ArticlePDF Available

Abstract

Reducing the overall vehicle weight is an efficient, system-level approach to increase the drive range of electric vehicle, for which structural parts in auto-frame may be replaced by battery modules. Such battery modules must be structurally functional, e.g., energy absorbing, while the battery cells are not necessarily loading–carrying. We designed and tested a butterfly-shaped battery module of prismatic cells, which could self-unfold when subjected to a compressive loading. Angle guides and frictionless joints were employed to facilitate the large deformation. Desired resistance to external loading was offered by additional energy absorption elements. The battery-module behavior and the battery-cell performance were controlled separately. Numerical simulation verified the experimental results.
A multifunctional battery module design for electric vehicle
Meng Wang
1
Liangliang Zhu
2
Anh V. Le
1
Daniel J. Noelle
3
Yang Shi
3
Ying Zhong
3
Feng Hao
2
Xi Chen
2
Yu Qiao
1,3
Received: 5 May 2017 / Revised: 11 September 2017 / Accepted: 19 September 2017
ÓThe Author(s) 2017. This article is an open access publication
Abstract Reducing the overall vehicle weight is an effi-
cient, system-level approach to increase the drive range of
electric vehicle, for which structural parts in auto-frame may
be replaced by battery modules. Such battery modules must
be structurally functional, e.g., energy absorbing, while the
battery cells are not necessarily loading–carrying. We
designed and tested a butterfly-shaped battery module of
prismatic cells, which could self-unfold when subjected to a
compressive loading. Angle guides and frictionless joints
were employed to facilitate the large deformation. Desired
resistance to external loading was offered by additional
energy absorption elements. The battery-module behavior
and the battery-cell performance were controlled separately.
Numerical simulation verified the experimental results.
Keywords Electric vehicle Battery module
Multifunctional Energy absorption
1 Introduction
While the first electric vehicle (EV) was developed a few
decades ago [1], there are still a large number of technical
hurdles that must be overcome, before EVs can be widely
commercialized. One key issue is the drive range: To
compete with fossil-fuel vehicles, once being charged, an
EV should be able to travel 200–300 miles, for which
70–80 kW h electrical energy is needed [2]. Thus, the
battery system in an EV, including battery cells and pack
components, could be heavier than 500 kg [3].
It was suggested that the specific energy of EV battery
system must be more than *150 Wh/kg at the pack level
[4]. A promising way to achieve this goal is to render the
battery modules/packs multifunctional. For instance, they
can be energy absorbing and protective. As a first-order
approximation, assume the mass of a lightweight EV is
M=1000 kg. At the speed of v= 35 MPH—the vehicle
speed in standard crashworthiness testing [5], the EV
would carry a kinetic energy of K=120 kJ. The volume
of an EV battery system is V= 300 L [6]. If upon collision
the battery system volume could shrink by *50%, the
kinetic energy can be entirely dissipated as long as the
crushing pressure (P) is above 0.8 MPa. Disintegration of
battery pack under this condition is acceptable, since the
EV structure has been destroyed.
For another order-of-magnitude assessment, assume that
the battery system is rectangle, with the cross-sectional
area of Aand the length of L. The deceleration of the
vehicle, as the battery system absorbs energy, can be
estimated as a=PA/M. Here, for the sake of simplicity, we
assume that the crushing pressure is constant over time, so
is the deceleration. Hence, for a battery system with A=
0.3 m
2
, to keep the deceleration below 60 G [7], Pshould
be lower than 3 MPa.
Clearly, the estimations above do not facilitate an
accurate analysis. Nevertheless, it validates that there exists
a range of crushing pressure, around 1–3 MPa, at which the
battery pack can be employed as a protective structural
component to absorb vehicle kinetic energy and to keep the
&Yu Qiao
yqiao@ucsd.edu
1
Department of Structural Engineering, University of
California – San Diego, La Jolla, CA 92093-0085, USA
2
Columbia Nanomechanics Research Center, Department of
Earth and Environmental Engineering, Columbia University,
New York, NY 10027, USA
3
Program of Materials Science and Engineering, University of
California – San Diego, La Jolla, CA 92093, USA
123
J. Mod. Transport.
DOI 10.1007/s40534-017-0144-8
deceleration relatively low, meeting the requirements of
vehicle crashworthiness testing. As a result, a variety of
other structural parts of auto-frame may no longer be
necessary, leading to a considerable weight reduction. The
effective ‘‘net’’ mass of battery system can be taken as the
actual battery system mass, m
1
, subtracting the saved mass
from auto-frame, m
2
. While due to the constraints of bat-
tery chemistry, m
1
must be relatively high, (m
1
-m
2
) may
meet the functional requirement of EV, by using existing or
near-future battery chemistry.
Currently, the study on multifunctional EV battery
system is still in its early stage. It was proposed that, as
cylindrical battery cells are placed in parallel and confined
by regular walls [8,9], a disintegrable structure can be
formed, which provides sufficient flexibility to protect
battery cells in a vehicle collision. A number of studies
were performed on battery safety and robustness at the cell
level [1015]. Functional current collector (FCC) [1012]
was developed to isolate the damaged areas in a mechan-
ically abused battery cell, which significantly decreased the
heat generation rate. Thermally sensitive binder (TSB)
[13,14] was developed to reduce the electronic conduc-
tivity once the battery was overheated, and thermal run-
away retardant (TRR) [15] was employed to lower the
ionic conductivity. The battery cells were typically tested
through nail penetration, blunt impact or indentation
[1015]; in such tests, the cell case would largely deform
and the active materials were internally shorted. In addi-
tion, computer simulation at the vehicle level [16] has
demonstrated that strategic placement of battery pack could
reduce the impact forces on occupants and minimize the
damages of battery cells. However, little study has been
conducted on the level of battery module. To fully take
advantage of the multifunctional design of battery cells in
EV, the structure of battery module needs to be re-
investigated.
It is hypothesized that a high deformability of battery
module would be beneficial. In the current research, we
focus on designing and testing individual battery module.
Since battery cells are expensive and contain flammable
electrolyte, mechanical loading on battery module will be
carried by the energy absorbing elements, separate from the
battery cells.
2 Experiment and computer simulation
A deformable, butterfly-shaped battery module structure
was designed, as depicted in Fig. 1. Prismatic aluminum
cells were employed as analogs to hard battery cells, with
the height, width, and thickness being 25.4, 25.4, and
4.76 mm, respectively. One end of the cell was tapered at
an angle of 45°. The tip of the tapered edge was rounded,
and the length of the ramp section was 4.76 mm. The
opposite end of the cell was flat, and the two surfaces were
respectively connected to two McMaster-Carr 1603A23
brass surface-mount hinges, using McMaster-Carr
91500A086 bolts and McMaster-Carr 91841A003 nuts.
The bolt size was 2–56; the hinge was 25.4 mm wide and
0.5 mm thick, with the leaf height of 25.4 mm.
Each model battery module consisted of four cells and
four hinges. The upper and bottom hinges were fully folded;
the left and right hinges were fully open. Thus, the four cells
were aligned along the axial direction. They were mounted
vertically on a McMaster-Carr 8982K39 aluminum angle,
which served as the support. Another angle was inserted
upside down on the top, as the guide. The width, the arm
length, and the thickness of the angles were 25.4, 25.4, and
0.5 mm, respectively. The initial configuration of the mod-
ule was left–right and top-town symmetric.
Two McMaster-Carr 6100K149 steel tubes, with the
length, the outer diameter, and the wall thickness of 76.2,
7.14, and 0.127 mm, respectively, were employed as
energy absorption elements (EAE). They were attached to
the two lateral sides of the hinged cells by 3M DP110
adhesive.
Fig. 1 a Schematic of butterfly-shaped battery module: before (left), during (middle), and after (right) deformation. bPhotos of a testing sample:
before (left) and after (right) impact; the scale bars indicate 20 mm
M. Wang et al.
123 J. Mod. Transport.
The module was placed on a large flat 6.35-mm-thick
steel plate, which was firmly mounted on the base holder of
an Instron Ceast-9350 drop tower. A 12.7-mm-thick 101.6-
mm-diameter circular hardened-steel impact head was
launched onto the angle guide, with the impact velocity of
v= 7.7 m/s. The total drop mass was m= 3.65 kg. The
deceleration was measured by an accelerometer embedded
in the impact head; the drop-mass displacement was
simultaneously recorded by a linear variable differential
transformer (LVDT). Altogether four sets of modules were
tested. Their behaviors were quite similar.
Finite element analysis (FEA) was conducted using
ABAQUS with explicit package. The FEA model is shown in
Fig. 2a, identical to the experimental setup. Linear elasto-
plastic material models were employed. For the EAE ele-
ments, the Young’s modulus E
Fe
= 200 GPa, the yield stress
r
Y-Fe
= 500 MPa, the Poisson’s ratio m
Fe
= 0.33, and the
mass density q
Fe
= 7800 kg/m
3
. For the cells, E
Al
= 70 GPa,
r
Y-Al
= 300 MPa, m
Al
= 0.33, and q
Al
= 2700 kg/m
3
. Friction
coefficient was set to l= 0.3. Mesh convergence study was
carried out to ensure appropriate mesh density.
3 Results and discussion
Currently, the energy storage of EV relies on lithium (Li)
ion batteries, which have the highest specific energy per kg
and the lowest specific cost per kWh, compared with lead
acid batteries, nickel-metal hydride (NiMH) batteries, and
double-layer and pseudo-supercapacitors [17]. Lithium-ion
battery cells contain electrolytes based on highly flam-
mable organic solutions such as dimethyl carbonate
(DMC), diethyl carbonate (DEC), and ethyl methyl car-
bonate (EMC), since Li phase is incompatible with aqueous
solutions [18]. The organic solvents are volatile, having
relatively low boiling points around 110 °C and low flash
points below room temperature; their combustion heats are
quite high, around 1 kJ/g [19], lower than yet on the same
scale as that of gasoline [20]. Thus, if the battery cells
largely deform and the electrolyte solutions spill out, tough
challenges would be imposed to system safety. To be
conservative, in the current research, the high deformabil-
ity of battery module is achieved by using connection
hinges; the battery cells behave as ‘‘rigid’’ parts.
x
z
x
z
x
z
y
z
y
z
Impact head (3.65 kg)
7.7 m/s
Cell
Hinge Steel tube
Steel plate
Support
(a)
(b)
(c)
Fig. 2 Computer simulation of battery module abefore and bafter impact; cstress distribution in the battery module at 10 ms during impact
A multifunctional battery module design for electric vehicle
123
J. Mod. Transport.
The initial configuration of the battery module is fully
folded. Upon the dynamic compressive loading from the
drop mass, the tapered cell edge and the impact guide
trigger a smooth self-unfolding, aided by the angle support
from the bottom. The cells are freely jointed by the hinges,
and the motion is quite resistance free and robust. Even
when the angle guide and support are damaged, once the
self-unfolding begins it would continue until the cell
assembly is flattened. During the deformation process, the
cells are designed to be ‘‘loading-free’’, as long as the
frictions are small. As shown in Fig. 2b, during impact, the
stress level in the cells is quite low; stress concentration
occurs around the hinges and the top of upper cells. Most of
the loadings are carried by the EAE. Therefore, the cell
assembly can reach a high deformability, while the cell
damage is trivial. According to necessity, additional pro-
tection components may be included in the bottom section
of the module; hence, when the module self-unfolding
completes, direct impact on cell surfaces is minimized.
The favorable working pressure of multifunctional bat-
tery system, as approximately analyzed in the introductory
section, is 1–3 MPa. Because the volume of battery mod-
ules is only a fraction of that of the battery pack [9] and
also because higher working pressure leads to better energy
absorption capacity, the crushing pressure at the module
level should be close to the high end, i.e., 3–5 MPa. The
resistance to external loading is mainly offered by EAE,
separately assembled next to the battery cells. The modu-
larized structure enables independent adjustment of the
performance of individual battery cells and the mechanical
responses of module. The EAE is lightweight and highly
deformable. As their wall thickness and size are controlled,
the buckling pressure can be tailored in a broad range. As
shown in Figs. 2c and 3a, shortly after the drop mass
impacts the cell assembly, in less than 1 ms, the tube
buckling takes place, resulting in a buckling plateau in the
stress–strain curve. Figure 3a shows the profiles of engi-
neering stress, r=F/A
0
, and engineering strain, e=DH/H
0
,
where F=ma is the impact force, ais the deceleration of
drop mass, A
0
is the initial cross-sectional area, DHis the
system deformation, and H
0
is the initial height. As the
EAE is compressed, elastic energy is stored by the tube
wall, and when it exceeds the limit of structural stability,
wrinkles would form and propagate along the axial direc-
tion. The buckling pressure, P, is relatively constant as the
wrinkles develop.
Figure 3a indicates that as the engineering strain is
*5%, the buckling pressure reaches 2 MPa, and it varies
around 2–5 MPa until the engineering strain exceeds
*60%, close to the desired level. The maximum strain is
around 70%, mainly determined by the volume fraction of
the hollow space, measured by
e
t¼t=R, with tbeing the
wall thickness and Rthe radius. According to the Pthe-
orem [21], the buckling pressure (P) is a functional of E,
H
0
,R, and
e
t, with Ebeing the Young’s modulus; thus, P/E
=f(q,
e
t), where q=H
0
/Ris the aspect ratio and fis a certain
function. By adjusting E,q, and
e
t, the working pressure of
EAE can be varied to meet different functional require-
ments. As a new wrinkle is nucleated, the pressure would
drop; as the wrinkle is folded, the pressure would increase.
Therefore, the buckling plateau of a smooth tube is inevi-
tably jerky. If needed, the buckling plateau can be
smoothened by using tubes of crimped walls.
Although the buckling pressure fluctuates, because the
fluctuation frequency is high, it does not have any pro-
nounced influence on the drop-mass velocity, as shown in
Fig. 3b. After the initial setting period of a couple of ms,
the drop-mass velocity decreases nearly linearly, with the
deceleration of *500 m/s
2
,or*50 G. The simulation
results agree well with the experiment. The relatively
Fig. 3 Typical impact testing and computer simulation results: athe
dynamic stress–strain relation; bthe drop-mass velocity; and cthe
absorbed energy
M. Wang et al.
123 J. Mod. Transport.
constant velocity changing rate suggests that the protective
cell module works smoothly.
The absorbed energy is shown in Fig. 3c. Due to the
reduction in drop-mass velocity, the energy dissipation rate
keeps descending. After the initial setting period, most of
the kinetic energy is absorbed in the following *5 ms,
after which the deformation of the cell assembly becomes
less intensive.
4 Concluding remarks
Butterfly-shaped self-unfolding battery module is designed
and tested. The goal is to achieve a controlled resistance
and a large deformability, with the impact loading on
battery cells being minimized. The battery cells are freely
jointed by a set of hinges and initially fully folded. Upon a
compressive loading, the hinges, aided by a guide from the
top and an angle support from the bottom, help unfold the
cells. The resistance is offered by a set of energy absorp-
tion elements (EAE) in parallel to the battery cells. The
resistance and the cell motion are decoupled, so as to
independently adjust the performance of battery cells and
the mechanical responses of module. The resistance pres-
sure offered by the cell assembly is a few MPa; the
deformability is more than 60%. The relatively large
fluctuation of resistance pressure does not have much
detrimental effect on the smooth reduction of drop-mass
velocity. During impact, most of the kinetic energy is
absorbed in a few ms after the initial setting period. Such a
multifunctional battery module may be employed as
structural components in electric vehicles, so as to lower
the overall vehicle mass and increase the drive range.
Acknowledgements This research was supported by the Advanced
Research Projects Agency-Energy (ARPA-E) under Grant No. DE-
AR0000396, for which we are grateful to Dr. Ping Liu, Dr. John
Lemmon, Dr. Grigorii Soloveichik, Dr. Chris Atkinson and Dr.
Dawson Cagle.
Open Access This article is distributed under the terms of the
Creative Commons Attribution 4.0 International License (http://
creativecommons.org/licenses/by/4.0/), which permits unrestricted
use, distribution, and reproduction in any medium, provided you give
appropriate credit to the original author(s) and the source, provide a
link to the Creative Commons license, and indicate if changes were
made.
References
1. Guarnieri M (2012) Looking back to electric cars. In: HISTory of
ELectro-technology conference (HISTELCON), 2012 Third
IEEE. IEEE, pp 1–6
2. Howell D (2012) Battery status and cost reduction prospects. In:
EV everywhere grand challenge battery workshop
3. Young K, Wang C, Wang LY, Strunz K (2013) Electric vehicle
battery technologies. In: Garcia-Valle R, Lopes JAP (eds) Elec-
tric vehicle integration into modern power networks. Springer,
New York, pp 15–56
4. Srinivasan V (2008) Batteries for vehicular applications. In:
Hafemeister D, Levine M, Schwartz P (eds) Physics of sustain-
able energy: using energy efficiently and producing it renewably,
AIP conference proceedings 1044. Berkeley, USA, March 1–2,
pp 283–296
5. Laboratory test procedure for new car assessment program frontal
impact testing. Federal Highway Administration, U.S. Depart-
ment of Transportation
6. Markel T, Tataria HS, Howell D (2009) Battery requirements for
plug-in hybrid electric vehicles–analysis and rationale. National
Renewable Energy Laboratory, Golden
7. Mackay M (1997) A review of the biomechanics of impacts in
road accidents. In: Ambro
´sio JA, Pereira MFS, da Silva FP (eds)
Crashworthiness of transportation systems: structural impact and
occupant protection. Springer, Netherlands, pp 115–138
8. Ginsberg SD (2010) Battery pack. Publication number:
EP2418709 A1
9. Nelson PA, Bloom KGI, Dees DW (2011) Modeling the perfor-
mance and cost of lithium-ion batteries for electric-drive vehicles
(No. ANL-11/32). Argonne National Laboratory, Lemont
10. Wang M, Le AV, Noelle DJ, Shi Y, Meng YS, Qiao Y (2017)
Internal-short-mitigating current collector for lithium-ion battery.
J Power Sources 349:84–93
11. Wang M, Le AV, Shi Y, Noelle DJ, Qiao Y (2017) Heteroge-
neous current collector in lithium-ion battery for thermal-run-
away mitigation. Appl Phys Lett 110:083902
12. Wang M, Le AV, Shi Y, Noelle DJ, Wu D, Fan J, Lu W, Qiao Y
(2017) Sigmoidal current collector for lithium-ion battery. J Appl
Phys 121:015303
13. Wang M, Le AV, Shi Y, Noelle DJ, Yoon H, Zhang M, Meng Y,
Qiao Y (2017) Effects of angular fillers on thermal runaway of
lithium-ion battery. J Mater Sci Technol 32:1117–1121
14. Le AV, Wang M, Noelle DJ, Shi Y, Yoon H, Zhang M, Meng YS,
Qiao Y (2017) Effects of macromolecular configuration of ther-
mally sensitive binder in lithium-ion battery. J Appl Polym Sci
2017:45078
15. Shi Y, Noelle DJ, Wang M, Le AV, Yoon H, Zhang M, Meng YS,
Fan J, Wu D, Qiao Y (2017) Mitigating thermal runaway of
lithium-ion battery through electrolyte displacement. Appl Phys
Lett 110:063902
16. Hao F, Lu X, Qiao Y, Chen X (2017) Crashworthiness analysis of
electric vehicle with energy-absorbing battery modules. ASME J
Eng Mater Technol 139:021022
17. Winter M, Brodd RJ (2004) What are batteries, fuel cells, and
supercapacitors? Chem Rev 104(10):4245–4270
18. Aurbach D, Talyosef Y, Markovsky B, Markevich E, Zinigrad E,
Asraf L, Kim HJ (2004) Design of electrolyte solutions for Li and
Li-ion batteries: a review. Electrochim Acta 50(2):247–254
19. Wang Q, Ping P, Zhao X, Chu G, Sun J, Chen C (2012) Thermal
runaway caused fire and explosion of lithium ion battery. J Power
Sources 208:210–224
20. Heating values of hydrogen and fuels. Hydrogen Analysis
Resource Center, U.S. Department of Energy
21. Lu G, Yu TX (2003) Energy absorption of structures and mate-
rials. Elsevier, Amsterdam
A multifunctional battery module design for electric vehicle
123
J. Mod. Transport.
... Apart from that, the depreciation seen in a compact HEV is surprisingly higher which could be due to its lesser demand and product and rapid technology changes in the field. It is evident that HEVs in the midsize market are already price competitive and are affordable choices [301][302][303][304]. ...
Article
Full-text available
The rapid consumption of fossil fuel and increased environmental damage caused by it have given a strong impetus to the growth and development of fuel-efficient vehicles. Hybrid electric vehicles (HEVs) have evolved from their inchoate state and are proving to be a promising solution to the serious existential problem posed to the planet earth. Not only do HEVs provide better fuel economy and lower emissions satisfying environmental legislations, but also they dampen the effect of rising fuel prices on consumers. HEVs combine the drive powers of an internal combustion engine and an electrical machine. The main components of HEVs are energy storage system, motor, bidirectional converter and maximum power point trackers (MPPT, in case of solar-powered HEVs). The performance of HEVs greatly depends on these components and its architecture. This paper presents an extensive review on essential components used in HEVs such as their architectures with advantages and disadvantages, choice of bidirectional converter to obtain high efficiency, combining ultracapacitor with battery to extend the battery life, traction motors’ role and their suitability for a particular application. Inclusion of photovoltaic cell in HEVs is a fairly new concept and has been discussed in detail. Various MPPT techniques used for solar-driven HEVs are also discussed in this paper with their suitability.
Chapter
Full-text available
The real world characteristics of road accidents relevant to biomechanical considerations will be outlined. A brief introduction to the Abbreviated Injury Scale will be given, and then the frequencies and severities of the major collision types will be presented in terms of velocity change for various injury levels. Crash severity distributions for restrained and unrestrained conditions will be analysed. Distributions of injuries by anatomical regions will be illustrated for car occupants in the main types of collisions; frontal, lateral, rear and rollover. The limits of protection of current restraint systems will be illustrated. Gender, age, height, weight and sitting positions will be analysed to show the wide biomechanical response of the actual population exposed in collisions. The consequences of these real world variations for the optimisation of seat belts, using intelligent restraint system technology, will be presented.
Article
Full-text available
This chapter aims at bridging the gap between chemistry scientists and electrical engineers on electric vehicle (EV) batteries. The power and energy of electric propulsion are first reviewed in Sect. 2.2. Commonly used terms to describe battery performance and characterization are then introduced in Sect. 2.3, followed by the review of various battery charging methods and EV charging schemes in Sect. 2.4. The fundamentals of EV battery technologies are addressed in Sect. 2.5. Two currently most common EV battery technologies, namely, nickel metal hydride (NiMH) and lithium-ion (Li-ion), are covered. It is targeted for giving power engineers a basic understanding of battery chemistry. The EV battery modeling is introduced in Sect. 2.6. It is important for power engineers to appreciate the fundamentals of battery chemistry and battery modeling and use it for power electronic interfacing converter design, battery management, and system level studies. Section 2.7 covers the topic on battery characterization including battery model parameter estimation, state of charge (SOC), and state of health (SOH) estimation. The battery aggregation for power grid applications is discussed in Sect. 2.8. The concept of virtual power plant (VPP) for battery aggregation is introduced to support EV’s participation in power markets.
Article
In order to suppress heat generation of nail-penetrated lithium-ion battery (LIB) cell, thermally sensitive binders (TSB) based on poly(vinylidenefluoride) (PVDF) and poly(vinylidenefluoride-co-hexafluoropropylene) (PVDF-HFP) were investigated. The testing data showed that with appropriate treatment, TSB could efficiently reduce the peak temperature associated with internal shorting, and did not influence the cycling performance of LIB. The molecular weight of TSB was not a vital factor, while crosslinking was critical. This technology can be used to mitigate thermal runaway of LIB, enabling safe and robust large-scale energy storage. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 45078.
Article
Mechanical abuse often causes thermal runaway of lithium-ion battery (LIB). When a LIB cell is impacted, radial cracks can be formed in the current collector, separating the electrode into petals. As separator ruptures, the petals on positive and negative electrodes may contact each other, forming internal short circuit (ISC). In this study, we conducted an experimental investigation on LIB coin cells with current collectors modified by surface notches. Our testing results showed that as the current collector contained appropriate surface notches, the cracking mode of electrode in a damaged LIB cell could be adjusted. Particularly, if a complete circumferential crack was generated, the petals would be cut off, which drastically reduced the area of electrode involved in ISC and the associated heat generation rate. A parameterized study was performed to analysis various surface-notch configurations. We identified an efficient surface-notch design that consistently led to trivial temperature increase of ISC.
Article
Current collector accounts for more than 90% of the electric conductivity and ∼90% of the mechanical strength of the electrode in lithium-ion battery (LIB). Usually, current collectors are smooth metallic thin films. In the current study, we show that if the current collector is heterogeneous, the heat generation becomes negligible when the LIB cell is subjected to mechanical abuse. The phenomenon is attributed to the guided strain concentration, which promotes the separation of the forward and the return paths of internal short circuit. As the internal impedance drastically increases, the stored electric energy cannot be dissipated as thermal energy. The modification of current collector does not affect the cycling performance of the LIB cell. This finding enables advanced thermal-runaway mitigation techniques for high-energy, large-scale energy storage systems.
Article
Alkanes are investigated as thermal-runaway retardants (TRR) for lithium-ion battery (LIB). TRR is a chemical that can rapidly terminate exothermic reactions in LIB. Under normal working conditions, TRR is sealed in separate packages in the LIB cell, and upon mechanical abuse, it is released to suppress heat generation. The alkanes under investigation include octane, pentadecane, and icosane, among which pentadecane has the highest thermal-runaway mitigation (TRM) efficiency. In nail penetration test on coin cells, ∼4 wt. % pentadecane reduced the maximum temperature by ∼60%; in impact test on pouch cells, ∼5 wt. % pentadecane reduced the maximum temperature by ∼90%. The high TRM efficiency of pentadecane is attributed to its high wettability to separator and its immiscibility with electrolyte. By forming a physical barrier between the cathode and anode, pentadecane interrupts lithium ion (Li⁺) transport and increases the charge transfer resistance by nearly two orders of magnitude. The diffusion rate of pentadecane in the electrode layer stack was measured to be ∼580 μm/s.
Article
In the current study, we investigated sigmoidal current collector in lithium-ion battery (LIB). Traditionally, the active material in an LIB electrode is coated on a flat current collector. By rendering the current collector sigmoidal-shaped, cracking and debonding of active material layer could be promoted, which would considerably increase the internal impedance, as the LIB is mechanically abused, beneficial to thermal-runaway mitigation. The energy absorption capacity is also improved, enabling multifunctional LIB cell design. This technique has important relevance to large-sized LIB systems, for which cell robustness and fire safety are prioritized.
Article
As a clean energy technology, the development of electric vehicles (EVs) is challenged by lightweight design, battery safety, and range. In this study, our simulations indicate that using a flexible structure of battery module has the potential to overcome the limitations in battery-powered EVs, contributing to a new design. Specifically, we focus on optimizing the structure of vehicle battery packs, aiming to improve the crashworthiness of EVs through frontal crash simulations. In addition, by considering battery packs as energy-Absorption components, it is found that occupant compartment acceleration (OCA) is greatly reduced at an optimal working pressure of 4 MPa for battery module.
Article
By adding 1 wt% damage homogenizer (DH), i.e. carbon black microparticles, into the electrodes of lithium-ion batteries, thermal runaway can be mitigated as the battery cells are subjected to impact loadings. In a drop tower test, the generated heat of the modified cells is reduced by nearly 40%, compared with the reference cells. This phenomenon may be attributed to the weakening effect of the carbon black fillers. The shape of the filler grains does not have a pronounced influence on the temperature profile.
Article
This important study focuses on the way in which structures and materials can be best designed to absorb kinetic energy in a controllable and predictable manner. Understanding of energy absorption of structures and materials is important in calculating the damage to structures caused by accidental collision, assessing the residual strength of structures after initial damage and in designing packaging to protect its contents in the event of impact. Whilst a great deal of recent research has taken place into the energy absorption behaviour of structures and materials and significant progress has been made, this knowledge is diffuse and widely scattered. This book offers a synthesis of the most recent developments and forms a detailed and comprehensive view of the area. It is an essential reference for all engineers concerned with materials engineering in relation to the theory of plasticity, structural mechanics and impact dynamics. © 2003 Woodhead Publishing Limited Published by Elsevier Ltd All rights reserved.