Currently, there is a growing concern with air pollution, the depletion of natural resources, and,
consequently, with the damage imposed on the environment. Asphalt pavements need to be technically
viable from a mechanical point of view, present adequate functional characteristics in terms of comfort
and road safety, be sustainable and at an acceptable cost. In this context, this thesis aims to develop
recycled asphalt mixtures (ecological through the partial replacement of virgin material) and with new
functions through the integration of nano/microparticles for the surface layer of asphalt pavements. The
integration of nano/microparticles provides new capabilities (functionalization) to asphalt mixtures,
namely photocatalytic, superhydrophobic, and self-cleaning with the additional anti-aging effect of asphalt
binders. With the development of the photocatalytic capability, the asphalt mixtures are able to
photodegrade pollutants, and therefore improving the air quality. Regarding the superhydrophobic
capability, the functionalized asphalt mixtures start to repel the water, providing higher road safety,
especially in periods of rain and negative environmental temperature. With the self-cleaning effect, the
functionalized asphalt mixtures are able to clean pollutants, such as dirt particles, oil, and grease, over
their surface, mitigating the decrease of friction due to the presence of these materials over their surface.
Therefore, an extensive bibliographic review was carried out to support this doctoral thesis. Then, the
asphalt mixtures were functionalized using different application methods (volume incorporation,
modification of binder, and spraying coating) and using different materials (TiO2, ZnO, and
Polytetrafluoroethylene). The new properties and their impacts were analyzed from mechanical,
functional, and functionalization point of views. The main conclusions indicate that these materials can
functionalize the asphalt mixtures to provide them with new capabilities, presenting benefits for the
environment, society, economy, and for the performance of the asphalt mixtures.