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Investigation of wood combustion in the high-enthalpy oxidizer flow

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Abstract

The experimental data of wood combustion in the high-enthalpy oxidizer flowresearch is presented. Combustion laws of two wood species (pine and birch) in a hybrid rocket engine (HRE) are obtained. Heat flows from the flame to the condensed phase surface are defined. The prospects of the wood use in the HRE (based on thrust characteristics) are shown.
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Investigation of wood combustion in the high-enthalpy oxidizer flow
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2017 J. Phys.: Conf. Ser. 789 012041
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Investigation of wood combustion in the high-enthalpy
oxidizer flow
S M Reshetnikov, I A Zyryanov, A G Budin, A P Pozolotin
Department of Engineering Physics ,610000, Kirov, Moskowskaya Street, 36, Russia
E-mail: b185@mail.ru
Abstract. The experimental data of wood combustion in the high-enthalpy oxidizer
flowresearch is presented. Combustion laws of two wood species (pine and birch) in a hybrid
rocket engine (HRE) are obtained. Heat flows from the flame to the condensed phase surface
are defined. The prospects of the wood use in the HRE (based on thrust characteristics) are
shown.
Wood combustion research in a high-enthalpy flow is an important scientific and technical task.On
the one hand, the wood can be used as fuel in a hybrid rocket engines whose development are actively
conducted in recent years [1-2].On the other hand, investigation results are interesting to forecasting
and fire prevention systems developers [3].
Based on the above, the task of the work is wood combustion in high-enthalpy flow research.
The experimental setup is a stand with a hybrid rocket engine, described in detail in [4].As two
woodspecies birch and pine are selected.The wood sample is a cylinder with initialmass
0
m
, length of
0.2m and channel radius
0
r
= 0.01m.Before the testing started the samples are dried in an oven at a
temperature of 600 °C for 3 days until the moisture content of 6%. Samples moisture is determined by
electric hygrometers.Combustion is performed in the gaseous oxygen withstream density [10-40]
kg/m2s.The linear combustion rate is calculated according to the formula given in [5], thrust
measurement is madeby the load cell[4]. Heat flow calculation from the flame to the wood surface
produced by the method described in [6]. Carbon black investigation is produced on the microscopes
JEM-2100 and JSM-6510 LV.
Fig. 1 shows a graph of linear wood combustion rate against oxygen flux.
Figure 1.Dependence of linear wood and PMMA combustion rate against oxygen flux.
1
International Conference on Recent Trends in Physics 2016 (ICRTP2016) IOP Publishing
Journal of Physics: Conference Series 755 (2016) 011001 doi:10.1088/1742-6596/755/1/011001
Content from this work may be used under the terms of the Creative Commons Attribution 3.0 licence. Any further distribution
of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.
Published under licence by IOP Publishing Ltd
LTP2016 IOP Publishing
IOP Conf. Series: Journal of Physics: Conf. Series 789(2017) 012041 doi:10.1088/1742-6596/789/1/012041
According to Fig. 1, combustion laws are the following:
39.0
)(1.0

U
for birch
forpine
57.0
)(029.0

U
forPMMA
Combustion law for PMMA is in good agreement with the data presented in [7].The exponent in
the combustion law refers to combustion mode, in our case for wood it is a mixed mode (diffusion-
kinetic).
Fig. 2 shows a graph of thrust against oxygen flux.
Figure 2.Dependence of the thrust against oxygen flux density.
According to Fig. 2, the thrust of HREwith wood almost as good asthrust of HREwith
PMMA.This indicates the prospects of wood using as a propellant.
Fig. 3 shows agraph of the combustion rate against heat flux from the flame to the wood
surface.
Figure 3.Dependence of linear wood combustion rate against heat flux density.
The value of the heat flux density from the flame to the wood surface is in the range [180-360]
2
m
kW
(Fig. 3).However, combustibility tests carried out when the samples are exposed bythe heat
flux value to 50
2
m
kW
[3]. Such data may not be sufficient to predict the development of a forest fire
with a heat flow of about 200
2
m
kW
, given in [8].
The thickness of the carbon layer formed during wood combustion in the HRE lies within [200-
400] micrometers.In tests [3] carbon layer thickness reaches 5000 micrometers at the heat flux
density 50
2
m
kW
.
2
LTP2016 IOP Publishing
IOP Conf. Series: Journal of Physics: Conf. Series 789(2017) 012041 doi:10.1088/1742-6596/789/1/012041
Thus, a comprehensive study of wood combustion in high-enthalpy flow is conducted, resulting in:
1. Combustion laws for birch and pine wood is defined, combustion mode is diffusion-kinetic;
2. Thrust of HRE with wood compared to thrust of HRE with PMMA, prospects of using of wood as a
new type of fuel are shown;
3. It has been determined that the heat flux from the flame to the wood surface with the high-enthalpy
combustion value in 3-7 times higher than the indicator used for assessing the flammability in case of
fire.
4. It is shown that the thickness of the carbon layer after wood combustionin high-enthalpy flow is 12
times lower than thickness obtained by standard fire tests.
References
[1] Ivanov NN, Ivanov A N, The use of hybrid rocket engines in space vehicles, Journal of FGUP
NPO named afterLavochkin,2010, V.3, P. 50-55.
[2] Gubertov A M, Mironov V V, Gollender R G and others, The processes in hybrid rocket
engines, ed. ASKoroteeva,Moscow: Nauka, 2008, 405 P.
[3] AssevaR M, Serkov B B, Sivenkov A B, Wood combustion and its fire behavior, Moscow:
Academy of GPS MCHS Russia, 2010, 262 P.
[4] ReshetnikovS M, ZyryanovIA, PozolotinA P, BudinA G, Electrostatic field influence on the
combustion rate in hybrid rocket. Kazan, Vestnik of the Kazan State Technical University,
2015, V.71, P. 52-57.
[5] Hudson M K et al. Guanidiniumazo-tetrazolate (GAT) as a high performance hybrid rocket fuel
additive, J. Pyrotechnics, 2004. V.19, P. 37-42.
[6] PozolotinAP, ReshetnikovS M, ZyryanovI A,BudinA G, ShaurkoP N, Methods of experimental
study of wood combustion in a high-enthalpy flow, Kirov, Society, science, innovation
(SPC-2016): Coll. materials, 2016.P. 1746-1751.
[7] Yuasa S, Yamamoto K, Hachiya H, Kitagawa K, Development of a Small Sounding Hybrid
Rocket with a Swirling-Oxidizer-Type Engine JAPAN AIAA, 2001, 353.
[8] ValendikE N, KosovIV, Thermal radiation of forest fires and its possible effects on the forest
stand, 2008, V.25, № 1-2, P. 88-92.
3
LTP2016 IOP Publishing
IOP Conf. Series: Journal of Physics: Conf. Series 789(2017) 012041 doi:10.1088/1742-6596/789/1/012041
... Wood is a renewable hydrocarbon fuel, and the prospects for its use have not been fully explored. One of the research areas is the high-enthalpy combustion study [8]. This kind of combustion realized in the combustion chamber of hybrid rocket engines [9], in conditions of fires spreading [10]. ...
Article
Full-text available
Experimental data of the wood combustion in a high-enthalpy flow in the presence of an electrostatic field with a potential difference of 5 kV research are given. Considering the field effect combustion laws are obtained for birch, used as a solid fuel component in a hybrid rocket engine.
Article
Full-text available
Polymers combustion in high-enthalpy flows is realized in many power plants. This process is energetically favorable, but there are also significant problems, the main of which is the low combustion rate. An effective method to increase the condensed component regression rate is the imposition of an electrostatic field on the polymer, the polymer reaction layer, and the combustion zone. The paper proposes a physical and mathematical model of the electrostatic field influence on the PMMA combustion rate in high-enthalpy flows. The combustion rate values calculated within the described model coincide with the experimental results within the error.
Article
Full-text available
The purpose of this investigation was to find a high regression rate fuel suitable for use as a mixture with hydroxyl-terminated polybutadi- ene (HTPB). Guanidinium azo-tetrazolate (GAT) is the compound that was the focus of our re- search. GAT is a salt containing a high per- centage of nitrogen. It has two conjugated ni- trogen rings, which are negatively charged, and a positively charged component consisting of nitrogen, carbon, and hydrogen. In addition to the high-energy content of this compound, as a salt, it has a lower heat of degradation due to the ease of breaking its ionic bonds. GAT was found to react with N100, a com- mon curative for HTPB. An alternative isocyan- ate curative was found, polyisocyanate (PAPI), with which it did not react. This polymer matrix was found to be suitable for GAT. The resulting fuel grains were difficult to cast due to the rapid polymerization of the HTPB/PAPI. Once grains were cast, they required no special care in storage or firing. The fuel grains with the GAT additive were fired for 3-second runs with oxygen flows of 0.04, 0.06, 0.08, 0.10 and 0.12 lbm/s. The regression rate of each GAT concentration was computed and plotted vs. the oxidizer mass flux on a log/log scale. The resultant curve is fit to the equation, b o ra G = , and the quantities a and b were recorded for each curve. GAT was found to increase the regression rate of HTPB when it was used as an additive. The resultant pressure and thrust from firing even the highest GAT concentrations at high oxygen flows still remained within safe operat- ing parameters of the UALR hybrid rocket mo- tor facility.
The use of hybrid rocket engines in space vehicles
  • N N Ivanov
  • A Ivanov
Ivanov NN, Ivanov A N, The use of hybrid rocket engines in space vehicles, Journal of FGUP NPO named afterLavochkin,2010, V.3, P. 50-55.
The processes in hybrid rocket engines
  • A M Gubertov
  • V V Mironov
  • R Gollender
  • Others
Gubertov A M, Mironov V V, Gollender R G and others, The processes in hybrid rocket engines, ed. ASKoroteeva,Moscow: Nauka, 2008, 405 P.
Wood combustion and its fire behavior
  • M Assevar
  • B B Serkov
  • A Sivenkov
AssevaR M, Serkov B B, Sivenkov A B, Wood combustion and its fire behavior, Moscow: Academy of GPS MCHS Russia, 2010, 262 P.
Electrostatic field influence on the combustion rate in hybrid rocket
  • M Reshetnikovs
  • Zyryanovia
  • P Pozolotina
  • G Budina
ReshetnikovS M, ZyryanovIA, PozolotinA P, BudinA G, Electrostatic field influence on the combustion rate in hybrid rocket. Kazan, Vestnik of the Kazan State Technical University, 2015, V.71, P. 52-57.
Methods of experimental study of wood combustion in a high-enthalpy flow, Kirov, Society, science, innovation (SPC-2016): Coll. materials
  • Reshetnikovs M Pozolotinap
  • A Zyryanovi
  • G Budina
  • N Shaurkop
PozolotinAP, ReshetnikovS M, ZyryanovI A,BudinA G, ShaurkoP N, Methods of experimental study of wood combustion in a high-enthalpy flow, Kirov, Society, science, innovation (SPC-2016): Coll. materials, 2016.P. 1746-1751.
Thermal radiation of forest fires and its possible effects on the forest stand
  • N Valendike
  • Kosoviv
ValendikE N, KosovIV, Thermal radiation of forest fires and its possible effects on the forest stand, 2008, V.25, № 1-2, P. 88-92.
  • S Yuasa
  • K Yamamoto
  • H Hachiya
  • K Kitagawa
Yuasa S, Yamamoto K, Hachiya H, Kitagawa K, Development of a Small Sounding Hybrid Rocket with a Swirling-Oxidizer-Type Engine JAPAN -AIAA, 2001, 353.