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A Novel Smart System for Contaminants Detection and Recognition in Water

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... The authors stem from a pre-existent system based on a specific multi-sensing platform, SENSIPLUS, briefly described in Section II. Furthermore, they exploit past efforts on the creation of a water monitoring smart system [11]- [13] to propose a low-cost solution, working as a finite-statemachine able to reduce false positive, thus enhancing system specificity, while keeping good system sensitivity. In detail, both in clean and waste water, what really influences the detection capability is the system's promptness to distinguish between normal condition (i.e. ...
... During acquisition phase, the distinction between aforementioned conditions is not straightforward, because the system continuously acquires and updates its background condition adopted to recognize pollutant case. In [11], the authors adopted a static background update, based on such a simple rule: the system acquired a certain amount of samples, surely belonging to background, and updated it with a very slow average operation, thus avoiding to sudden spikes, due to contaminant, to deeply influence the background levels. ...
... In this section, a new approach for baseline tracking is presented and compared to that proposed in [11]. ...
Conference Paper
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Water monitoring systems continuously working ensure real–time pollutant detection capabilities according to their sensitivity and specificity. It is necessary to balance such features because, although being able to sense several substances is a desired feature, the reduction of false positives is a primary goal a classification system should have. High false positive makes the system unusable. The current solution enables a 24/7 service with a sampling rate equal to 0.6 Hz. Our goal is to limit false positives to 1 per day, thus achieving 99.99% accuracy at least. In this paper, we add a false positive reduction module to our pre- existent system, aiming to manage false positive boosters as sensor drift and signal oscillations. Obtained results, using a Multi Layer Perceptron classifier, confirm the false positive reduction while keeping high true positive rates.
... The EIS technique has been adopted for measurements from sensors, and nine different machine learning solutions have been evaluated for the classification task. Preliminary studies and research activities based on the same MASP technology have been proposed in Ferdinandi et al. [16] and Betta et al. [5] . Further experimental activities adopting the same technology for different applications were proposed in Cerro et al. [10] , Bruschi et al. [8] , and Cerro et al. [9] . ...
... Further experimental activities adopting the same technology for different applications were proposed in Cerro et al. [10] , Bruschi et al. [8] , and Cerro et al. [9] . This work extends our previous works [5,16] in several directions: (i) we consider new substances (Sulphuric Acid, Phosphoric Acid, Acetic Acid, Formic Acid, Hydrogen Peroxide, Ammonia); (ii) we adopt new sensor combinations, from two sensors (Gold and Copper) to four sensors (Gold, Silver, Nickel, Platinum) integrated in a compact configuration; (iii) we adopt a different sensor setting in which the stimulus signal has been changed to 200 Hz and 78 kHz; and (iv) we evaluate nine different classifiers and analyze their trade-off with respect to performance, processing time and memory usage. The idea exploited with the partially selective sensors reported at point (ii), is that they can contribute to the discrimination capability of the array. ...
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Water pollution caused by human activities poses a serious global threat to human health. Sensor technologies enabling water monitoring are an important tool that can help facing this problem. In this work, we propose an embedded IoT-ready system based on a proprietary sensor technology for the detection and recognition of six water contaminants. The system architecture is composed of two layers: (i) a sensing layer based on the SENSIPLUS chip, a proprietary Micro-Analytical Sensing Platform with six interdigitated electrodes metalized through different materials; and (ii) a data collection, communication, and classification layer with both hardware and software components. Being classification the most computationally and resource intensive operation, we evaluated nine machine learning solutions of different complexity and analyzed the trade-off between recognition accuracy, processing time, and memory usage to find a solution suitable to be implemented on an edge node. The highest average accuracy of 95.4% was achieved with K-nearest neighbor classification without constraints on processing time and memory usage, which confirms the potentiality of the system. When such constraints are taken into consideration, the best performance dropped to 86.4% offered by Multi Layer Perceptron.
... In particular, several kinds of technologies contribute to developing sensors that discriminate and classify undesired substances to ensure an adequate water quality level. Some of the authors developed systems able to monitor both water and air thanks to the SENSIPLUS platform [10,11,12,13]. The monitoring outputs can vary, ranging from a classification of the pollutants to a simple binary decision on the presence of contaminants in general. ...
Article
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The detection of contaminants in several environments (e.g., air, water, sewage systems) is of paramount importance to protect people and predict possible dangerous circumstances. Most works do this using classical Machine Learning tools that act on the acquired measurement data. This paper introduces two main elements: a low-cost platform to acquire, pre-process, and transmit data to classify contaminants in wastewater; and a novel classification approach to classify contaminants in wastewater, based on deep learning and the transformation of raw sensor data into natural language metadata. The proposed solution presents clear advantages against state-of-the-art systems in terms of higher effectiveness and reasonable efficiency. The main disadvantage of the proposed approach is that it relies on knowing the injection time, i.e., the instant in time when the contaminant is injected into the wastewater. For this reason, the developed system also includes a finite state machine tool able to infer the exact time instant when the substance is injected. The entire system is presented and discussed in detail. Furthermore, several variants of the proposed processing technique are also presented to assess the sensitivity to the number of used samples and the corresponding promptness/computational burden of the system. The lowest accuracy obtained by our technique is 91.4%, which is significantly higher than the 81.0% accuracy reached by the best baseline method.
... At the same time, it has been demonstrated that the SENSIPLUS platform is suitable for identifying pollutants in water [27,28] or air [8,29] in an effective way. The open issue is that, in all these cases, the machine learning models have been deployed on external devices (PC, Workstation, or into the cloud). ...
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The technological step towards sensors’ miniaturization, low-cost platforms, and evolved communication paradigms is rapidly moving the monitoring and computation tasks to the edge, causing the joint use of the Internet of Things (IoT) and machine learning (ML) to be massively employed. Edge devices are often composed of sensors and actuators, and their behavior depends on the relative rapid inference of specific conditions. Therefore, the computation and decision-making processes become obsolete and ineffective by communicating raw data and leaving them to a centralized system. This paper responds to this need by proposing an integrated architecture, able to host both the sensing part and the learning and classifying mechanisms, empowered by ML, directly on board and thus able to overcome some of the limitations presented by off-the-shelf solutions. The presented system is based on a proprietary platform named SENSIPLUS, a multi-sensor device especially devoted to performing electrical impedance spectroscopy (EIS) on a wide frequency interval. The measurement acquisition, data processing, and embedded classification techniques are supported by a system capable of generating and compiling code automatically, which uses a toolchain to run inference routines on the edge. As a case study, the system capabilities of such a platform in this work are exploited for water quality assessment. The joint system, composed of the measurement platform and the developed toolchain, is named SENSIPLUS-LM, standing for SENSIPLUS learning machine. The introduction of the toolchain empowers the SENSIPLUS platform moving the inference phase of the machine learning algorithm to the edge, thus limiting the needs of external computing platforms. The software part, i.e., the developed toolchain, is available for free download from GitLab, as reported in this paper.
... Water, which covers more than 70% of the Earth's surface and is involved in almost all life activities, is a primary factor influencing life on the Earth. Consequently, water quality monitoring is a crucial task, and ways to address it are widely spreading in the scientific literature (Ighalo et al., 2021;Budiarti et al., 2019;Saravanan et al., 2018;Akhter et al., 2022;Ferdinandi et al., 2019). Particularly critical is the issue related to wastewater (Trubetskaya et al., 2021), i.e., water having suffered pollution due to domestic, industrial, or hospital processes. ...
Article
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The problem of detecting illegal pollutants in wastewater is of fundamental importance for public health and security. The availability of distributed, low–cost and low–power monitoring systems, particularly enforced by IoT communication mechanisms and low-complexity machine learning algorithms, would make it feasible and easy to manage in a widespread manner. Accordingly, an End-to-End IoT-ready node for the sensing, local processing, and transmission of the data collected on the pollutants in the wastewater is presented here. The proposed system, organized in sensing and data processing modules, can recognize and distinguish contaminants from unknown substances typically present in wastewater. This is particularly important in the classification stage since distinguishing between background (not of interest) and foreground (of interest) substances drastically improves the classification performance, especially in terms of false positive rates. The measurement system, i.e., the sensing part, is represented by the so-called Smart Cable Water based on the SENSIPLUS chip, which integrates an array of sensors detecting various water-soluble substances through impedance spectroscopy. The data processing is based on a commercial Micro Control Unit (MCU), including an anomaly detection module, a classification module, and a false positive reduction module, all based on machine learning algorithms that have a computational complexity suitable for low-cost hardware implementation. An extensive experimental campaign on different contaminants has been carried out to train machine-learning algorithms suitable for low-cost and low-power MCU. The corresponding dataset has been made publicly available for download. The obtained results demonstrate an excellent classification ability, achieving an accuracy of more than 95% on average, and are a reliable ”proof of concept” of a pervasive IoT system for distributed monitoring.
... On the other hand, the industry is moving towards systems that have the same goals, such as SPC5-STUDIO by ST Microelectronics [6] or the BME AI-Studio Software from Bosch Sensortec [7]. In particular, the multisensory device was exploited for the acquisition of characteristics suitable for the identification of pollutants in water [8]- [11] or air [12]- [14], creating a system that allows to automatically generate the complete firmware in all its parts. A firmware that starts from the acquisition of the features up to the preprocessing and classification phase, providing the output result according to an appropriate protocol. ...
... They are trying to propose new emerging sensors able to reliable detect pollutants saving money, size and energy consumption, new network technologies, new communication standards, and, finally, new methods for the data analysis. Many researchers are exploiting the advantages offered by Artificial Intelligence and Machine Learning (ML) [3,4,13,15]. ML techniques are often preprocessed using Principal Component Analysis (PCA). ...
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The problem of detecting pollutants in water with non-invasive and low-cost sensors is an open question. In this paper, we propose a system for the detection and classification of pollutants based on the improvement of a previous proposal, focused on geometric cones. The solution is based on a classifier suitable to be implemented aboard the so-called Smart Cable Water (SCW) sensor, a multi-sensor based on SENSIPLUS® technology developed by Sensichips s.r.l. The SCW endowed with six interdigitated electrodes is a smart-sensor covered by specific sensing materials that allow differentiating between different water contaminants. Using the PCA or LDA decomposition, we obtain a data compression that makes data suitable for the “edge computing” paradigm with a reduction from a 10-dimensional space to a 3-dimensional space. We defined an ad-hoc classifier to distinguish contaminants represented by points in the 3-dimensional space. We used an evolutionary algorithm to learn the classifier’s parameters. Finally, we compared the performance of our system with that achieved by the old classification system based only on PCA, as well as those achieved by other machine learning algorithms. The proposed system achieved the best accuracy of 87%, outperforming the other state-of-the-art systems compared. The novelty of the system proposed lies in the usage of an evolutionary algorithm for the optimization of the parameters of a novel PCA-based classification algorithm for the detection of water pollutants.
... In such framework, a special mention is deserved by the monitoring of natural quantities, as temperature, humidity, water [4] and air quality [5], [6], specific gas presence in the atmosphere. Among them, a growing interest is given to the Radon Gas Monitoring [7]- [9], for two distinct aspects: human health and Earth's status. ...
... Nowadays, many research activities have been addressing the problem of pollution monitoring by using the emerging sensing technologies, as well as the new possibilities of data analysis offered by Artificial Intelligence and Machine Learning [3,4,15,17]. Among the others, in [7] the authors used Artificial Neural Network and Principal Component Regression techniques to estimate nitrate concentration in groundwater, whereas a pattern recognition solution based on partial least square discriminant analysis (PLS-DA) was presented in [15]. ...
Chapter
Nowadays, the problem of pollution in water is a very serious issue to be faced and it is really important to be able to monitoring it with non-invasive and low-cost solutions, like those offered by smart sensor technologies. In this paper, we propose an improvement of an our innovative classification system, based on geometrical cones, to detect and classify pollutants, belonging to a given set of substances, spilled into waste water. The solution is based on an ad-hoc classifier that can be implemented aboard the Smart Cable Water (SCW) sensor, based on SENSIPLUS technology developed by Sensichips s.r.l. The SCW is a smart-sensor endowed with six interdigitated electrodes, covered by specific sensing materials that allow detecting between different water contaminants. In order to develop an algorithm suitable to apply the “edge computing” paradigm we first compress the input data from a 10-dimensional space to a 3-D space by using the PCA decomposition techniques. Then we use an ad-hoc classifier to classify between the different contaminants in the transformed space. To learn the classifier’s parameters we used the evolutionary algorithms. The obtained results have been compared with the old classification system and other, more classical, machine learning approaches.
... The Fig. 1. The adopted acquisition and processing system same MASP technology has been used in several studies for contaminants detection [12]- [15]. Due to time and cost issues of collecting measures for any substance that could be found in wastewater, the faced machine learning problem should be considered as an "open-set recognition" problem, i.e., a classification problem where the training data only gives a partial view of the application domain. ...
Conference Paper
In smart city framework, the water monitoring through an efficient, low-cost, low-power and IoT-oriented sensor technology is a crucial aspect to allow, with limited resources, the analysis of contaminants eventually affecting wastewater. In this sense, common interfering substances, as detergents, cannot be classified as dangerous contaminants and should be neglected in the classification. By adopting classical machine learning approaches having a finite set of possible responses, each alteration of the sensor baseline is always classified as one out of the predetermined substances. Consequently, we developed an anomaly detection system based on one-class classifiers, able to discriminate between a recognized set of substances and an interfering source. In this way, the proposed detection system is able to provide detailed information about the water status and distinguish between harmless detergents and dangerous contaminants.
... pH, conductivity and turbidity. Moreover, the huge datasets generated require the adoption of Artificial Intelligence (AI) and Machine Learning (ML) techniques (Bernieri et al., 2006;Gunda et al., 2018;Betta et al., 2019;Bruschi et al., 2018;Cerro et al., 2017Cerro et al., , 2018Ferdinandi et al., 2019). ...
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Water pollution causes an ever-increasing number of diseases and represents a worldwide concern, both for governments and researchers, as well as public opinion. This pollution also regards drinkable water, with two billion people plagued by this problem. Therefore, it is crucial to find reliable and low-cost technologies for a continuous and diffused monitoring of water. In this paper, we present a novel approach that allows the detection of water contaminants by using an ad-hoc classification system that can be implemented aboard low-cost sensors. To this aim, we first project the input data from the sensors into a 3-D space by using the PCA algorithm, then we use an ad-hoc devised classifier to distinguish the contaminants in the transformed space. We used an evolutionary algorithm to learn the parameters of the classifiers. The experiments were performed on a large dataset containing data from four contaminants, with the phosphoric and sulphuric acids, among the others. The results obtained confirm the effectiveness of the proposed approach.
... In this sense, the authors propose an integrated system, able to optimize both the sensing and processing, responding to desirable requirements such as low cost, integration, portability, light computational burden, good sensitivity and classification capability. In detail, stemming from the authors' experience in gas recognition [7], water analysis [8], [9], an indoor air monitoring system, VOLUME 4, 2016 based on a compact and low cost sensing technology and Artificial Intelligence (AI) techniques for the detection and classification of air contaminants, is proposed. The system development starts from the assumption, well known in scientific literature on this field, that a single sensor is seldom sensitive to more contaminants and therefore the best solution is the employment of a sensor array, as implemented in this work. ...
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In the framework of indoor air monitoring, this paper proposes an Internet of Things ready solution to detect and classify contaminants. It is based on a compact and low–power integrated system including both sensing and processing capabilities. The sensing is composed of a sensor array on which electrical impedance measurements are performed through a microchip, named SENSIPLUS, while the processing phase is mainly based on Machine Learning techniques, embedded in a low power and low resources micro controller unit, for classification purposes. An extensive experimental campaign on different contaminants has been carried out and raw sensor data have been processed through a lightweight Multi Layer Perceptron for embedded implementation. More complex and computationally costly Deep Learning techniques, as Convolutional Neural Network and Long Short Term Memory, have been adopted as a reference for the validation of Multi Layer Perceptron performance. Results prove good classification capabilities, obtaining an accuracy greater than 75% in average. The obtained results, jointly with the reduced computational costs of the solution, highlight that this proposal is a proof of concept for a pervasive IoT air monitoring system.
... As reported in [20], three steps are needed to perform the measurement procedure in a correct way. Firstly, the baseline values, i.e. the impedance measurements when only water is Fig. 8. Set-up for water monitoring purposes. ...
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Water is a vital resource for natural ecosystems and human life, and assuring a high quality of water and protecting it from chemical contamination is a major societal goal in the European Union. The Water Framework Directive (WFD) and its daughter directives are the major body of legislation for the protection and sustainable use of European freshwater resources. The practical implementation of the WFD with regard to chemical pollution has faced some challenges. In support of the upcoming WFD review in 2019 the research project SOLUTIONS and the European monitoring network NORMAN has analyzed these challenges, evaluated the state-of-the-art of the science and suggested possible solutions. We give 10 recommendations to improve monitoring and to strengthen comprehensive prioritization, to foster consistent assessment and to support solution-oriented management of surface waters. The integration of effect-based tools, the application of passive sampling for bioaccumulative chemicals and an integrated strategy for prioritization of contaminants, accounting for knowledge gaps, are seen as important approaches to advance monitoring. Including all relevant chemical contaminants in more holistic "chemical status" assessment, using effect-based trigger values to address priority mixtures of chemicals, to better consider historical burdens accumulated in sediments and to use models to fill data gaps are recommended for a consistent assessment of contamination. Solution-oriented management should apply a tiered approach in investigative monitoring, to identify toxicity drivers, strengthen consistent legislative frameworks and apply solutions-oriented approaches that explore risk reduction scenarios before and along with risk assessment.
Conference Paper
This paper proposes the realization and preliminary characterization of a smart sensor platform for the online monitoring of the residual life of activated carbon air based filters. The platform performs the measurement to give reliable information about the filter maintenance or early warning for the presence of dangerous gases both in industrial and military scenarios. A preliminary feasibility study has been carried out to evaluate the activated carbon filter electrical impedance sensitivity to chemicals adsorption. After a detailed presentation of the employed hardware and software solutions, a description of the experimental setup is given and a preliminary proof of the assumed relationship is provided.
Article
Water is a vital resource for natural ecosystems and human life, and assuring a high quality of water and protecting it from chemical contamination is a major societal goal in the European Union. The Water Framework Directive (WFD) and its daughter directives are the major body of legislation for the protection and sustainable use of Euro- pean freshwater resources. The practical implementation of the WFD with regard to chemical pollution has faced some challenges. In support of the upcoming WFD review in 2019 the research project SOLUTIONS and the Europe- an monitoring network NORMAN has analyzed these challenges, evaluated the state-of-the-art of the science and suggested possible solutions. We give 10 recommendations to improve monitoring and to strengthen comprehen- sive prioritization, to foster consistent assessment and to support solution-oriented management of surface waters. The integration of effect-based tools, the application of passive sampling for bioaccumulative chemicals and an in- tegrated strategy for prioritization of contaminants, accounting for knowledge gaps, are seen as important ap- proaches to advance monitoring. Including all relevant chemical contaminants in more holistic “chemical status” assessment, using effect-based trigger values to address priority mixtures of chemicals, to better consider historical burdens accumulated in sediments and to use models to fill data gaps are recommended for a consistent assessment of contamination. Solution-oriented management should apply a tiered approach in investigative monitoring to identify toxicity drivers, strengthen consistent legislative frameworks and apply solutions-oriented approaches that explore risk reduction scenarios before and along with risk assessment.
Article
This paper presents a developed methodology for the detection of bovine milk adulteration by applying electrical impedance measurements. This parameter allows characterizing samples of raw and ultrahigh temperature milk, adulterated with different proportions of drinking water, deionized water, hydrogen peroxide (H2O2), sodium hydroxide (NaOH), and formaldehyde (CH2O). The samples were electrically analyzed by applying the electrical impedance spectroscopy measurements and a dedicated microcontroller system, developed for this application. In both cases, the measures allowed classifying the milk quantitatively, enabling the development of real-time monitoring systems for fraud detection in milk composition. A classification of the results is proposed through a k-nearest neighbors algorithm that allows to quantitatively qualify the samples of pure and adulterated milk.
Article
The water quality monitoring plays an important role in water contamination surveillance and guides the water resource protection for safe and clean water. A flexible automated real-time water quality monitoring and alarm system based on the wireless sensor network(WSN) is proposed. The WSN is built in accordance with Zigbee communication protocol, which consists of the sensor nodes, route nodes and coordinator node. The sensor nodes based on cheap and efficient sensors (pH electrode, dissolved oxygen electrode, temperature senor) and wireless transreceiver collect the environmental data and transmit to the coordinator node via the route nodes. The data are sent to the remote monitoring center with the help of GPRS. The time synchronous algorithm is adopted to wake up all the nodes in the network to improve the stability and reliability of the communication. The long-time measurement results verify the real time and accuracy in data acquisition and stability and reliability in communication. The system meets the requirements of water quality monitoring, and has great practical value.
Lstm: A search space odyssey
  • K Greff
  • R K Srivastava
  • J Koutnk
  • B R Steunebrink
  • J Schmid-Huber
K. Greff, R. K. Srivastava, J. Koutnk, B. R. Steunebrink, J. Schmidhuber, Lstm: A search space odyssey, IEEE Transactions on Neural Networks and Learning Systems 28 (10) (2017) 2222-2232. doi:10.1109/TNNLS.2016.2582924.
Forest Fire Detection System Using IoT and Artificial Neural Network, New Age International
  • N C Vinay Dubey
  • Prashant Kumar
N. C. Vinay Dubey, Prashant Kumar, Forest Fire Detection System Using IoT and Artificial Neural Network, New Age International, 2006. doi:doi.org/10.1007/978-981-13-2324-9.