In order to study the effect of chelate formation at cystine bridge in wool on its properties, cystine bridge was broken and then treated with Cu solution to form metallic salt with S and the recombined wool was compared with original wool and the chelated wool in alkali duarability, the changes in S content during alkali treatment and mechanical properties. Thioglycolic acid which. is known to
... [Show full abstract] break only cystine bridge in wool without damaging other parts of it was used. Degreased Merino wool was used. Wool was immersied in 0.05M of thioglycolic acid at the ratio. of 1:100 for 4hours at 20°C. and washed with water. The mixture of 50ml of 0.05M Cu(NO3)2, 20ml of 0.5N HNO3, 50ml of 2M KNO3, 50ml of 3% aqueous solution of nonionic surface active agent and 200ml of water was used for Cu treatment. About 15g of wool were immersed in the mixture at 30°C for 67 hours and washed and dried. Alkali solubility was determined in 0.1N NaOH solution at 65°C. The results are shown in Fig. 1.The recombined wool showed to have nearly same durability to alkali as the chelated wool. It is much improved in alkali resistance in comparison with the original wool. The change of S content during alkali treatment is shown in Table 1. This also shows that the recombined wool has the same tendancy as the chelated wool.From these results, the combination of Cu ion with S in wool irrespective of S in cystine bridge or S in free state has a relation to alkali durability, therefore chelate formation is preferable.