The printed structure can have a sheet resistance of 0.0203 Ω/ with good adhesion to the substrate. The effect of folding on the conductivity is examined, and an application to wireless power transfer serving as a resonator is demonstrated. The proposed paper-based AJP printed electronics can be folded, bent, and pasted to any surface. This combination of AJP with paper substrates opens a window for low-cost flexible, high resolution printed electronics.

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... The AJP technology has been applied to fabricate various types of functioning components, such as sensors [5], antennas [6], solar cells [7], etc. It can be applied to provide compact components to wireless power transfer [8][9][10], metamaterials [8,11,12], portable magnetic resonance imaging [13], etc. ...
... The AJP technology has been applied to fabricate various types of functioning components, such as sensors [5], antennas [6], solar cells [7], etc. It can be applied to provide compact components to wireless power transfer [8][9][10], metamaterials [8,11,12], portable magnetic resonance imaging [13], etc. ...
... The effect of the sintering sequence is examined. Besides the proposed sintering sequence as shown in Fig. 3(b), the proposed hot-air sintering can be done after all the layers are printed [8]. Fig. 11(a) shows such an alternative sintering sequence, named SQ 2, for AJP printing on cellulose fiber paper when a high conductivity can be obtained. ...
Article
Aerosol jet printing (AJP) is a promising method for micro-scaled digital additive manufacturing for printed electronics. It usually requires a high sintering temperature (280 °C) and a long sintering time (e.g., 12 h on a glass substrate) to guarantee a high conductivity of the printed structures, which has limited AJP to only a few types of substrates. Moreover, the printed metallic structure peels off from the substrate easily. In this paper, a procedure of AJP printing on cellulose fiber paper is proposed, which includes the use of cellulose fiber paper as the substrate, and a new sintering method, i.e., hot-air sintering with an optimized sequence. With the proposed approach, the sintering temperature is significantly lowered (80 °C), and the sintering time is considerably shortened (40 min). The printed structure has a measured sheet resistance of 1.13 × 10⁻² Ω/m² which is equivalent to a conductivity of greater than 10⁶ S/m and close to that of the bulk silver (6.30 × 10⁷ S/m), and it has good adhesion to the substrate. The determinant factors underlying the diffusion and curing processes of AJP, i.e., the properties of the substrate (cellulose fiber paper), the printing parameters, the sintering parameters, and the sequence were systematically investigated. The investigation is carried out through evaluation of the morphologies of the printed structures based on scanning electron microscope (SEM) images and through the study of the correlation between the morphology and the conductivity of the structures. Moreover, the proposed paper-based AJP electronics offer tremendous flexibility. They can be folded, bent, and pasted to any surface. This proposed cellulose-fiber-paper-based AJP opens a window for low-cost, eco-friendly, flexible, and high-resolution printed electronics. It will be an essential alternative fabrication approach for flexible electronic circuits, antennas, and electromagnetic-functioning surfaces, such as reconfigurable meta-surfaces.
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Direct writetm system
  • M J Renn
M. J. Renn, "Direct writetm system," 18 2007, uS Patent 7,270,844 B2.