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Environmental security control of resource utilization of shale gas’ drilling cuttings containing heavy metals

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The overall objective of this research project was to investigate the heavy metals environmental security control of resource utilization of shale gas’ drilling cuttings. To achieve this objective, we got through theoretical calculation and testing, ultimately and preliminarily determine the content of heavy metals pollutants, and compared with related standards at domestically and abroad. The results indicated that using the second Fike’s law, the theoretical model of the release amount of heavy metal can be made, and the groundwater environmental risk as main point compared with soil. This study can play a role of standard guidance on environmental security control of drilling cuttings resource utilization by the exploration and development of shale gas in our country.
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RESEARCH ARTICLE
Environmental security control of resource utilization of shale
gasdrilling cuttings containing heavy metals
Chao-qiang Wang
1,2,3,4
&Xiao-yan Lin
1,3
&Chun Zhang
2,4
&Xu-dong Mei
2,4
Received: 16 March 2017 /Accepted: 4 July 2017 /Published online: 7 August 2017
#Springer-Verlag GmbH Germany 2017
Abstract The overall objective of this research project was to
investigate the heavy metals environmental security control of
resource utilization of shale gasdrilling cuttings. To achieve
this objective, we got through theoretical calculation and test-
ing, ultimately and preliminarily determine the content of
heavy metals pollutants, and compared with related standards
at domestically and abroad. The results indicated that using
the second Fikes law, the theoretical model of the release
amount of heavy metal can be made, and the groundwater
environmental risk as main point compared with soil. This
study can play a role of standard guidance on environmental
security control of drilling cuttings resource utilization by the
exploration and development of shale gas in our country.
Keywords Environmental security .Shale gas .Drilling
cuttings .Resource utilization
Introduction
With the rapid development of Chinaseconomy,energyde-
mand is constantly increasing, and shale gas, as the new type
energy resources, has become one of the major motivations in
the economic development of China. In the course of explo-
ration and development of shale gas, we use water-based dril-
ling fluid in straight hole, and then water-based drillings cir-
culate the ground which includes water-based cuttings and a
portion of water-based mud. In addition, we use oil-based
drilling fluid of multi-interval fracturing technology in hori-
zontal well for gas recovery, and then oil-based drillings cir-
culate the ground which include oil-based cuttings and a por-
tion of oil-based mud. The pre-processes of water/oil-based
drilling fluid and cuttings are presented in Fig.1. All the pro-
cesses are mainly through the vibrating screen system, which
available the water/oil-based drilling cuttings. In one well
about 1000 m
3
water-based cuttings would be generated,
and about 250 m
3
oil-based cuttings would be generated.
Because they are a kind of solid waste which contains organic
pollutant, pressure filtration technique is used to ensure the
safe discharge. The water-based drillingswater content of
the produced will be controlled within 13% which can guar-
antee solidification treatment. The oil-based residuesoil con-
tent of the produced will be controlled within 0.3% through
pyrolysis procedures which can guarantee solidification treat-
ment (Leonard and Stegemann 2010).
Treatment processes of water-based drillings
Water-based drilling is a kind of solid waste which contains
organic pollutant, so it must be pre-processed to ensure safe
disposal. Figure 2is the treatment process drawing and com-
prehensive utilization of WDC. It is clear that the pressure
filtration technique is used to ensure the safe discharge of
Responsible editor: Philippe Garrigues
*Xiao-yan Lin
linxiaoyan@swust.edu.cn
1
Institute of School of Materials Science and Engineering, Southwest
University of Science and Technology, Sichuan Province,
Mianyang 621010, China
2
Chongqing Environmental Protection Center for Shale Gas
Technology & Development, Fuling, Chongqing 400800, China
3
Technology and Engineering Research Center of Biomass Materials,
Ministry of Education, Southwest University of Science and
Technology, Sichuan Province, Mianyang 621010, China
4
Chongqing Environmental Protection Engineering Technology
Center for Shale Gas Development, Fuling, Chongqing 408000,
China
Environ Sci Pollut Res (2017) 24:2197321983
DOI 10.1007/s11356-017-9703-0
Content courtesy of Springer Nature, terms of use apply. Rights reserved.
... Heavy metals most generally related to the poisoning of people are lead (Pb), mercury (Hg) and arsenic (As). Heavy metal poisoning may additionally take place as an end result of petroleum industrial exposure, air or water pollution, etc. (Kaewtubtim et al. 2016, Oz et al. 2019, Wang and Zhang 2017. ...
... This is not unconnected with the possibility that Penicillium chrysogenum-MK696383.1 may have different responses, adaptive mechanism and bioremediation approaches to lead in polluted soil (Oz et al. 2019). Furthermore, the rate of lead in the drilling waste samples relay on several factors including pH, temperature, formation solids, type of based muds, and mineral oils (Oz et al. 2019, Wang andZhang 2017). ...
... Mercury content was undetectable (below the detection limit of 0.001 mg/kg) before and after bioremediation treatment ( Table 5). Occurrences of some heavy metals (such as mercury, arsenic, etc.) in drilling wastes are noticeably associated with sources of oil-based muds cuttings (Wang and Zhang 2017), furthermore, mercury in the drilling waste samples ordinarily originate from the lube oil and grease. Similar preceding research detected zero mercury content in WBM drill-cuttings in distinctive components of the world (Oz et al. 2019). ...
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... An alarming point is the signal detected at 31.2 in 2θ that corresponds to the Pb phase (Lead) according to ICDD 04-0686 card. This component has been reported in some sludge and congenital waters, as well as, in contaminated sites whose source of generation are hydrocarbons (Yi et al., 2016;Wang et al., 2017;Gómez-Mellado et al., 2020). ...
... Also, it is estimated that metals such as Cd, Cr, Cu, Ni, Zn and, V as potentially toxic due to cumulative effects on ecosystems (Kovacs & Szemmelveisz, 2017;Bakshi et al., 2018). Similarly, it has been found that metals such as V, Pb and, Zn are associated with emissions and spills of products and waste from the oil industry (Wang et al., 2017;Xu et al., 2018;Khudur et al., 2018). These studies, coincide with the results of evaluations carried out in areas close to the study (Kennish & Paerl, 2010;Gómez-Mellado et al., 2020). ...
... For instance, cuttings may be used to manufacture concretes (Mostavi et al. 2015), non-fired bricks (Liu et al. 2018), sintered bricks (Liu et al. 2022), and cements (Liu et al. 2019). Notably, concrete and non-fired bricks are not considered reliable pathways for cuttings disposal in the long term because contaminants, such as drilling additives and heavy metals, are predominantly encapsulated during the manufacturing process and can migrate into the environment as a result of temperature and humidity changes (Wang et al. 2017). When preparing sintered bricks, the drilling cutting content used is always below 30%, and the low market price of such bricks makes this process unattractive (Liu et al. 2021a). ...
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... For example, some studies like the one of Wang et al. (2017) have reported the presence of V, Cr, Pb, and Ni in the rivers sediments and the coastal areas of sites adjacent to oil facilities. These reports are consistent with studies carried out at two oil assets: at Cinco Presidentes in Veracruz, and at Samaria-Luna in Tabasco, in which Pb, Zn, Na, and Ni outside of regulatory ranges have been detected, as well as V, Cr, and Cd have been observed in different concentrations (Ruiz-Fernández et al., 2019;Gómez-Mellado et al., 2020;Machain-Castillo et al., 2020). ...
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Oil shale can potentially be utilized in manufacturing the Portland cement. In addition to the utilization of the spent oil shale after combustion, it can also reduce the required temperature for the clinkering reactions during the production of Portland clinker. A study on the Jordanian oil shale was performed to maximize the use of oil shale ash in the manufacturing of Portland cement. It was found that Jordanian oil shale can be used up 15% with the typical raw materials to produce Portland clinker without altering its principle properties. The corresponding temperature required to generate the required liquid for the clinkering reactions as well as the essential ingredients for clinker was found to be around 1300°C. The optimized blend ratio obtained was equal to of 16% oil shale ash, 18% kaolinite, and 66% calcite. The operating temperatures for this optimized blend ratio were found to be between 1300 and 1350°C. The resulting Portland clinker from this ratio will need further testing in accordance with international standards for Portland cement to examine properties like strength, setting time, etc.
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This study determined the concentration of three heavy metals zinc (Zn), lead (Pb), and cadmium (Cd) in soil and in a woody plant species, Milicia excelsa, at Ishiagu quarry, Nigeria. The highest soil concentrations of Zn, Pb, and Cd in soil were obtained at 1 m from the quarry site. In M. excelsa, the highest concentrations of Zn, Pb, and Cd were 3.12–9.1, 3.9–6.01, and 0.51–1.12 mg kg−1, respectively. There were significant positive correlations between Cd and Zn (r = 0.963) and Cd and Pb (r = 0.974) in plants as well as between Cd and Pb (r = 9.84) in soil. The level of Cd in soil reflected significant pollution compared to average global concentrations in soils.