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Thermal maturity of Miocene organic matter from the Carpathian Foredeep in the Czech Republic: 1D and 3D models

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... This interpretation is consistent with reconstruction based on the seismic data [34], and the low thermal maturity of organic matter in the Miocene strata of the Carpathian Foredeep, which is in the range of 0.3 to 0.6%VR [37,38]. In the Czech area of the Carpathian Foredeep, even at a depth of 4300 m, thermal maturity is 0.58%VR in the Miocene sediments [39]. ...
... Model 2 assumed that 1500 m of Devonian and 1200 m of Carboniferous was eroded. This scenario was based on the geological evolution of adjacent areas [39][40][41][42]. The model showed a significant increase in VR in the Devonian to Carboniferous (Figure 6). ...
... 3) assumed important erosional events in the Jurassic (500 m) and Cretaceous (1800 m) (Figure 7). However, this model appears to be less probable considering geological evolution of the study area [39][40][41][42]. This model also allows for proper calibration. ...
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Hydrocarbon exploration under thrust belts is a challenging frontier globally. In this work, 1-D thermal maturity modeling of the Paleozoic–Mesozoic basement in the northern margin of the Western Outer Carpathians was carried out to better explain the thermal history of source rocks that influenced hydrocarbon generation. The combination of Variscan burial and post-Variscan heating due to elevated heat flow may have caused significant heating in the Paleozoic basement in the pre-Middle Jurassic period. However, the most likely combined effect of Permian-Triassic burial and Late Triassic–Early Jurassic increase of heat flow caused the reaching of maximum paleotemperature. The main phase of hydrocarbon generation in Paleozoic source rocks developed in pre-Middle Jurassic times. Therefore, generated hydrocarbons from Ordovician and Silurian source rocks were lost before reservoirs and traps were formed in the Late Mesozoic. The Miocene thermal overprint due to the Carpathian overthrust probably did not significantly change the thermal maturity of organic matter in the Paleozoic–Mesozoic strata. Thus, it can be concluded that petroleum accumulations in the Late Jurassic and Cenomanian reservoirs of the foreland were charged later, mainly by source rocks occurring within the thrustbelt, i.e., Oligocene Menilite Shales. Finally, this work shows that comprehensive mineralogical and geochemical studies are an indispensable prerequisite of any petroleum system modelling because their results could influence petroleum exploration of new oil and gas fields.
... (Summary after Blizkovsky et al., 1994;Francu et al., 1994;Brzobohaty et al., 1996;Francu et al., 1996;Krejci et al., 1996;Zimmer and Wessely, 1996a;Picha and Peters, 1998;Arzmüller et al., 2006;Kostelnicek et al., 2006;Picha et al., 2006;Gerslova et al., 2015;Goldbach et al., 2017). ...
... (Summary after Blizkovsky et al., 1994;Francu et al., 1994;Brzobohaty et al., 1996;Francu et al., 1996;Krejci et al., 1996;Zimmer and Wessely, 1996a;Picha and Peters, 1998;Arzmüller et al., 2006;Kostelnicek et al., 2006;Picha et al., 2006;Gerslova et al., 2015;Goldbach et al., 2017). ...
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Conference Paper
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Regional kinematic analysis of the more internal domains prove the early-Variscan top-to-N lower crust synmetamorphic nappe shearing. The Lower Devonian collision caused ENE-WSW transtensional stretching - oblique rifting of the Brunovistulian foreland brittle crust. The top-to-N thrusting of the Variscan orogenic front is recorded by an a-type of stretching lineations in the gneiss of the Orlice-Sneznik Unit. Due to the NW-SE trend of the western indented edge of the Brunovistulian foreland, an oblique dextral wrench collision in the Moravosilesian Zone occurred. The late-Variscan transtension, with an ENE trend of stretching lineations, followed crust overthickening. The gravitational collapse and out-ward lateral escape in the inner and deeper domains was contemporaneous with wide-spread intrusions of S-type granites and the growing of subperpendicular half-grabens. -from Authors
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The thermal maturity of Paleozoic rocks in the SE part of the Bohemian Massif is characterized by clay minerals and organic matter. The expandability of illite-smectite (S in I-S), illite crystallinity index (IC) and reflectance of (R(r)) were measured and their regional distribution was evaluated. The mutual correlation of IC and R(r) from diagenesis to very low-grade metamorphism is compared with the published data and used to distinguish data with more reliable paleogeothermal information from those affected by other factors. In the SE part the Paleozoic units have illite-smectites with an expandable component of 15-35 % S. The reflectance values (R(r) of 0.55-1.1 %) are in good agreement with the expandability and suggest the oil window range of catagenesis with paleotemperature close to 100 °C. In the NNW part of the area the clays contain no expandable layers in illite. The illite crystallinity (IC of 0.36-0.24 Δ °2Θ) and vitrinite reflectance (R(r) from 3.17 to 5.23 %) indicate very low-grade metamorphic conditions with probable maximum paleotemperatures of 240-300 °C. The systematic change in both clay and organic parameters shows the gradual decrease in thermal exposure towards the front of the Variscan orogenic zone in the S and SE and suggest extensive erosion in the NNW.
Article
According to geomorphologic, seismic and gravimetric analyses carried out in the area between Frenštát pod Radhoštěm and Vsetín, today, the mountain regions of Kněhyně and their wider neighbourhood are not in balance with the platform basement and the processes of erosion. This is caused by the fact that, due to the accumulation of light masses of Lower Miocene rocks of the Carpathian Foredeep in footwall of the Godula nappe and frontal parts of the Magura nappe, mountain peaks arrived to higher altitudes than one would expect from simple overthrusting of the Silesian and Subsilesian units over the underlying foreland. Consequently, the whole mountain massifs experience gravitational spreading and break-up, which is well documented by development of deep and widespread deformations - predomininantly by pseudokarst phenomena. Concept of gravitational break-up of whole mountain complexes by mechanism of gravitational spreading is presented. The mechanism of gravitational spreading may in specific instances generate gravitational nappes but, for the most part, it is effective on continental slopes of the present-day oceans. More recently, however, the gravitational spreading is often considered in explanations of extension of mountain regions during final stages of orogenic cycles when the tectonic uplift exceeds topographic reduction due to denudation and erosion, which is the case of the Western Carpathians flysch.
Article
In the Magura Group of nappes, Cretaceous sediments were proved in the Rača and Bílé Karpaty units nearly in the whole range of the period. This was made possible by new biostratigraphic (foraminifers and calcareous nannofossils) and biofacies data. In the present paper, the Kurovice Klippe, Gault Flysch, Kaumberg Formation and the lower part of the Sólaň Formation are included in the Rača Unit, while the Hluk, Kaumberg and Javorina formations and the lowermost part of the Svodnice Formation are placed in the Bílé Karpaty Unit. Some lithostratigraphic units of Senonian age appear in tectonic slices only (Púchov Marl and Antonínek Formation) which makes their incorporation into the paleogeographical model of the Magura Group of nappes difficult.
Article
Biomarker analyses indicate that at least two petroleum systems operate in the Vienna basin, Carpathian thrust belt and the European foreland plate in Moravia - one associated with Jurassic and the other with Palaeogene organic-rich rocks. Four oils from the sub-Carpathian foreland plate and one sample from the Vienna basin were analysed and geochemically compared to extracts from Jurassic and Palaeogene source rocks. Two oils from the subthrust foreland plate (Lubna-18 and Dolni Lomna-1) are genetically related based on similar geochemical compositions. These oils show high oleanane and 24-nordiacholestane ratios, age-related biomarker ratios that are consistent with an origin from Palaeogene organic-rich rocks. These rocks are inferred to be either the Menilitic shales of the Carpathian thrust belt or autochthonous Palaeogene deposits buried below the thrust belt. Two other oils from the subthrust plate (Zdanice-7 and Damborice-16) correlate geochemically with extracts from Jurassic source rocks in the Sedlec-1 and Nemcicky-1 wells. Like the oil extracts, these oils lack oleanane and show low 24-nordiacholestane ratios, supporting an origin from Jurassic organic-rich marls. The oil sample from the Vienna basin (Tynec-34) appears to be a mixture of the two oil groups.
Article
Sedimentary basins in NW-Germany and the Netherlands represent potential targets for shale gas exploration in Europe due to the presence of Cretaceous (Wealden) and Jurassic (Posidonia) marlstones/shales as well as various Carboniferous black shales. In order to assess the regional shale gas prospectivity of this area a 3D high resolution petroleum system model has been compiled and used to reconstruct the source rock maturation based on calibrated burial and thermal histories. Different basal heat flow scenarios and accordingly different high-resolution scenarios of erosional amount distribution were constructed, incorporating all major uplift events that affected the study area. The model delivers an independent 3D reappraisal of the tectonic and thermal history that controlled the differential geodynamic evolution and provides a high-resolution image of the maturity distribution and evolution throughout the study area and the different basins. Pressure, temperature and TOC-dependent gas storage capacity and gas contents of the Posidonia Shale and Wealden were calculated based on experimentally derived Langmuir sorption parameters and newly compiled source rock thickness maps indicating shale gas potential of the Lower Saxony Basin, southern Gifhorn Trough and West Netherlands Basin.This article is protected by copyright. All rights reserved.
Article
The results of seismic measurements along three deep seismic sounding (DSS) profiles on the territory of Czechoslovakia and in adjacent countries have provided sufficient material about the crustal structure and the depth of the Moho discontinuity. These data, together with gravity and aeromagnetic data and the determinations of heat-flow values, were used to select several locations where the temperature—depth profiles were calculated. The Moho temperature of about 500 C beneath the Bohemian Massif increases to 800–1000 C and even more beneath the inner Neogene depressions of the Carpathian system. The regional differences in mantle heat-flow contribution between both these provinces may reach 1 μcal. cm−2 sec−1; such a variation in energy inflow may then be the driving force for the geological evolution. The geophysical implications of different thermal structure of the crust are discussed. Because of high subsurface temperatures in the Hungarian basin, partial melting at a depth of about 30 km may not be excluded.
Article
This paper presents a model of depositional history in the Karpatian stage, Lower Miocene of the Carpathian Foredeep based on the study of foraminifers. The paleoecological interpretations, and the data on bioevents and biofacies of the Karpatian deposits were obtained through the statistical evaluation of microfauna. The occurrence of rich faunas alternating with impoverished ones indicates unstable conditions in the depositional area. Euryoxybiont foraminifers such as Bolivina div. sp., Bulimina div. sp., Praeglobobulimina div. sp., and Uvigerina div. sp. dominate these faunas. Two biostratigraphical levels containing Uvigerina and an overlying one with Pappina breviformis (Papp and Turn.) were identified. Two stages of the development of a transgression can be distinguished. The first stage spread to the eastern part of the Carpathian Foredeep, where the sediments contain agglutinated foraminifers. The second stage reached the present location of the Karpatian deposits. Later shallow-water sediments in the western part of the Carpathian Foredeep have been eroded away.
Article
SUMMARY The coalification data (vitrinite reflectance, percentage Rm) from 49 boreholes located in the Czechoslovak part of the Upper Silesian Basin were processed and the palaeotemperature gradient which prevailed during the Namurian and the Early Westphalian was estimated. Very high gradients (mean: 95 Km-1) are calculated at least in the western part of the basin during the Namurian A. At that time, the Ostrava Formation (FM) was deposited with a high subsidence rate. The corresponding heat flow density of 200 mW m-2 may not reflect the characteristic heat flow density of the region, but may represent a subsurface value within the uppermost 2–3 km thick layer, probably sustained by the convective system inside the basin. The gradient during the Namurian B, C and Westphalian A is lower (mean: 77 K km-1 in the Karviná FM). It is suggested that the decrease in the gradient coincides with changes in the basin development. An intra Namurian hiatus occurred at the turn of the Namurian A and B. The lower thermal regime which governed during the sedimentation of the Karviná FM, results also from the Rm data of the Ostrava FM at the southern rim and in the Karviná part of the basin (mean gradient 60–65 K km-1). Due to the relatively small thickness of the Ostrava FM and/or the big thickness of the Karviná FM in these areas, the sediments of the Ostrava FM reached the maximum temperature during the deposition of the Karviná FM. Thus, the Rm data must reflect the lower gradient. By applying palaeogradients estimated in both formations together with present mean thermal conductivities within them, a heat flow density of 115–130 mWm-2 was computed. This value agrees well with the heat flow of 125 mWm-2 estimated for the Westphalian A in the Ruhr Basin by the same method.
Article
Selected representative core and gas samples from the Miocene sediments of the Polish part of the Carpathian Foredeep were analyzed by means of geochemical methods. The results of elementary analyses, vitrinite reflectance and δ13C-values of organic matter, as well as the Rock-Eval® data and distribution of n-alkanes and isoprenoids, have shown that the organic matter is mainly of type III (terrestrial origin) and presents a feeble degree of maturation (beginning of oil window at 2000–3000-m depth interval, according to vitrinite reflectance). According to °13C-values, however, methane in these series results from biogenic processes.
Article
The Lower Saxony Basin (LSB) in northwest Germany is one of the oldest oil‐producing basins in the world, where the first production well was drilled in 1864. It has been intensively investigated with respect to its hydrocarbon potential and can be regarded as a well‐studied example of a sedimentary basin that experienced strong inversion and uplift. Oil and gas source rocks of economic importance include Upper Carboniferous coals as well as Jurassic (Toarcian Posidonia Shale) and Cretaceous (Berriasian/Wealden) shales. We have developed a fully integrated 3D high‐resolution numerical petroleum systems model incorporating the LSB, and parts of the Pompeckj Block in the north as well as the Münsterland Basin in the south. Aside from temperature and maturity modeling calibrated by a large amount of vitrinite reflectance and downhole temperature data, we also investigated petroleum generation and accumulation with special emphasis on the shale gas potential of the Jurassic Posidonia Shale.
Article
The Brno Massif in Moravia, Czech Republic, is an important exposure of Precambrian basement in central Europe. It includes large volumes of Cadomian granitoids and a narrow fault-bounded zone with metagabbros, metadiorites, and metabasalts. This so-called Central Basic Belt also contains some metarhyolites; one of these was dated by means of the zircon evaporation method at 725 ±15 Ma. Chemical and isotope data show that the dated rock represents a mantle-derived magma which is cosanguinous with surrounding MORB-type metabasites. The data suggest that the Brno Massif hosts the oldest metabasite complex currently known in central Europe. Its formation apparently coincides with the main period of ocean-floor spreading and island-arc formation in the Panafrican orogens. This lends further support to the theory that the Brno Massif is a Gondwana-derived element.
Article
We have modelled three-dimensional seismic anisotropy of the mantle lithosphere from anisotropic parameters of teleseismic body waves. We invert jointly shear-wave splitting parameters and P residual spheres based on data from dense networks of temporary and permanent stations in four European regions ranging from the Variscan belt to the Baltic Shield. Changes in orientation of the large-scale anisotropy, caused by systematic preferred orientation of olivine, identify boundaries of domains of mantle lithosphere. Individual domains are characterized by a consistent large-scale orientation of anisotropy approximated by hexagonal or orthorhombic symmetry with generally inclined symmetry axes. The domains are separated by mapped tectonic boundaries (sutures), which cut the entire lithosphere. Besides the change of anisotropy orientation at domain boundaries, we often observe a change of the lithosphere and/or crust thicknesses. We do not detect any fabric of the mantle lithosphere, which could have been produced by a collision of microcontinents in a volume detectable by large-scale seismic anisotropy. The observations of consistent anisotropy within individual blocks of the mantle lithosphere reflect frozen-in olivine preferred orientation, most probably formed prior to the assembly of microcontinents that created the modern European landmass. Therefore, our findings support a plate tectonic view of the continental lithosphere as a mosaic of rigid blocks of the mantle lithosphere with complicated but relatively sharp contact zones. These contacts are blurred by the easily deformed overlying crust terranes.
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