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Natural Cellulose Fiber from Mendong Grass (Fimbristylis globulosa)

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The global waste problems resulting from the use of synthetic fiber are becoming increasing environmental concerns. It would be better if the synthetic fibers give way to the natural fibers as renewable resources for environmental sustainability. New sources of natural fibers are being developed in recent years as natural fibers offer many advantages over synthetic fibers. Mendong grass is one of the natural sources of fiber. It is easy to grow and cultivate, and it offers several harvests from one plantation. The fiber has found many applications for small-scale industries and helps in economic welfare of small farmers. This chapter provides a general overview of mendong grass cultivation and obtaining fiber. The chemical, physical, mechanical, and thermal properties and prospective application of the mendong fiber are also presented. Agricultural crops, forest trees, and other plant species have many uses for the farming community. Plant-based materials have been used traditionally for food and feed. Biobased polymeric products based on green materials such as plant and agricultural stocks are the basis for forming a portfolio of sustainable, eco-efficient
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Chapter 3
Natural Cellulose Fiber from Mendong
Grass (Fimbristylis globulosa)
Heru Suryanto, Solichin Solichin and Uun Yanuhar
Abstract The global waste problems resulting from the use of synthetic ber are
becoming increasing environmental concerns. It would be better if the synthetic
bers give way to the natural bers as renewable resources for environmental
sustainability. New sources of natural bers are being developed in recent years as
natural bers offer many advantages over synthetic bers. Mendong grass is one of
the natural sources of ber. It is easy to grow and cultivate, and it offers several
harvests from one plantation. The ber has found many applications for small-scale
industries and helps in economic welfare of small farmers. This chapter provides a
general overview of mendong grass cultivation and obtaining ber. The chemical,
physical, mechanical, and thermal properties and prospective application of the
mendong ber are also presented.
Keywords Mendong Fiber structure Mechanical properties Thermal
properties
3.1 Introduction
Agricultural crops, forest trees, and other plant species have many uses for the
farming community. Plant-based materials have been used traditionally for food
and feed. Biobased polymeric products based on green materials such as plant and
agricultural stocks are the basis for forming a portfolio of sustainable, eco-efcient
H. Suryanto (&)S. Solichin
Department of Mechanical Engineering, Universitas Negeri Malang,
Jl. Semarang 6, Malang, East Java, Indonesia
e-mail: heru.suryanto.ft.@um.ac.id
U. Yanuhar
Biotechnology Laboratory, Department of Fisheries and Marine Science,
University of Brawijaya, Jl. Veteran, Malang, Indonesia
©Springer International Publishing Switzerland 2016
K.G. Ramawat and M.R. Ahuja (eds.), Fiber Plants, Sustainable Development
and Biodiversity 13, DOI 10.1007/978-3-319-44570-0_3
35
products which compete with synthetic products in market. The production of
chemicals and materials from biobased feedstocks is expected to increase from
todays 5 % level to about 12 % in 2010, about 18 % in 2020, and about 25 % in
2030 (Mohanty et al. 2005). Expectations are that the production of bulk chemicals
from renewable resources could reach 113 million tons by 2050. It represents 38 %
of all organic chemical production (de Jong et al. 2012).
Environmental sustainability-based technology is a global issue to move away
from synthetic material to renewable resources. The synthetic ber beneted human
in various ways. Synthetic bers are very durable and non-degradable, depending
on their composition and the particular application. The disposal of parts made of
synthetic ber, such as composite for packaging containers and trash bags, also
creates an environmental problem. It requires alternative ways to secure sustainable
world development. Renewable biomaterials can be used as an alternative to replace
the synthetic products.
Natural bers have been offering many advantages over the synthetic bers in
recent years. The advantages of natural ber as reinforcement composite are low
price, low density, easy to be separated, abundantly available, renewable,
biodegradable, and no health hazard (Li et al. 2007; Mu et al. 2009). Several
alternatives of ber sources, especially agricultural by-products such as ramie
(Marsyahyo et al. 2008), banana (Venkateshwaran and Elayaperumal 2010), kenaf
(Akil et al. 2011), hemp (Beckermann and Pickering 2008), Sisal (Li et al. 2000),
Indian grass (Liu et al. 2004), Napier grass (Reddy et al. 2009), and Pineapple
leaves (Mishra et al. 2004), have been used to produce cellulose bers.
Traditionally, mendong grass has been used for a long time by the community
for mats, rope bers, and other product such as handbags, baskets, and furniture
mats. In Indonesia, the grass is grown as a crop cultivated in some regions of Java,
Sumatra, and Nusa Tenggara. Estimated production of mendong in Java, Indonesia,
was 14,000 tons/year (Suryanto et al. 2014b). Since it has an economic potency,
mendong needs more intensive cultivation.
3.2 Biology of Mendong Grass (Fimbristylis globulosa)
3.2.1 Taxonomy
Fimbristylis is a genus of sedges that known commonly as a mbristyle, mbry, or
fringe-rush. Several continents have native species, but many species have been
introduced to regions where they are not native. Mendong grass (Fimbristylis
globulosa) was categorized as cyperaceae family and genus of Fimbristylis Vahl.
This species is a synonym of Fimbristylis umbellaris (Table 3.1).
36 H. Suryanto et al.
3.2.2 Ecology
Mendong grass is originated in the Southeast Asia. This plant requires a watery
environment for better growth. Therefore, mendong grass is easily found in the
technically irrigated rice farm or swamps where there is always standing water
year-round (Fig. 3.1). Mendong grass can grow well in the area that has an altitude
of 300700 m above the sea level, provided there is enough water, and exposed to
full sunlight. These plants do not require particular soil types, but it would be better
if planted in the sandy soils. In the marshy soils, mendong plants can also grow
well. Mendong plants require plenty of water similar to the rice plants. Therefore,
the mendong plants should not face water shortage, especially in the dry season.
The mendong plants that lack water will turn yellow producing trunk of inferior
quality. Well-maintained mendong plants ourish and produce good quality stalk
mendong for long term, which are very strong.
Before the harvest is conducted, the water that inundated the plant area is
removed in advance so that the surface of the land is visible and harvesting of
mendong can be done easily. Mendong harvest is done by cutting the stalks
mendong 3 cm above the surface of the ground using the sharp sickle leaving the
clump of roots in the soil. After 1 month, clumps will sprout again and can be
harvested after 3.54.5 months. This cycle is repeated up to 5 times in 2 years.
After that, the plant was dismantled for the processing of land for the next planting.
Farmers can save costs for soil tillage by harvesting ve times the grass from one
sowing. Managing the harvest and post-harvest should be done adequately and
correctly to maintain the quality of mendong straw.
3.2.3 Morphology and Structure
Mendong grass is an annual plant with morphological characteristics such as stalks
green shiny, rhizomes short, brous roots, and grooved (Fig. 3.2). Mendong leaves
Table 3.1 Taxonomy of mendong grass (USDA 2015)
Kingdom PlantaePlants
Subkingdom TracheobiontaVascular plants
Superdivision SpermatophytaSeed plants
Division MagnoliophytaFlowering plants
Class LiliopsidaMonocotyledons
Subclass Commelinidae
Order Cyperales
Family CyperaceaeSedge family
Genus Fimbristylis Vahlmbry
Species Fimbristylis globulosa (Retz.) Kunthglobe mbry
3 Natural Cellulose Fiber from Mendong Grass (Fimbristylis globulosa)37
are often reduced to sessile, hairy on the edges and have a small bula. Mendong
leaves grow on the top of the stem with some strands. Mendong straw is actually a
ower stalk. The straw is compact, slender, hollow, 0.20.4 cm in diameter, and
fast becoming stiff and looks like a cylinder but almost attened beneath the ower
stalk. Straw length can reach 1.51.7 m. This straw is harvested and used in the
manufacture of various goods for human needs.
Mendong straw contains ber bundles, vascular bundles, xylem, phloem, and
aerenchyma (Fig. 3.3a). The most mendong bers are located under the epidermis.
Some bers present near the vascular bundles in the middle of the straw. Fibers are
a bit at shaped with varied length, and pores can be seen on the ber wall. In the
transverse sections, the straw consists of 512 vascular bundles which mostly
located in the center of the straw (Fig. 3.3a, b). The ber bundle consists of some
individual bers (Fig. 3.3f, g). Each ber has a lumen, middle lamella, primary
wall, and a secondary wall (Fig. 3.3d). The primary wall is usually very thin
(<1 lm), but the secondary wall is thick. It is composed of three layers, consists of
microbrils with a different orientation that contains larger quantities of cellulose
molecules (*80 %). This wall is the main contributor to the overall properties of
ber. The microbrils present parallel to each other forming a steep helix around
the cell (Akil et al. 2011).
Fig. 3.1 Mendong grass in land (a), harvest of mendong grass (b), and dried mendong grass (c)
38 H. Suryanto et al.
3.3 Mendong Fiber Properties
3.3.1 Chemical Composition
The plant contains large amounts of water due to its semiaquatic habitat. Based on
the dry weight of the plant, all plant-based polymers were composed of sugars
(carbohydrates) in combination with lignin and with lower amounts extractable
proteins, starch, and inorganic materials. These chemicals are present in outer cell
wall layer consists of primary and secondary wall. The chemical composition varies
in each plant, even in the different parts of the same plant and in different plants
depending upon geographic location, age, climate, and soil conditions (Rowell et al.
2000).
Fig. 3.2 Mendong grass: asingle mendong grass, bower, and croot
3 Natural Cellulose Fiber from Mendong Grass (Fimbristylis globulosa)39
Fig. 3.3 Structure of mendong ber: adry mendong straw cutoff, bcomponent of fresh mendong
straw, cber bundle in dry mendong straw, dber bundle in wet mendong straw (observed by
optic microscope), eextracted mendong ber, fsingle-ber bundle, and gsingle-cell ber (SEM
2000)
40 H. Suryanto et al.
The properties of ber are inuenced by the chemical composition, particularly
cellulose. Cellulose determines the strength of bers because the cellulose has a
high modulus of 45 GPa in the plant (Mwaikambo and Ansell 2006).
Hemicellulose is a polysaccharide with low molecular weight. It often forms
copolymers with glucose, glucuronic acid, mannose, arabinose, and xylose. It may
take the form of random, amorphous branched, or nonlinear structure with low
strength. Hemicellulose easily hydrolyzed by dilute acid or alkali, or enzyme
hydrolysis (Summerscales et al. 2010). At the plant ber level, hemicellulose serves
as a matrix for cellulose (Bergander and Salmen 2002) and responsible for moisture
absorption, both bio- and thermal degradation of the bers.
Lignin provides rigidity to the plants. It is present localized to the luminal
surface and around porous wall area to maintain the strength of the wall and helps
transport water. Lignin is resistant to microorganisms attack due to the presence of
aromatic rings, which provides resistance to the anaerobic processes (Bismarck
et al. 2005). Lignin is thermally stable but responsible for the UV degradation of the
bers (Yi et al. 2010; Akil et al. 2011). Lignin strength is 100 times higher com-
pared with hemicellulose at 70 % moisture level (Cousins 1976); thus, lignin can
inuence the ber structure, properties, and morphology.
The mendong ber is composed of cellulose of 72.14 %, hemicellulose 20.2 %,
lignin 3.44 %, extractive matter 4.2 %, and moisture of 4.25.2 %. Table 3.2
shows a comparison of chemical content of others bers with the mendong ber. It
is clear from these data that the mendong ber has high cellulose content but lower
than established ber such as cotton and ax.
Table 3.2 Chemical content of mendong ber as compared to other natural bers
Fiber Cellulose
(%)
Hemicellulose
(%)
Lignin
(%)
Others
(%)
Moisture
content (%)
References
Mendong 72.14 20.2 3.44 4.2 4.25.2 Suryanto et al.
(2014b)
Cotton 8590 13 0.7
1.6
5.4
13.3
810 Foulk et al.
(2011)
Flax 85 9 4 2 8.7610 Foulk et al.
(2011)
Jute 5863 2024 1215 10.99 Wang et al.
(2009)
Rice
straw
64 8 28 9.8 Reddy and
Yang (2006)
Sea grass 57 28 5 10 Davies et al.
(2007)
3 Natural Cellulose Fiber from Mendong Grass (Fimbristylis globulosa)41
3.3.2 Physical Properties
The mendong ber bundle is consist of some single-cell ber having 9.16 and
923 lm diameter and length, respectively (Suryanto et al. 2014b). The mendong
ber varies in shape and diameter. The average diameter of the ber is 33.4 lm
with the aspect ratio and density of 101 and 0.892 g/cm
3
, respectively (Table 3.3).
The physical properties of mendong are dependent on the species, maturity, and
fertilization and site of growth. Comparison of physical properties of other bers is
shown in Table 3.3. The mendong ber has low density compared with cotton, ax,
rice straw, jute, and sea grass ber.
Biober can be regarded as a composite of cellulose brils, formed in a matrix of
lignin and hemicelluloses (Jayaraman 2003). The structure and the properties of the
bers are inuenced by both dimension and arrangement in ber bundle. High
aspect ratio of bers will improve the modulus and strength by optimizing stress
transfer between the matrix and the cellulose.
The total content of cellulose and non-cellulose ber constituents determines the
structure, properties, and affect to the crystallinity (Reddy and Yang 2005). The
mendong ber was arranged by the crystalline structure of cellulose. The
semicrystalline cellulose structure of mendong produced three peaks at 2hof 16.5°,
22.5°, and 34.5°. The third peak at 34.5° corresponds to 1/4 of the length of one
cellobiose unit and arises from ordering along the ber direction. It is sensitive to
the alignment of the chains into brils (Cheng et al. 2011). The amorphous com-
ponent showed the little-diffracted intensity around 18 (Fig. 3.4). The peaks showed
reections at crystal planes of (011), (002), and (400). Widening at the 16.31° refer
to non-cellulose materials such as hemicellulose and lignin in the bers. The major
intensity at an angle 2h= 22.5° has the same angle relative to the structure of
cellulose Ib(2h= 22.3°). Thus, the structure of the cellulose bers is cellulose Ib
mendong in which the unit Ibcellulose structure is monoclinic (Bismarck et al.
2005). Both crystallinity and crystalline index of the mendong ber were 70.7 and
58.6 %, respectively (Table 3.4), and the cellulose bers extracted from the
Table 3.3 Physical properties of mendong ber as compared to other natural bers
Fiber Density
(g/cm
3
)
Diameter
(lm)
Fiber aspect
ratio (average)
Reference
Mendong 0.892 33.8 ±5.6 101 Suryanto et al. (2014b)
Cotton 1.51.6 1238 1919 Gassan and Bledzki (1999) and Rouison
et al. (2004)
Flax 1.5 40600 1000 Gassan and Bledzki (1999), Foulk et al.
(2011) and Rouison et al. (2004)
Rice
straw
1.36 416 74 Reddy and Yang (2006), Abe and Yano
(2009) and Rowell et al. (2000)
Jute 1.3 26.0 100 Gassan and Bledzki (1999), Park et al.
(2006) and Rowell et al. (2000)
Sea grass 11.5 5 Davies et al. (2007)
42 H. Suryanto et al.
mendong have crystallinity and crystalline index for 85.8 and 83.5 %, respectively.
It indicates that the ber mendong contains non-crystalline materials such as
hemicellulose, lignin, and pectin which should be cleaned to make the bers strong.
3.3.3 Mechanical Properties
The mechanical properties of natural bers were affected by the ber structure,
chemical composition, and numbers of defects in a ber. Mendong straw has
enough strength homogeneous up to a length of 60 cm from the base of the stem
with a coefcient of variation of <15 %. After 60 cm, the strength of the straw has a
variation that is too high (>20 %), as shown in Table 3.5.
Fig. 3.4 Diffractogram of both ber and cellulose of mendong
Table 3.4 Structure of mendong ber as compared to other natural bers
Fiber Crystallinity
(%)
Crystalline
index (%)
Crystalline
size (nm)
Microbril
angle (deg)
References
Mendong 70.7 58.6 14.3 22.2 Suryanto et al. (2014a)
Cotton 78.7 68 57Ioelovich and Leykin (2008)
Flax 77 70 5.4 510 Kaith and Kalia (2008) and
Bismarck et al. (2005)
Rice straw 62.8 57 3.75 19.4 Reddy and Yang (2006)
Jute 68.89 65.8 29.25 16.9 Wang et al. (2009),
Mwaikambo (2009) and
Sinha and Rout (2009)
3 Natural Cellulose Fiber from Mendong Grass (Fimbristylis globulosa)43
The mendong ber had tensile strength, elastic modulus, and the specic
strength of 452 MPa, 17.4 GPa, and 507 kN m/kg, respectively (Table 3.5). The
mendong ber has a relatively high tensile strength, and ber mendong has a lower
density so that the specic strength of the mendong ber is over cotton, rice straw,
and sea grass ber, but lower than jute and ax ber (Table 3.6).
3.3.4 Thermal Properties
Thermal properties of the mendong ber were observed by thermogravimetric test.
The heat resistance of the ber can be seen from the decomposition process.
Curvesloss of mass and the mass loss were obtained using a sample of approxi-
mately 20 mg of sample (powdered mendong ber), with an inert gas (Argon), the
Table 3.5 Strength distribution along mendong straw from base to top
Distance from the base (cm) Load at break (N) Coefcient of variation (%)
010 74.0 9.6
1020 98.7 8.6
2030 100.1 1.6
3040 94.8 13.7
4050 89.1 8.0
5060 87.3 10.2
6070 78.9 20.4
7080 71.2 32.1
8090 59.1 22.9
90100 52.8 20.9
Table 3.6 Mechanical properties of mendong ber as compared to other natural bers
Fiber Tensile
strength
(MPa)
E-modulus
(GPa)
Specic
strength
(kN m/kg)
References
Mendong 452 ±47 17.4 ±3.9 507 Suryanto et al. (2014a,b)
Cotton 287597 5.512.6 179398 Gassan and Bledzki (1999) and
Rouison et al. (2004)
Flax 3451035 27.6 230690 Gassan and Bledzki (1999), Foulk
et al. (2011) and Rouison et al. (2004)
Rice
straw
450 26 331 Reddy and Yang (2006), Abe and
Yano (2009) and Rowell et al. (2000)
Jute 1316 91.9 1012 Gassan and Bledzki (1999), Park
et al. (2006) and Rowell et al. (2000)
Sea grass 573 ±120 1 458 Davies et al. (2007)
44 H. Suryanto et al.
heating rate of 10 °C/min. The mendong ber decomposition test results are shown
in Fig. 3.5.
Based on Fig. 3.5, it is observed that the decomposition of the samples is a
exothermic process of chemical reaction that releases a signicant amount of heat
and shows the break down of organic material (Sonibare et al. 2005). The
decomposition by thermal degradation of the whole sample shows four main stages
associated with degradation of the mendong ber. The rst step is the initial
devolatilization, characterized by the rst basin in the reduction rate curve. This
stage is related to the release of water content, and volatile compounds are very
light (Chen et al. 2011). Devolatilization at the mendong ber occurs at tempera-
tures up to 164 °C. The second step is a transition period, which is indicated by the
rate of mass loss. This is relatively stable and shows the decrease in release of
volatile compounds and start of degradation of the ber. This stage occurs until the
temperature reaches 250 °C. In third step, the ber decomposes rapidly, and the
decomposition of complete biomass occurs at 321 °C temperature, which further
decomposes until temperature reaches exact 350 °C. The fourth step is the slow
combustion reaction. Residual mass shows a very slow decomposition which is
characterized by low mass loss and the amount of mass that is relatively stable up to
700 °C temperature.
From Fig. 5, it is observed that the ber mendong is less resistance to heat
degradation as the mass is lost at a constant rate until the temperature reaches 250 °C.
When it is compared to other bers, this temperature is lower than bagasse (273 °C)
Fig. 3.5 Decomposition curve of the mendong ber in an inert atmosphere (Argon) with a heating
rate of 10 °C/min
3 Natural Cellulose Fiber from Mendong Grass (Fimbristylis globulosa)45
(Han et al. 2010), napier grass ber (280 °C) (Reddy et al. 2009) and higher than
maize ber (211 °C) (Bavan and Kumar 2012).
3.4 Mendong Grass Utilization
3.4.1 Mendong Grass as Phytoremediation Plant
Metal hyper-accumulator plants can accumulate and tolerate greater metal con-
centrations in shoots than those usually found in non-accumulators, without visible
symptoms. Over 400 of hyper-accumulator plants have been reported and include
members of the families Asteraceae, Brassicaceae, Caryophyllaceae, Cyperaceae,
Flacourtiaceae, Cunoniaceae, Fabaceae, Lamiaceae, Poaceae, Violaceae, and
Euphorbiaceae (Gratão et al. 2005).
Several cultivated plant species (maize, rice, and sugar beet) have been estab-
lished to use as metal phytoremediation (Poniedzialek et al. 2010). Plants of several
grass families are also used for phytoremediation (Żurek et al. 2013). Vetiver grass
(Vetiveria zizanioides) can absorb and promote biodegradation of organic wastes
(2,4,6-trinitroluene, phenol, ethidium bromide, benzo[a]pyrene, atrazine, and heavy
metals (Danh et al. 2009; Chen et al. 2004). Cyperaceae plants are capable of
improving soil and water contaminated by heavy metals and toxic materials. Some
species of Fimbristylis were applied as phytoremediation plants, which are
Fimbristylis globulosa (Kurnia et al. 2004;Saad et al. 2011), Fimbristylis cymosa
(Paquin et al. 2006), Fimbristylis dichotoma (Muhammad et al. 2013), Fimbistylis
miliacea L. (Akutam et al. 2014), and Fimbristylis littoralis (Nwaichi et al. 2015).
3.4.2 Mendong Straw as Craft Material
Mendong straw is used for several craft items such as woven handicrafts and wicker
crafting mats, hats, ropes, bags, wallets, fancy paper, and others. A good mendong
straw has good length and exibility. Once harvested, the mendong straw is dried in
the sun, for 46 h in dry season or for several days in rainy season. Drying twice
produces good quality mendong straw. The rst drying is performed immediately
after the harvest, while the second drying is conducted after the rst drying and
soaking in water overnight. After coloring, mendong is used to make into various
forms of handicrafts as shown in Fig. 3.6.
46 H. Suryanto et al.
3.4.3 Mendong Fiber as Reinforcement in the Polymer
Composite
The natural ber has several advantages if applied in polymer composites because
they are low price, low density, can be easily separated, abundantly available,
renewable, biodegradable, and have no health hazard (Li et al. 2007; Mu et al.
2009). Fiber from crop plants such as ramie, jute, and hemp have already been
established as reinforce ber for the composite. Some of these bers from crop have
Fig. 3.6 Craft product from mendong straw: arope, bmat, cbag, and dtting basket
3 Natural Cellulose Fiber from Mendong Grass (Fimbristylis globulosa)47
applied as reinforcement in the polymer composite such as rice straw (Reddy and
Yang 2006), wheat straw (Reddy and Yang 2007a), Indian grass (Liu et al. 2004),
switch grass (Reddy and Yang 2007b), and napier grass (Reddy et al. 2009).
High specic strength is the characteristic of the mendong ber which is worthy
to explore as reinforcement material in the polymer composite. The high specic
strength is making it suitable for lightweight composites with applications in the
eld of road transport as a complementary component. Before its use for composite
reinforcement, mending ber should be soaked in sodium hydroxide solution with a
concentration of 5 % for 2 h to increase the strength of the ber as well as cleaning
of ber surface. Such treatment increases ber strength to about 10 % (Suryanto
et al. 2014a). As reinforcement composite, the mendong ber has a critical length of
630 lm in matrix epoxy and interface shear strength of 11.1 MPa (Suryanto et al.
2015). This value is lower than hemp ber in polypropylene matrix (Beckermann
and Pickering 2009) and ramie ber in polypropylene matrix (Awal et al. 2011).
This low value of critical ber length indicates the better stress transfer of the
mendong ber as reinforcement in the polymer composite. With the low (0.63 mm)
critical length of ber and the convenience in the extraction process, the processing
to make composite is easier with these bers.
3.4.4 Mendong Fiber as Source of Microcrystalline
Cellulose
Microcrystal cellulose (MCC) is cellulose with ne size. Microcrystal cellulose had
been used in different elds such as both binder and ller in medical tablets, fat
replacer and stabilizer in the food industry, and a composite material in the plastic
industry (Terinte et al. 2011). It was characterized by the size (diameter in
micrometers) of the bers. These bers consist of crystalline cellulose that has a
width of about 5 nm and a length of about 2030 nm (Leppänen et al. 2009).
Usually, MCC is obtained from woody pulp. It means that it is produced from
the trees following deforestation. There is a need for environment-friendly process
with slowdown of the fast global deforestation. The use of plants having short life
cycle, such as mendong grass, needs to be encouraged. The initial research was
conducted with by extracting MCC from cellulose bers of mendong through a
chemical extraction sequence (Fig. 3.7). The results obtained show MCC with a
crystallinity of 83 %. This value is lower by 3 % compared with the commercial
MCC (Suryanto et al. 2013).
48 H. Suryanto et al.
3.5 Conclusion
Mendong grass is the plant with a potential future that has a variety of applications
for the needs of community. This plant has been successfully characterized in the
biological structure, its properties such as physical, mechanical, chemical content,
and thermal degradation in comparison with other natural bers. Because of high
cellulose content and specic strength, mendong ber is an excellent material to be
used in the elds of biocomposites and handicrafts, as well as a source of cellulose
microcrystal. Exploitation of this plant needs to be done so that this plant can be
applied to other elds.
Acknowledgments Gratefulness to the Ministry of Research, Technology and Higher Education,
Indonesia, through the competitive research Grant 2013 and the fundamental research Grant with
Contract No. 9.4.3/UN32.14/LT/2015.
References
Abe K, Yano H (2009) Comparison of the characteristics of cellulose microbril aggregates of
wood, rice straw and potato tuber. Cellulose 16:10171023. doi:10.1007/s10570-009-9334-9
Akil HM, Omar MF, Mazuki AAM et al (2011) Kenaf ber reinforced composites: a review. Mater
Des 32:41074121. doi:10.1016/j.matdes.2011.04.008
Akutam A, Pappoe ANM, Armah FA, Enu-Kwesi L (2014) Phytoremediation potential of
indigenous Ghanaian grass and grass-like species grown on used motor oil contaminated soils.
J Ecol Environ 37:4151. doi:10.5141/ecoenv.2014.006
Awal A, Cescutti G, Ghosh SB, Müssig J (2011) Interfacial studies of natural bre/polypropylene
composites using single bre fragmentation test (SFFT). Compos Part A 42:5056. doi:10.
1016/j.compositesa.2010.10.007
Bavan S, Kumar M (2012) Morphological and thermal properties of maize ber composites. Fibers
Polym 13:887893. doi:10.1007/s12221-012-0887-0
Fig. 3.7 Extraction of MCC from mendong ber
3 Natural Cellulose Fiber from Mendong Grass (Fimbristylis globulosa)49
Beckermann GW, Pickering KL (2008) Engineering and evaluation of hemp bre reinforced
polypropylene composites: bre treatment and matrix modication. Compos Part A Appl Sci
Manuf 39:979988. doi:10.1016/j.compositesa.2008.03.010
Beckermann GW, Pickering KL (2009) Engineering and evaluation of hemp bre reinforced
polypropylene composites: micro-mechanics and strength prediction modelling. Compos
Part A 40:210217. doi:10.1016/j.compositesa.2008.11.005
Bergander A, Salmen L (2002) Cell wall properties and their effects on the mechanical properties
of bers. J Mater Sci 37:151156. doi:10.1023/A:1013115925679
Bismarck A, Mishra S, Lampke T (2005) Plant bers as reinforcement for green composites. In:
Mohanty AK, Misra M, Drzal LT (eds) Natural bers, biopolymer, and biocomposites. CRC
Press Tailor and Francis Group, Boca Raton
Chen Y, Shen Z, Li X (2004) The use of vetiver grass (Vetiveria zizanioides) in the
phytoremediation of soils contaminated with heavy metals. Appl Geochem 19:15531565.
doi:10.1016/j.apgeochem.2004.02.003
Chen C, Ma X, Liu K (2011) Thermogravimetric analysis of microalgae combustion under
different oxygen supply concentrations. Appl Energy 88:31893196. doi:10.1016/j.apenergy.
2011.03.003
Cheng G, Varanasi P, Li C et al (2011) Transition of cellulose crystalline structure and surface
morphology of biomass as a function of ionic liquid pretreatment and its relation to enzymatic
hydrolysis. Biomacromolecules 12:933941. doi:10.1021/bm101240z
Cousins WJ (1976) Elastic modulus of lignin as related to moisture content. Wood Sci Technol
10:917. doi:10.1007/BF00376380
Danh LT, Truong P, Mammucari R et al (2009) Vetiver grass, Vetiveria zizanioides: a choice plant
for phytoremediation of heavy metals and organic wastes. Int J Phytoremediat 11:664691.
doi:10.1080/15226510902787302
Davies P, Morvan C, Sire O, Baley C (2007) Structure and properties of bres from sea-grass
(Zostera marina). J Mater Sci 42:48504857. doi:10.1007/s10853-006-0546-1
De Jong E, Higson A, Walsh P, Wellisch M (2012) Product developments in the bio-based
chemicals arena. Biofuels Bioprod Bioren 6:606624. doi:10.1002/bbb.1360
Foulk J, Akin D, Dodd R, Ulven C (2011) Production of ax ber for biocomposite. In: Kalia S,
Kaith BS, Kaur I (eds) Cellulose bers: bio- and nanopolymer composites. Springer, Berlin
Gassan J, Bledzki AK (1999) Possibilities for improving the mechanical properties of jute/epoxy
composites by alkali treatment of bres. Compos Sci Technol 59:13031309. doi:10.1016/
S0266-3538(98)00169-9
Gratão PL, Prasad MNV, Cardoso PF et al (2005) Phytoremediation: green technology for the
clean up of toxic metals in the environment. Braz J Plant Physiol 17:5364. doi:10.1590/
S1677-04202005000100005
Han W, Chen K, Yang R-D et al (2010) Utilization of bagasse ber for preparation of
biodegradable ame retarding composites (BFRCS). BioResources 5:16051617. doi:10.
15376/biores.5.3.1605-1617
Ioelovich M, Leykin A (2008) Structural investigations of various cotton bers and cotton
celluloses. BioResources 3:170177. doi:10.15376/biores.3.1.170-177
Jayaraman K (2003) Manufacturing sisalpolypropylene composites with minimum bre
degradation. Compos Sci Technol 63:367374. doi:10.1016/S0266-3538(02)00217-8
Kaith BS, Kalia S (2008) Graft copolymerization of MMA onto ax under different reaction
conditions: a comparative study. Express Polym Lett 2:93100. doi:10.3144/expresspolymlett.
2008.13
Kurnia U, Suganda H, Saraswati R (2004) Pollution control technology in paddy elds. In:
Fahmudin A (ed) Paddy elds and Processing Technology (in Indonesian Language). Center of
Research and Development for Agroclimate Land, Bogor Indonesia, pp 249283
Leppänen K, Andersson S, Torkkeli M et al (2009) Structure of cellulose and microcrystalline
cellulose from various wood species, cotton and ax studied by X-ray scattering. Cellulose
16:9991015. doi:10.1007/s10570-009-9298-9
50 H. Suryanto et al.
Li X, Tabil LG, Panigrahi S (2007) Chemical treatments of natural ber for use in natural
ber-reinforced composites: a review. J Polym Environ 15:2533. doi:10.1007/s10924-006-
0042-3
Li Y, Mai Y, Ye L (2000) Sisal bre and its composites: a review of recent developments. Compos
Sci Technol 60:20372055. doi:10.1016/S0266-3538(00)00101-9
Liu W, Mohanty AK, Askeland P et al (2004) Inuence of ber surface treatment on properties of
Indian grass ber reinforced soy protein based biocomposites. Polymer (Guildf) 45:7589
7596. doi:10.1016/j.polymer.2004.09.009
Marsyahyo E, Soekrisno S, Rohardjo HSB, Jamasri J (2008) Identication of ramie single ber
surface topography inuenced by solvent-based treatment. J Ind Text 38:127137. doi:10.
1177/1528083707087835
Mishra S, Mohanty AK, Drzal LT et al (2004) A review on pineapple leaf bers, sisal bers and
their biocomposites. Macromol Mater Eng. doi:10.1002/mame.200400132
Mohanty AK, Misra M, Drzal LT, Selke SE, Harte BR, Hinrichsen G (2005) Natural bers,
biopolymers, and biocomposites: an introduction. In: Mohanty AK, Misra M, Drzal LT
(eds) Natural bers, biopolymers, and biocomposites. CRC Press: Boca Raton, pp 136
Mu Q, Wei C, Feng S (2009) Studies on mechanical properties of sisal ber/phenol formaldehyde
resin in-situ composites. Polym Compos 30:131137. doi:10.1002/pc.20529
Muhammad S, Shah MT, Khan S et al (2013) Wild plant assessment for heavy metal
phytoremediation potential along the mac and ultramac terrain in northern Pakistan. Biomed
Res Int 2013:110. doi:10.1155/2013/194765
Mwaikambo LY (2009) Tensile properties of alkalised jute bres. BioResources 4:566588.
doi:10.15376/biores.4.2.566-588
Mwaikambo LY, Ansell MP (2006) Mechanical properties of alkali treated plant bres and their
potential as reinforcement materials. I. Hemp bres. J Mater Sci. doi:10.1007/s10853-006-
5098-x
Nwaichi EO, Frac M, Nwoha PA, Eragbor P (2015) Enhanced phytoremediation of crude
oil-polluted soil by four plant species: effect of inorganic and organic bioaugumentation. Int J
Phytoremediat. doi:10.1080/15226514.2015.1058324
Paquin DG, Sun WH, Tang C-S, Li QX (2006) A phytoremediation study: selection of tropical and
other vascular plants for decolorization of Poly R-478 dye. Remediat J 16:97107. doi:10.
1002/rem.20104
Park J, Tran S, Hwang B, Devries KL (2006) Interfacial evaluation of modied Jute and Hemp
bers/polypropylene (PP)-maleic anhydride polypropylene copolymers (PP-MAPP) compos-
ites using micromechanical technique and nondestructive acoustic emission. Compos Sci
Technol 66:26862699. doi:10.1016/j.compscitech.2006.03.014
Poniedzialek M, Sekara A, Jedrszczyk E, Ciura J (2010) Phytoremediation efciency of crop
plants in removing cadmium, lead and zinc from soil. Folia Hortic 22:2531. doi:10.2478/
fhort-2013-0155
Reddy N, Yang Y (2005) Biobers from agricultural byproducts for industrial applications. Trends
Biotechnol 23:2227. doi:10.1016/j.tibtech.2004.11.002
Reddy N, Yang Y (2006) Properties of high-quality long natural cellulose bers from rice straw.
J Agric Food Chem 54:80778081. doi:10.1021/jf0617723
Reddy N, Yang Y (2007a) Preparation and characterization of long natural cellulose bers from
wheat straw. J Agric Food Chem. doi:10.1021/jf071470g
Reddy N, Yang Y (2007b) Natural cellulose bers from switchgrass with tensile properties similar
to cotton and linen. Biotechnol Bioeng 97:10211027. doi:10.1002/bit.21330
Reddy K, Maheswari CU, Reddy DJP, Rajulu AV (2009) Thermal properties of Napier grass
bers. Mater Lett 63:23902392. doi:10.1016/j.matlet.2009.08.035
Rouison D, Sain M, Couturier M (2004) Resin transfer molding of natural ber reinforced
composites: cure simulation. Compos Sci Technol 64:629644. doi:10.1016/j.compscitech.
2003.06.001
3 Natural Cellulose Fiber from Mendong Grass (Fimbristylis globulosa)51
Rowell RM, Han JS, Rowell JS (2000) Characterization and factors effecting ber properties. In:
Frollini E, Leao A, Mattoso LHC (eds) Natural polymer and agrobre based composites.
Embrapa Instrumentação Agropecuária, Sao Carlos, pp 115134
Saad NS, Artanti R, Dewi T (2011) Phyto-remediation for rehabilitation of agricultural land
contaminated by cadmium and copper. Indones J Agric 4:1721
Sinha E, Rout SK (2009) Inuence of bre-surface treatment on structural, thermal and mechanical
properties of jute bre and its composite. Bull Mater Sci 32:6576. doi:10.1007/s12034-009-
0010-3
Sonibare OO, Ehinola OA, Egashira R, KeanGiap L (2005) An investigation into the thermal
decomposition of Nigerian Coal. J Appl Sci 5:104107. doi:10.3923/jas.2005.104.107
Summerscales J, Dissanayake N, Virk AS, Hall W (2010) A review of bast bres and their
composites. Part 1bres as reinforcements. Compos Part A Appl Sci Manuf 41:13291335.
doi:10.1016/j.compositesa.2010.06.001
Suryanto H, Zakia N, Marsyahyo E (2013) The exploration of cellulose nanocrystal from
Mendong Fibers using Pulsed Electric Field (PEF), and the utilization for biopackaging
applications (in Indonesian language). Research report, Universitas Negeri Malang
Suryanto H, Irawan YS, Marsyahyo E, Soenoko R (2014a) Effect of alkali treatment on crystalline
structure of cellulose ber from mendong (Fimbristylis globulosa) straw. Key Eng Mater 594
595:720724. doi:10.4028/www.scientic.net/KEM.594-595.720
Suryanto H, Marsyahyo E, Irawan YS, Soenoko R (2014b) Morphology, structure, and mechanical
properties of natural cellulose ber from mendong grass (Fimbristylis globulosa). J Nat Fibers
11:333351. doi:10.1080/15440478.2013.879087
Suryanto H, Marsyahyo E, Irawan YS et al (2015) Improvement of interfacial shear strength of
mendong ber (Fimbristylis globulosa) reinforced epoxy composite using the AC electric
elds. Int J Poly Sci 2015, Article ID 542376, 10 pages. http://dx.doi.org/10.1155/2015/
542376
Terinte N, Ibbett R, Schuster KC (2011) Overview on native cellulose and microcrystalline
cellulose I structure studied by X-ray diffraction (WAXD): comparison between measurement
techniques. Lenzing Ber 89:118131
USDA (2015) Plant Prole. http://plants.usda.gov/java/prole?symbol=FIGL#. Accessed 11 Jan
2015
Venkateshwaran N, Elayaperumal A (2010) Banana ber reinforced polymer compositesa
review. J Reinf Plast Compos 29:23872396. doi:10.1177/0731684409360578
Wang W, Cai Z, Yu J, Xia Z (2009) Changes in composition, structure, and properties of jute
bers after chemical treatments. Fibers Polym 10:776780. doi:10.1007/s12221-009-0776-3
Yi C, Tian L, Tang F et al (2010) Crystalline transition behavior of sisal in cycle process. Polym
Compos 31:933938. doi:10.1002/pc.20885
Żurek G, Pogrzeba M, Rybka K, Prokopiuk K (2013) Suitability of grass species for
phytoremediation of soils polluted with heavy-metals. In: Barth S, Milbourne D
(eds) Breeding strategies for sustainable forage and turf grass improvement. Springer,
Dordrecht
52 H. Suryanto et al.
... Mendong Biogeotextile can absorb water and increase the weight in wet conditions because of their fiber's component dominated by cellulose. According to Suryanto et al. (2016) [10], Mendong straw has cellulose content up to 72% of the total weight. According to ANOVA, there were significantly different among the increasing weight of bio-geotextile in wet condition depending on the different treatment of layers. ...
... Cellulose is hygroscopic, meaning it can absorb water molecules, and many of its chains contain a hydroxyl group (OH) that can form a hydrogen bond with water. Fiber can bind water in a variety of ways, including hydrogen bonds [12]. Hydrogen bonds are formed when hydrogen (H) is bound to an element with high electronegativities, such as carbon (C), oxygen (O), or fluorine (F). ...
... Mendong is a type of grass, a family of Cyperaceans with short rhizomes, fibrous roots, and grooved. This plant is used to make traditional mats such as ropes, bags, hats and wallets because of its high fiber and its low cost [17]. Estimated production of Mendong in Java is about 14.000 tons per years [18]. ...
... Mendong fibers have a higher crystallinity and crystalline size than straw fibers and wheat stalks [18]. Until now, Mendong also used as phytoremediation plant, microcrystalline cellulose, and polymer composite [17]. Thus, Mendong is considered to have potential as charcoal as it has relatively high content of cellulose. ...
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This study aims to find alternative low-cost, easy and environmental-friendly adsorbent materials to eliminate SO2 gas, by utilizing Mendong plants as activated charcoal. Therefore, need to know the ability of this low-cost adsorbent in term of optimum concentration, adsorption efficiency, and the adsorption capacity of the charcoal to eliminate SO2. Mendong plants were prepared with a modified tool and macerated with ZnCl2 2.5% (w/v) for 24 hours. Then, the adsorption process with artificial SO2 waste was conducted for 1 hour. UV-Vis Spectrophotometer was used to determine the gas concentration. The results showed that the highest concentration of absorbed SO2 gas (Ct) is at the initial gas concentration 4.4006 µg/mL (mass Na2S2O3 0.015 g), with 3.008 µg/mL of gas is absorbed. The gas adsorption efficiency is 70.53% at the variation of initial gas concentration of 4.1400 µg/mL. While, the adsorption capacity of activated ZnCl2- Mendong stem charcoal is 92.1123 (µg/g). The results of the characterization by FTIR showed that the Mendong plant ZnCl2- activated charcoal is polar and aromatic, verified by the absorbance of hydroxyl group and aromatic skleleton of cellulose, hemicellulose and lignin.
... Struktur kimia lignin sampai saat ini belum secara tepat dipastikan tetapi hampir semua gugus fungsional dan unit bangun molekul belum teridentifikasi. Lignin memiliki kekuatan mekanis 100 kali dibandingkan penurunan massa tersebut yang diperoleh dari pengujian termogravimetri dengan jumlah sampel sekitar 20 mg sampel serbuk serat mendong, dengan gas inert (Argon), pada laju pemanasan 10 o C/menit.Gambar 3Grafik dekomposisi dari serat mendong pada kondisi inert (Argon) dengan laju pemanasan 10 o C/menit[19] Berdasarkan Gambar 3, dapat diamati bahwa dekomposisi sampel adalah proses reaksi kimia yang hebat yang melepaskan banyak kalor dan menunjukkan terjadinya pemecahan secara termal bahan organik sampel[20]. Dari kurva dekomposisi akibat degradasi termal dari keseluruhan sampel, ada 4 tahapan utama berkaitkan dengan degradasi akibat reaksi dekomposisi serat mendong.Tahap 1 adalah devolatilisasi awal, ditandai dengan adanya cekungan pertama di kurva laju pengurangan. ...
... Kekuatan spesifik dari serat mendong lebih tinggi dari serat jerami padi, serat jerami gandum, sisal, sabut kelapa, tebu, rumput laut, tetapi lebih rendah dari serat rumput alfa, serat sanseviera dan rami (Tabel 4).Serat adalah substrat lignoselulosa yang memiliki struktur heterogen dan menunjukkan pola spektral dengan penyerapan relatif tajam pada bilangan gelombang gelombang tertentu yang menunjukkan keberadaan suatu gugus kimia. Gugus fungsional serat mendong yang mampu terdeteksi pada uji FTIR antara lain ditunjukkan pada Gambar 6 dan Tabel 5.Gambar 6 Diagram hasil analisis dengan spektroskopi FTIR pada serat mendong[19] Tabel 5 Gugus fungsi pada serat yang terdeteksi melalui uji spektroskopi FTIR Bilangan gelombang (cm -1 ) ...
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... Mendong (Fimbristylis globulosa) is a type of grass that grows in wetland areas and usually grows up to more than 100 cm in the length. Traditionally, the mendong straws have been used for rope, mats, and other product like baskets, furniture, and handbags [5]. The mendong grass has the potency as fiber sources because of the production of mendong estimated 14,000 tons every year in Java, Indonesia [6]. ...
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the disposal of synthetic fiber is very difficult to be degraded and cause problems in the environment. The renewable materials have potency as an alternative material for replacing the synthetic material in the composite product. This study was to determine the critical fiber length of mendong fiber embedded in the epoxy composite. The methods were the extraction of mendong fiber from straw, pull out test methods, and morphology analysis of pull out test using scanning electron microscope. Results show that mendong fiber had shear strength of 11 MPa and indicate a critical fiber length of 630 µm. The low critical fiber length of mendong embedded in epoxy matrix indicate a good adhesion properties of mendong in epoxy matrix. It recommends that mendong fibers can apply as reinforcement in the epoxy composite in the form of short fiber.
... Bahan yang berasal dari tanaman telah digunakan secara tradisional untuk makanan dan pakan. Produk polimer berbasis bahan hijau seperti tanaman pertanian merupakan dasar untuk membentuk produk yang eco-efisien dan berkelanjutan, dan bersaing dengan bahan-bahan sintesis (Suryanto et al., 2016). Serat alami telah menunjukkan keunggulan dalam beberapa tahun terakhir. ...
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Musa acuminata stem is an agricultural waste that has good economic potential. For this reason, efforts are needed to increase the saba banana tree not only as waste, but also to increase its function into natural fiber raw materials for polyester matrix composite reinforcement. The purpose of this study was to determine the characteristics of Musa acuminata stem fibre (MASF) from North Lombok Regency, Indonesia Country as a reinforcement for polyester matrix composites. In this study, the fiber (specimen), taken from pseudo stem Musa acuminata, which consists of three layers: outer, middle and inner stem. The ratting process is done mechanically using a fiber extraction machine. To remove impurities in the fiber, alkaline treatment was carried out, by soaking for 24 hours in a 5 % NaOH solution. To determine the characteristics, a scanning electron microscopy (SEM) test was carried out for MASF morphology analysis, chemical compound content testing, heat resistance testing, and fiber tensile strength testing. The results showed that the MASF of the outer layer pseudo-stem has a strong character. Fiber morphology is different, between the outer, middle and inner layers pseudo-stems. The cellulose content (73.12 %) was higher than the fiber of Fimbristylis globulosa, hemp, jute, rice straw, wheat straw, seaweed, sorghum straw, coir, and alpha grass. Less resistant to heat degradation because mass loss occurs at a constant rate up to 245 °C. The highest MASF, in the outer pseudo-stem layer it is 40–50 cm from the base stem. Its characteristics are better than other natural fibers so that its potential can be further developed as a reinforcement for polymer matrix composites
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With ever increasing environmental awareness, renewable raw materials for textile and composite industry have become an important alternative to reduce the use of petroleum-based non-biodegradable fibers in various applications such as marine, automotive, sports and aerospace. Therefore, it is highly critical to understand the chemistry, structure, and properties of novel plant fibers. Natural fibers have been used for various purposes since ancient times. Numerous research and review papers were published on harvesting, production, properties and potential applications of conventional natural fibers. Sustainability, renewability, and recyclability issues increased the use of novel natural fibers globally. New applications such as natural fiber reinforced biodegradable composites also increased the importance of investigations on new natural fibers. This review paper considers extraction methods, fiber structure, chemical, physical and mechanical properties of novel cellulosic fibers. Fiber chemical constituents, functional groups, and surface hydrophilicity were discussed in terms of chemical properties. Physical properties of the cellulosic fibers such as density, crystallinity, maximum thermal degradation, mechanical performance and surface morphology were also discussed. Additionally, mechanical performance of new plant fibers was performed by comparing between some properties of common and recently characterized cellulosic fibers. The brief information about life-cycle assessment, sustainability, recycling, and biocomposite application of the novel plant fibers is also presented. According to the best our knowledge on literature review, this review may be unique to provide detailed information about recently characterized cellulosic fibers. This survey will be helpful to researchers who have interest in novel ligno-cellulosic fibers and fiber reinforced composites.
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