The frequent eruptive activity from the Southern Volcanic Zone (SVZ) directly affects the sedimentation in adjacent areas, and the dominance of the westerlies in austral latitudes allowed the dispersion of pyroclastic products over Argentinean territory. The Nahuel Huapi National Park (NHNP) and surroundings are adequate places for the study of quaternary pyroclastic sedimentation due to its geographic location and the geological setting. This has been evidenced with the recent eruptions of Cordón Caulle and Calbuco volcanoes, among others. The diversity of environments within the Park, lacustrine and superficial, offers the possibility to perform comparative studies about past pyroclastic events and its effects. Considering this, the objective of the present work is to characterize volcanic ash deposits identified in different depositional settings, both superficial and lacustrine, defining the origin volcano and comparing the sedimentation conditions and the preservation potential of pyroclastic material in the different environments. The characterization of volcanic layers included the sedimentology of the sequences, and the geochemistry, mineralogy and mineral chemistry of the volcanic components. This information allowed to identify the volcanic origin and to perform correlations between sites when it was possible.
On one hand, medial-proximal deposits from superficial environments were studied by the opening of a pit. The proximity of the sampling site to the Puyehue-Cordón Caulle Volcanic Complex, close to the Cardenal Samoré international border (Argentina-Chile border) and next to the NHNP, allowed to obtain a depositional sequence with high influence of such Complex. It was possible to identify 3 deposits which were correlated, in part, with previous bibliographic information, identifying products emitted by Puyehue-Cordón Caulle Volcanic Complex during the last 1100 years approximately.
In addition, two lacustrine sequences recovered from El Trébol lake, located in medial-distal zones from the SVZ inside the NHNP were studied, and the piroclastic layers were analyzed. Eight tephra layers were identified and the morphological, petrological, mineralochemical, and geochemical characterization of the most abundant components, named pumice, scoria, glass shards, and crystaloclast, was carried out. Each tephra layer was correlated with material of explosive origin from Cordón Caulle Complex and Calbuco volcano, mainly based on the geochemical information. The eruptive chronology was established by the dating of one sequence using 210Pb and 137Cs, the estimation of sedimentation rates, and from available information about historical eruptions. In some cases, pyroclastic layers corresponded to estimated dates older than the most ancient historical records of these volcanoes, spanning approximately 500 years before present.
The magma features that originate the pyroclasts, the atmospheric factors, the kind of depositional environment, and the geographic location regarding the different volcanic sources strongly determine the dispersion patterns, the importance, and the preservation potential. This is evidenced in the presence or absence of tephra layers and the complexity in the field correlations, as was observed in the lack of correlation of deposits between the two environments analyzed in this work. However, each kind of environment has advantages and disadvantages in the study of volcanic events, being highly important the sampling in several dispersion directions to obtain better information of the pyroclastic dispersal phenomenon in the past.
Beside these complexities, the correct characterization of a tephra layer, mainly in lacustrine
environments, gives the possibility to be applied as a valuable tephrochronological tool, very important to perform correlations and dates in areas with high eruptive frequency, in periods in which other methods result inaccurate.