We demonstrate single junction GaInNAsSb solar cells with high nitrogen content, i.e. in the range of 5–8%, and bandgap energies close to 0.7 eV grown by molecular beam epitaxy. A good crystalline quality is demonstrated for the entire range of N concentrations. An average external quantum efficiency of 0.45 is demonstrated for GaInNAsSb solar cell with 6.2% N exhibiting a bandgap of 0.78 eV (no antireflection coatings has been applied). The internal quantum efficiency for the cell is 0.65 at E g + 0.2 eV. The solar cells exhibited bandgap-voltage offsets between 0.55 V (for N = 5.3%) and 0.66 V (for N = 7.9%). When used in a six-junction solar cell architecture under AM1.5D illumination, the estimated short-circuit current density corresponding to the 0.78 eV cell is 8.2 mA/cm ² . Furthermore, using the parameters obtained for the GaInNAsSb junction with 6.2% N, we have estimated that such six-junction solar cell architecture could realistically attain an efficiency of over 50% at 1000 suns concentration.