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Chemical Rocket Propulsion - A Comprehensive Survey of Energetic Materials

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Abstract

This book deals with energetic materials and their application to chemical rocket propulsion as initially discussed at the 12th IWCP titled “New Energetic Materials for Space Exploration.” This event was held at Politecnico di Milano (PoliMi), Campus Bovisa, Milan, Italy, 9–10 June 2014 and was attended by about 200 participants from 20 countries. In total, 37 technical papers were offered, including 28 oral presentations and 9 poster papers. The Workshop was a unique gathering and opportunity, where participants could freely discuss the future of chemical rocket propulsion for access to, and exploration of, space. Distinguished scientists and propulsion engineers from academia, government, and industry were invited to attend.
Springer Aerospace Technology
LuigiDeLuca
ToruShimada
ValeryP.Sinditskii
MaxCalabro Editors
Chemical
Rocket
Propulsion
A Comprehensive Survey of Energetic
Materials
Springer Aerospace Technology
luigi.deluca@polimi.it
More information about this series at http://www.springer.com/series/8613
luigi.deluca@polimi.it
Luigi T. DeLuca Toru Shimada
Valery P. Sinditskii Max Calabro
Editors
Chemical Rocket Propulsion
A Comprehensive Survey of Energetic
Materials
123
luigi.deluca@polimi.it
Editors
Luigi T. DeLuca
Space Propulsion Laboratory (SPLab)
Department of Aerospace Science
and Technology
Politecnico di Milano
Milan, Italy
Valery P. Sinditskii
Department of Chemical Engineering
Mendeleev University
of Chemical Technology
Moscow, Russia
Tor u Shimada
Institute of Space and Astronautical
Science (ISAS)
Japan Aerospace Exploration
Agency (JAXA)
Sagamihara, Japan
Max Calabro
The Inner Arch
Poissy, France
ISSN 1869-1730 ISSN 1869-1749 (electronic)
Springer Aerospace Technology
ISBN 978-3-319-27746-2 ISBN 978-3-319-27748-6 (eBook)
DOI 10.1007/978-3-319-27748-6
Library of Congress Control Number: 2016941937
© Springer International Publishing Switzerland 2017
This work is subject to copyright. All rights are reserved by the Publisher, whether the whole or part of
the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation,
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The publisher, the authors and the editors are safe to assume that the advice and information in this book
are believed to be true and accurate at the date of publication. Neither the publisher nor the authors or
the editors give a warranty, express or implied, with respect to the material contained herein or for any
errors or omissions that may have been made.
Printed on acid-free paper
This Springer imprint is published by Springer Nature
The registered company is Springer International Publishing AG Switzerland
luigi.deluca@polimi.it
Preface
This book deals with energetic materials and their application to chemical rocket
propulsion as initially discussed at the 12th IWCP titled “New Energetic Materials
for Space Exploration.” This event was held at Politecnico di Milano (PoliMi),
Campus Bovisa, Milan, Italy, 9–10 June 2014 and was attended by about 200
participants from 20 countries. In total, 37 technical papers were offered, including
28 oral presentations and 9 poster papers. The Workshop was a unique gathering
and opportunity, where participants could freely discuss the future of chemical
rocket propulsion for access to, and exploration of, space. Distinguished scientists
and propulsion engineers from academia, government, and industry were invited to
attend. The official Group Photo of the Milan Workshop is shown as Fig. 1.
This book includes selected technical papers of high-quality presented at the
Workshop, with several additional papers invited from the relevant international
scientific community. All papers were accepted for publication only after passing
a careful and severe peer review process by two to five anonymous international
experts, according to the same comprehensive procedures employed by the most
qualified archival publications. Every printed paper has a DOI reference. Therefore,
this volume should not be considered an unfiltered collection of conference
proceedings but rather an advanced supplemental reading for graduate students,
lecturers, researchers, and scientists in academia or research centers, engineers, and
industrialists.
The International Workshop on Combustion and Propulsion (IWCP) series was
started in 1990 by the Space Propulsion Laboratory (SPLab) of Politecnico di
Milano as an attempt to bridge the gap between researchers of the Eastern and
Western blocs, which were until that time rigidly separated, in the broad areas of
combustion applications for propulsion and rocket propulsion. Conveniently located
between the two big countries, Italy has kept communication channels open between
American and Russian scientists, even during the hard times of global competition.
The IWCP series intends to promote free technical discussion and knowledge
exchange in a relaxed atmosphere. The meeting format was built in order to favor
detailed discussions among leading international researchers on selected areas of
interest, rather than formal presentations of final results by registered authors on
v
luigi.deluca@polimi.it
vi Preface
a wide range of topics. Plenary Lectures by outstanding speakers are meant to
offer a critical survey of specific themes and pave the way to detailed contributions
from the authors as well as general discussions within the audience. For quality
assurance, participation of lecturers/speakers/observers is normally restricted to
a small number of invited people internationally selected for their demonstrated
technical competence but also innovative vision or provocative approach. Serious
efforts are made to ensure that the results are readily and easily available to a wide
range of international readers, and the level of technical accuracy at all stages, from
paper presentations to written diffusion of results, is set at the highest professional
standards.
Although some of these features may have been diluted or adapted during the
years, the basic flavor has been kept. The attendance of worldwide renowned authors
in the meetings and timeliness of topics contained in the IWCP collection of events
prove the effectiveness and success of the series in advancing energetic material
combustion and rocket propulsion understanding.
The 12th IWCP addressed the current status in the field of energetic materials,
from the viewpoint both of formulation and related topics from rocket propulsion
to other applications. The workshop also looked for inspiring perspectives in a
number of areas related to the energetic materials specifically used in chemical
rocket propulsion.
Subsequently, the book will:
Survey the current international status of energetic materials for propulsion
Identify new promising ingredients for novel energetic materials formulation
Provide an insight into powerful new energetic formulations under study at
world-wide advanced laboratories
Provide some rarely accessible information from Russian and Chinese sources
Recommend future directions for a wide range of themes, from chemical
propulsion to applications, resorting to energetic materials
Offer the advantage of a common source for several topics treated in the book
but scattered in the open literature
Discuss little-known propulsion topics such as gel propulsion, catalytic tech-
niques, and nanosized ingredients
The book is meant to offer a comprehensive survey of chemical rocket propulsion
from the energetic materials viewpoint. Thus, the whole “life-cycle” of energetic
materials is covered: from their conceptual formulation to practical manufacturing,
including theoretical and experimental ballistics as well as performance properties,
laboratory-scale and full system-scale, management (handling, storage, ageing,
hazards, impact, disposal, remediation), and so on. Each of the chapters shall focus
on one of main aspects, without however overlooking possible interactions with the
remaining issues. All topics are considered from a broad international viewpoint.
In order to offer readers a comprehensive survey of current technical problems, a
fine selection of accomplished experts from the pioneering era of space propulsion
luigi.deluca@polimi.it
Preface vii
as well as of current technologists from some of the most advanced international
laboratories was put together and agreed to support this editorial initiative.
The whole collection of 45 accepted papers is structured in the following 11
book chapters with a common target of “advancing chemical propulsion systems by
addressing all aspects of propellants” (as expressed by an anonymousreviewer).
The book is opened by a collective introductory chapter that provides a consistent
theme for the volume and shows how distinctly different chapters fit into this
theme and cooperate to reach a common final goal. Such chapter was assembled by
collecting well-focused essays by internationally recognized experts in the covered
area, who briefly introduce each chapter. This introductory chapter will also help
in arousing the interest of potential readers and will hopefully prompt them to look
into individual chapters or papers.
It is our great pleasure to thank the following international reviewers for their
substantial help in raising the quality of the book. Without their efforts, the
publication of this volume would have been impossible:
Shalini Anand,Hiroshi Aoki,Hiroya Asakawa,Valery A. Babuk,M. Balduccini,
Yann Batonneau,L. Boccaletto,Manfred A. Bohn,Ch. Bonhomme,Ch. Bonnal,
Max Calabro,Leonard H. Caveny,S. Mary Celin,N. Cesco,Helmut Ciezki,
Adam S. Cumming,B. DAndrea,E. DAversa,W.P.C. de Klerk,Luigi T. DeLuca,
Y. Fabignon,Go Fujii,Luciano Galfetti,S. Gallier,A. Gany,N.G. Glumac,
T.I. Gor ben ko ,J.F. Guéry,Dietrich Haeseler,Oskar J. Haidn,Stephen D. Heister,
Keiichi Hori,N. Ierardo,Charles Kappenstein,Arif Karabeyo˘glu,Thomas M.
Klapötke,M.J. Klopfstein,A. Korotkikh,Bernard M. Kosowski,C.J. Lee,David
Lempert,Filippo Maggi,Anthony P. Manzara,K. Menke,Harunori Nagata,Ichiro
Nakagawa,Benveniste Natan,A. Neri,J. Neutz,O. Orlandi,Bryan A. Palaszewski,
D. Pavarin,Wei Qiang Pang,P. Pe m p i e ,Alla N. Pivkina,S. Peters,S. Petitot,Sergey
A. Rashkovskiy,Takashi Sakurai,Keisuke Sawada,H. Schöyer,Toru Shimada,Y.J .
Shu,Irina L. Simakova,Valery P. Sinditskii,Haridwar Singh,V.I. Trushlyakov,Ruth
Tunnell,D. Yagodnikov,N. Wingborg,Q.L. Yan,Vladimir E. Zarko,Feng Qi Zhao.
In addition, the technical language of many non-native English authors was
polished by Dr. Adam S. Cumming,Dr. Anthony P. Manzara,Mr. Bryan A.
Palaszewski,andDr. Ruth Tunnell, who deserve special thanks for their patient and
generous assistance in the phase of paper revision. We would also like to thank all
the authors for their paper contribution and collaboration in following the format
specified by Springer International Publishing AG. Finally, special thanks are due
to Ms. Charlotte Cross for her continuous assistance in the many publishing issues
we had to face.
Further high-quality presentations were made at the Workshop by I.G. Assovskiy
(Semenov Institute of Chemical Physics, Russia), P. Bellomi (Avio, Italy), E. Bucci
(Avio, Italy), Helmut Ciezki (DLR, Germany), Charles Kappenstein (University
of Poitiers, France), Bernard M. Kosowski (MACH I, USA), K.K. Kuo (Pennsyl-
vania State University, USA), Z. Mansurov (Institute of Combustion Problems,
Kazakhstan), M. Persson (ECAPS, Sweden), S. Schlechtriem (DLR, Germany),
luigi.deluca@polimi.it
viii Preface
and N. Wingborg (FOI, Sweden). Unfortunately, these contributions could not
be included in the book, but the authors are greatly thanked for their active
participation. In addition to the several chapter authors listed in the Table of
Contents, further short contributions were provided by Dr. Chaoyang Zhang (China
Academy of Engineering Physics, Mianyang, Sichuan, China), Dr. Qinghua Zhang
(China Academy of Engineering Physics, Mianyang, Sichuan, China), and Dr. Hao
Feng (Xi’an Modern Chemistry Research Institute, Xi’an, Shaanxi, China).
This book was started at Politecnico di Milano, Milan, Italy, by one of the editors
(Luigi T. DeLuca), continued after his retirement at Konkuk University, Seoul,
Korea, and finally completed at Nanjing University of Science and Technology,
Nanjing, China. Sincere thanks are due to both Konkuk University and Nanjing
University of Science and Technology for providing an excellent atmosphere and all
needed professional support. This opportunity is taken to thank also Ms. I. Palmucci,
Mr. D. Trache, Dr. Wei Qiang Pang, and Mr. Giovanni Colombo for their valuable
and continuous assistance duringthe entire Workshop organization and conduction.
We sincerely wish that this joint international effort will help all readers to gain
a better understanding of the puzzling intricacies and appealing secrets of energetic
materials as well as of the perplexing difficulties but also fascinating horizons of
space propulsion!
Sic itur ad astra (Virgil, Aeneid Book IX, line 641, 19 BC)
30 September 2015 The Volume Co-Editors
Milan, Italy Luigi T. DeLuca
Sagamihara, Japan Toru Shimada
Moscow, Russia Valery P. Sinditskii
Poissy, France Max Calabro
luigi.deluca@polimi.it
Preface ix
Fig. 1 Group Photo 12th IWCP Workshop, PoliMi, Campus Bovisa, Milan, Italy, 9–10 June 2014
luigi.deluca@polimi.it
xPreface
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12th IWCP Workshop Identity of book contributors (editors, authors, and reviewers) and selected Workshop participants
(41)A. Annovazzi,(47)I.G. Assovskiy,(5)Valery A. Babuk,(62)L. Balasubramanyam,(21)P. Bellomi,(34)Manfred A. Bohn,(46)C. Bombardieri,
(36)E. Bucci,(2)M. Calabro,(58)C. Carmicino,(3)Shri M. Chandradathan,(30)Helmut Ciezki,(42)Giovanni Colombo,(59)Adam S. Cumming,
(57)N. de Backer,(1)Luigi T. DeLuca,(45)A. Di Biase,(29)L. Fanton,(50)Marco Fassina,(51)A. Franzin,(39)G. Fundarò,(43)Luciano Galfetti,
(33)Volker Gettwert,(24)Keiichi Hori,(63)S.R. Jangoan,(60)Charles Kappenstein,(37)Marcos A. Kettner,(27)Koki Kitagawa,(28)M. Kobald,
(15)Bernard M. Kosowski,(11)K.K. Kuo,(12)C.J. Lee,(4)S. Magham,(6)Z. Mansurov,(35)G. Marra,(20)O. Martos,(64)S. Muttangi,(55)F. Na s u t i ,
(49)M. Negri,(14)O. Orlandi,(19)Wei Qiang Pang,(54)D. Pastrone,(40)M. Persson,(17)G. Platova,(16)Yulii Platov,(38)F. Pochetti,(23)Z. Qin,
(44)H. Raina,(
10)Sergey A. Rashkovskiy,(52)JAFF Rocco,(53)L. Rocco Jr., (25)R.Q. Shen,(22)T. Sgobba,(13)Toru Shimada,(7)Irina L. Simakova,
(8)Valery P. Sinditskii,(9)Haridwar Singh,(61)Y. Sundhari,(48)Pietro Tadini,(65)Elena Toson,(26)Alexander B. Vorozhtsov,(31)Volker Weiser,
(32)N. Wingborg,(18)Q.L. Yan,(56)Y.F. Zhao
luigi.deluca@polimi.it
Contents
Part I An Introduction to Energetic Materials for Propulsion
An Introduction to Energetic Materials for Propulsion ................... 3
Luigi T. DeLuca, Toru Shimada, Valery P. Sinditskii, Max Calabro,
and Anthony P. Manzara
Part II New Ingredients for Chemical Propulsion
Synthesis of New Oxidizers for Potential Use in Chemical
Rocket Propulsion.............................................................. 63
Marcos A. Kettner and Thomas M. Klapötke
High-Nitrogen Energetic Materials of 1,2,4,5-Tetrazine
Family: Thermal and Combustion Behaviors ............................... 89
Valery P. Sinditskii, Viacheslav Yu. Egorshev, Gennady F. Rudakov,
Sergey A. Filatov, and Anna V. Burzhava
Survey of New Energetic and Eco-friendly Materials
for Propulsion of Space Vehicles.............................................. 127
Haridwar Singh
Performance Additives for Hybrid Rockets ................................. 139
Arif Karabeyo˘
glu
Introducing Tetrazole Salts as Energetic Ingredients
for Rocket Propulsion ......................................................... 165
Xuezhong Fan, Fuqiang Bi, Min Zhang, Jizhen Li, Weiqiang Pang,
Bozhou Wang, and Zhongxue Ge
Synthesis and Characterization of 3,4-bis
(3-fluorodinitromethylfurazan-4-oxy)furazan .............................. 179
Lianjie Zhai, Bozhou Wang, Xuezhong Fan, Fuqiang Bi,
Peng Lian, Jizhen Li, and Weiqiang Pang
xi
luigi.deluca@polimi.it
xii Contents
Part III Metals as Energetic Fuels for Chemical Propulsion
Prospects of Aluminum Modifications as Energetic Fuels
in Chemical Rocket Propulsion ............................................... 191
Luigi T. DeLuca, Filippo Maggi, Stefano Dossi, Marco Fassina,
Christian Paravan, and Andrea Sossi
Novel Micro- and Nanofuels: Production, Characterization,
and Applications for High-Energy Materials ............................... 235
Alexander B. Vorozhtsov, Alexander S. Zhukov,
Mansur Kh. Ziatdinov, Sergey S. Bondarchuk, Marat I. Lerner,
and Nikolay G. Rodkevich
Combustion Behavior of Aluminum Particles in ADN/GAP
Composite Propellant s ......................................................... 253
Volker Weiser, Andrea Franzin, Luigi T. DeLuca, Sebastian Fischer,
Volker Gettwert, Stefan Kelzenberg, Sebastian Knapp,
Angelika Raab, Evelin Roth, and Norbert Eisenreich
Laser Ignition of Different Aluminum Nanopowders for Solid
Rocket Propulsion.............................................................. 271
Fengqi Zhao, Ergang Yao, Siyu Xu, Huixiang Xu, and Haixia Hao
Experimental Investigation of an Aluminized Gel Fuel Ramjet
Combustor ...................................................................... 297
Gilad Gafni, Alexander Kuznetsov, and Benveniste Natan
Part IV Solid Rocket Propulsion
Formulation Factors and Properties of Condensed Combustion
Products ......................................................................... 319
Valery A . B a buk
Energy and Combustion Characteristics of Propellants Based
on BAMO-GAP Copolymer ................................................... 341
Jiangfeng Pei, Fengqi Zhao, Ying Wang, Siyu Xu, Xiuduo Song,
and Xueli Chen
Synergistic Effect of Ammonium Perchlorate on HMX: From
Thermal Analysis to Combustion ............................................ 365
Alla N. Pivkina, Nikita V. Muravyev, Konstantin A. Monogarov,
Valery G. Ostrovsky, Igor V. Fomenkov, Yury M. Milyokhin, and
Nickolay I. Shishov
Combustion of Solid Propellants with Energetic Binders ................. 383
Sergey A. Rashkovskiy, Yury M. Milyokhin,
and Alexander V. Fedorychev
luigi.deluca@polimi.it
Contents xiii
Effects of Dual Oxidizers on the Properties of Composite Solid
Rocket Propellants ............................................................. 403
Wei Qiang Pang, Luigi T. DeLuca, Hui Xiang Xu, Xue Zhong Fan,
Feng Qi Zhao, and Wu Xi Xie
Part V Liquid and Gel Rocket Propulsion
Russian Engine Technologies ................................................. 427
Dietrich Haeseler and Oskar J. Haidn
The Status of the Research and Development of LNG Rocket
Engines in Japan ............................................................... 463
Hiroya Asakawa, Hideaki Nanri, Kenji Aoki, Isao Kubota,
Hatsuo Mori, Yasuhiro Ishikawa, Kenichi Kimoto, Shinji Ishihara,
and Shinichiro Ishizaki
Research and Development Activities on JAXA’s
Spacecraft Propulsion ......................................................... 489
Go Fujii and Hirohide Ikeda
High Shear Rheometry of Unsymmetrical Dimethylhydrazine Gel ...... 519
Mohan Varma
Part VI Hybrid Rocket Propulsion
Hybrid Propulsion Technology Development in Japan
for Economic Space Launch .................................................. 545
Toru Shimada, Saburo Yuasa, Harunori Nagata, Shigeru Aso,
Ichiro Nakagawa, Keisuke Sawada, Keiichi Hori,
Masahiro Kanazaki, Kazuhisa Chiba, Takashi Sakurai,
Takakazu Morita, Koki Kitagawa, Yutaka Wada, Daisuke Nakata,
Mikiro Motoe, Yuki Funami, Kohei Ozawa, and Tomoaki Usuki
Internal Flow Characteristics and Low-Frequency Instability
in Hybrid Rocket Combustion ................................................ 577
Kyung-Su Park, Yang Na, and Changjin Lee
Performance Analysis of Paraffin Fuels for Hybrid Rocket Engines..... 605
Songqi Hu, Wu Guanjie, and Noor Fatima Rashid
Hybrid Combustion Studies on Regression Rate Enhancement
and Transient Ballistic Response ............................................. 627
Luciano Galfetti, Matteo Boiocchi, Christian Paravan,
Elena Toson, Andrea Sossi, Filippo Maggi, Giovanni Colombo,
and Luigi T. DeLuca
luigi.deluca@polimi.it
xiv Contents
Part VII New Concepts in Chemical Propulsion
In-Space Chemical Propulsion System Roadmap .......................... 655
Bryan A. Palaszewski, Michael L. Meyer, Les Johnson,
Dan M. Goebel, Harold White, and David J. Coote
Mapping of Aluminum Particle Dispersion in Solid Rocket
Fuel Formulations.............................................................. 673
Arezoo Zare, Tres A. Harriman, Don A. Lucca, Silvia Roncalli,
Bernard M. Kosowski, Christian Paravan, and Luigi T. DeLuca
New Concept of Laser-Augmented Chemical Propulsion ................. 689
Ruiqi Shen, Lizhi Wu, Zhao Qin, Xiaoyong Wang, and Nianbai He
Catalytic Aspects in the Synthesis of a Promising Energetic Material ... 697
Irina L. Simakova and Valentin N. Parmon
Part VIII Life-Cycle Management of Energetic Materials
Environmental Aspects of Energetic Materials Use and Disposal ........ 727
Adam S. Cumming
Overview and Appraisal of Analytical Techniques for Aging
of Solid Rocket Propellants ................................................... 743
Ruth Tunnell
Aging Behavior of ADN Solid Rocket Propellants and Their
Glass-Rubber Transition Characteristics ................................... 771
Manfred A. Bohn and Sara Cerri
Lessons Learned in the Thruster Tests of HAN ............................ 801
Keiichi Hori
Physical Mechanisms of Upper Atmosphere Optical
Phenomena Associated with Rocket Engine Operation.................... 819
Yulii V. Platov and Sergey Sh. Nikolayshvili
Green Technologies for the Safe Disposal of Energetic
Materials in the Environment................................................. 835
Shalini Anand and S. Mary Celin
Part IX Space Launchers
Challenges in Manufacturing Large Solid Boosters ........................ 863
Shri M. Chandradathan
Evaluating the Interest of New Propellants for the VEGA
Launch Vehicle ................................................................. 887
Max Calabro
luigi.deluca@polimi.it
Contents xv
Overview of Research and Development Status of Reusable
Rocket Engine .................................................................. 905
Makoto Yoshida, Toshiya Kimura, Tomoyuki Hashimoto,
Shinichi Moriya, and Satoshi Takada
Part X Further Applications of Energetic Materials
Some Civilian Applications of Solid Propellants ............................ 935
Vladica Bozic and Boris Jankovski
Novel Ammonium Nitrate-Based Formulations for Airbag Gas
Generation ...................................................................... 963
Shingo Date
Comparison of Chemical Propulsion Solutions for Large Space
Debris Active Removal ........................................................ 985
Pietro Tadini, Urbano Tancredi, Michele Grassi, Carmen Pardini,
Luciano Anselmo, Toru Shimada, and Luigi T. DeLuca
Part XI History of Solid Rocket Propulsion in Russia
Highlights of Solid Rocket Propulsion History ............................. 1015
Luigi T. DeLuca
Survey of Solid Rocket Propulsion in Russia ............................... 1033
Alexey M. Lipanov and Vladimir E. Zarko
The Contribution of the Semenov Institute of Chemical Physics
to the Science of Combustion: A Historical Review ........................ 1055
Alexander A. Berlin, Yury V. Frolov, and Yury G. Isaevich
The Russian Missile Saga: Personal Notes from a Direct Participant .... 1069
George B. Manelis
luigi.deluca@polimi.it
luigi.deluca@polimi.it
Short Biography
Luigi T. DeLuca
Professor of Aerospace Propulsion
Space Propulsion Laboratory,Politecnico di Milano,Milan,Italy
Timeline
2014: Retired (maximum age) with a 2-year part-time extension, Politecnico di
Milano, Milan, Italy
1989: Full Professor of Aerospace Propulsion, Politecnico di Milano, Milan, Italy
1983: Associate Professor of Aerospace Propulsion, Politecnico di Milano,
Milan, Italy
1976: Ph.D. Aerospace and Mechanical Sciences, Princeton University, Prince-
ton, NJ, USA, under the supervision of Prof. Martin Summerfield
1973: Assistant Professor of Aerospace Propulsion, Politecnico di Milano,
Milan, Italy
1967: Laurea Aeronautical Engineering, Politecnico di Milano, Milan, Italy
Accolades
2015 Fall: Visiting Professor NUST (Nanjing University of Science and Tech-
nology), Nanjing, China
2015 Spring: Visiting Professor Konkuk University, Seoul, Korea
2014: Honorary Fellowship by High-Energy Materials Society of India
(HEMSI), India
2013: Guest Professor NUST (Nanjing University of Science and Technology),
Nanjing, China
2010: Honorary Professor OmSTU (Omsk State Technical University), Omsk,
Russia
1998: Visiting Scholar, Kyushu Institute of Technology, Japan
1997: Visiting Scientist, CalTech, Pasadena, CA, USA
1993: Visiting Scholar, Brigham Young University, Provo, UT, USA
1977: Visiting Scientist, Princeton University, Princeton, NJ, USA
xvii
luigi.deluca@polimi.it
xviii Short Biography
Toru Shimada
Professor of Space Flight Systems
JAXA/ISAS Japan Aerospace Exploration Agency,Sagamihara,Japan
Timeline
2006–Present: Professor, Institute of Space and Astronautical Science, JAXA
2006–Present: Visiting Professor, University of Tokyo, Graduate School of
Engineering
2007–2003: Technical Manager of MuV Launch Vehicle Project, JAXA
2006–2000: Associate Professor, Institute of Space and Astronautical Science,
JAXA
2000–1985: Senior Engineer, Aerospace Division, Nissan Motor Co., Ltd.
1985: Doctor of Engineering, University of Tokyo (Aeronautics)
1982: Master of Engineering, University of Tokyo (Aeronautics)
1980: Bachelor of Engineering, Kyoto University (Aeronautical Engineering)
Research
Flow dynamics inside solid/hybrid rocket motor combustion chambers and
nozzles including internal ballistics, multiphase flows, ablation phenomena of
nozzle TPS, combustion instability, fuel/propellant regression rate modeling,
CFD for combustive, swirling, and turbulent flows.
R&D for low-cost launch vehicle systems dedicated for nano/micro satellites,
using hybrid rocket engines
luigi.deluca@polimi.it
Short Biography xix
Valery P. Sinditskii
Professor and Head of Department of Chemical Engineering
Mendeleev University of Chemical Technology,Moscow,Russia
Timeline
2008–Present: Dean of Chemical Engineering Department at Mendeleev Univer-
sity of Chemical Technology of Russia
1999–Present: Professor, Mendeleev University of Chemical Technology of
Russia
1999–Present: Head of Chair, Mendeleev University of Chemical Technology of
Russia
1999–1997: Associate Professor, Mendeleev University of Chemical Technology
of Russia
1997–1984: Senior Researcher, Mendeleev University of Chemical Technology
of Russia
1984–1981: Researcher, Mendeleev University of Chemical Technology of
Russia
1981–1976: Ph.D. in Chemistry, Academy of Science of USSR
1976: Graduated from Moscow State University, Department of Chemistry
Research
Energetic materials, synthesis, combustion, thermal decomposition, and application
Accolades
2013: Foreign honorary member of the High-Energy Materials Society of India
2012: Visiting professor of Beijing Institute of Technology, China
2010–Present: Associate editor of “International Journal of Energetic Materials
and Chemical Propulsion”
2010–Present: Editorial board of “Combustion, Explosion, and Shock Waves”
2002–Present Editorial board of “Central European Journal of Energetic
Materials”
luigi.deluca@polimi.it
xx Short Biography
Max Calabro
Consultant
Mechanical Engineer INSA,Lyon
Timeline
2004–Present: Consultant at “The Inner Arch” S.A.R.L.
2003–2002: ONU Inspector in Baghdad (UNMOVIC)
2002–1965: EADS
2002–1985:Chairman of the Steering Committee for Propulsion R&D
2001–1990: Head of the Propulsion Department
1982: In charge of Propulsion Design Team
1972: Managementof rocket motor design and development
1973–1969: Studies on propulsion design for civil launchers and military
satellites propulsion system design
1969–1965: Development of the cryogenic engine HM 4, ancestor of the
HM7B
Memberships
IAF (International Astronautic Federation) IPC Member
Fellow Member and Vice-President of European Conference for Aerospace
Sciences (EUCASS)
AIAA: Associated Fellow and SRTC Emeritus Member
Member of IAA (International Astronautical Academy)
AAAF Emerit. Member
luigi.deluca@polimi.it
... the previous work of the laser spectroscopy thechnique .the first is Fourier transform infrared (FTIR) spectroscopy is the ability to obtain real-time spectral measurements by collecting data over a large wavelength range using an interferometer [8]. of UV-visible spectroscopy are identical to those used in infrared spectroscopy, with the exception of the interferometer, which is replaced by a monochromator in the UV-visible region [9]. Infrared cameras and thermal imagers record images using infrared (IR) radiation instead of the visible light used by conventional cameras [10]. ...
... Figure .5. shows the thermal spectrum of exhaust solid propellant. The second harmonic generation of NH, C2 and CH spectra was measured under experimental pressure, temperature, exhaust and high flow velocity conditions, and the results are shown in Figs 6,7,8,9 and 10. The majority of these chemicals' spectra are limited to the near to mid-infrared range from 1 to 5 µm. ...
Article
In this paper, the design and implementation of a proposed visual system, based on laser spectroscopy (LS) of the products of solid missile fuel combustion (MFC), is one of the most prominent scientific works in the field of spacecraft in the past two decades, to determine the quality of the manufacture, before placing the solid missile fuel in the propulsion engine and the actual experience of the missile engine. The prominent scientific contribution to the proposed research is the spectroscopy using laser chamber test for the missile fuel exhaust represented by, CH4 / N 2 0, CN, C3H8, OH. Where the results showed the exact values of the output of these organic compounds (OC) at the start of the ignition of solid missile fuel to the end of the trial time.
Article
Based on the methods of quantum chemistry and atom–atom potentials, the molecular and crystal structure of a number of high-energy pyrazines was modeled: unsubstituted diazines, as well as fully nitrated 1,4-diazabenzenes, their oxides and polymorphs. The enthalpies of formation, densities of molecular crystals, and some performance characteristics of these compounds were determined. The parameters of decomposition of substances were estimated. It has been established that tetranitropyrazine-1,4-dioxide has maximum energy content and excellent performance characteristics, which determine the prospects for using this compound as a high-energy one in the considered series of compounds. In this work, DFT calculations were conducted through the software Gaussian 09 using B3LYP functional with basis set aug-cc-PVDZ and the Grimme dispersion correction D2. For crystal structure optimization, the atom–atom potential methods with PMC program (Packing of Molecules in Crystal) were used. Charges for molecular electrostatic potential were fitted by FitMEP and enthalpies of formation in gas phase were assessed by G3B3.
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Modern energy policies encourage the replacement of fossil fuels with a more sustainable type. Succinic acid is a promising renewable material that can react with ethylene glycol and 1,4‐butanediol in a two‐step polycondensation reaction to form hydroxylated polyesters. Copolymerization reactions were investigated to produce novel green binders for manufacture of solid propellants. The ester of the first step of polycondensation was used as a plasticizer in the propellant formulation. These products can be an alternative to binders of fossil sources, such as hydroxyl‐terminated polybutadiene (HTPB), frequently used as fuel of commercial propellants. Initially, analyses of Fourier transform infrared spectroscopy, nuclear magnetic resonance and gel permeation chromatography indicated the formation of polymeric products and adequate chain growth at reaction conditions. Then, the obtained copolymers were characterized by rheological analyses, which revealed that the processability of the copolymer materials was similar to that of the HTPB samples. Additionally, thermogravimetric analyses indicated that the copolymers presented good thermal stability below 200°C. Furthermore, differential scanning calorimetric (DSC) analyses indicated that the glass transition temperatures of the obtained copolymer samples ranged from −20 to −60°C, a suitable range for the intended use. Solid propellants were then prepared with solid loadings above 70 wt %, heat of combustion above 11,300 J g ⁻¹ and heat of explosion above 4,980 J g ⁻¹ , which are compatible with values expected for solid propellants. Finally, oxygen balance calculations showed that the intrinsic oxygen content of the polyesters can allow the reduction of amounts of oxidizers in the final propellants.
Article
The aim of this work is to develop a new numerical calculation program making it possible to correct the thrust coefficient CF and the exit Mach number ME of an existing MLN by studying the effect of the stagnation temperature T0 of the combustion chamber below the dissociation threshold of the molecules, based on the use of the HT model to, firstly, correct the flow in the nozzle, and then deduce the new corresponding values of (CF)C and (ME)C. The nozzle equipped with missiles and supersonic aircraft is determined using the PG model. This model is developed without dependence of T0. In reality, and depending on the used propellants, the combustion chamber T0 value can reach high values exceeding 500 K. Since T0 can be high, the (CF)C and (ME)C cannot be those obtained by the PG model. They must respond to the behavior of T0 effect, since the gas actually behaves like a gas at HT. Since the MLN has an unchanged contour, that is to say the mass of the nozzle is unchanged, it is necessary to correct the (CF)PG as well as, (ME)PG in order to further correct the other performances of the aerospace machines using the MLN, like the range, flight time, and maximum altitude of the supersonic missiles. An introduction of two new dimensionless coefficients λ and ψ making it possible to respectively determine the correction rate of (CF)C and (ME)PG compared to those determined by the manufacturers during the design of the MLN by the PG model. The calculation of the error between the obtained correction value and that given by the manufacturer is done for all parameters. The application is made for air and for three other gases H2O (gas), CO and N2. For example when (ME)PG = 3.00, T0 = 3500 K, r* = 1.00 and air, we will have a correction until 21.16% for (CF)C and 9.50% for (ME)C.
Chapter
Ammonium perchlorate (AP) is the most commonly used oxidizers in solid rocket propellants. Although AP possesses high oxygen balance, high density, high thermal stability, and good compatibility, it also exhibits biological toxicity. What’s more, the combustion of AP releases hydrochloric acid, which not only causes ozone layer depletion and acid rain, but also generates smoke trail and results in tactical disadvantage. Plenty of work has been carried out to develop environmentally friendly substitutions for AP. However, applications of these candidates are still restricted due to some critical limitations. In this chapter, we mainly reviewed several green oxidizers which could potentially replace AP in solid rocket propellants. The preparation, modification, properties, and applications of these environmentally friendly oxidizers are discussed. Further research and development of new oxidizers are still needed in future to find green oxidizer products.
Chapter
High-energy density materials are widely used in various application areas, which makes the creation of new materials and study of their properties an important task. The paper addresses to the study of properties of a number of promising high-energy tetracyclic compounds annelated with pyrrole nitro derivatives, by quantum-chemical methods within the Gaussian 09 software package. Optimized structures, enthalpies of formation, and IR absorption spectra have been calculated for existing and not yet synthesized compounds. Dependence of the enthalpy of formation on the structural parameters of the compounds has been analyzed. The energy potential of the studied compounds has been initially assessed.
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The synthesis of substituted 2,4,6,8,10,12-hexaazaisowurtzitane via direct condensation is challenging. The selection of starting ammonia derivatives is very limited. The important step in developing alternative synthetic routes to these compounds is to investigate their formation process in detail. Here, we examined an acid-catalyzed condensation between benzyl carbamate and glyoxal in a ratio of 2:1 in a range of polar protic and aprotic solvents, and discovered a new process occurring during the cascade condensation of glyoxal with ammonia derivatives as well as discovered several processes hindering the formation of caged compounds. More specifically, a cyclic compound, N,N′-bis(carbobenzoxy)-3,6-diamino-1,4-dioxane-2,5-diol, was found to form at the early stage of condensation under low acidity conditions. The formation of this compound is governed by an easier condensation of alcohol groups compared to the amide ones. The condensation intermediates, N,N′-bis(carbobenzoxy)ethan-1,2-diol, N,N′,N″-tris(carbobenzoxy)ethanol, and N,N′,N″,N‴-tetrakis(carbobenzoxy)ethan, were obtained at a higher acidity. A range of solvents were identified: those that react with benzyl carbamate, those that promote the progress of side processes, and those that promote precipitation of condensation intermediates. A few byproducts were isolated and identified. It was found that DMSO exhibits a strong deactivating ability, while CH3CN exhibits a strong activating ability towards the acid-catalyzed condensation process of benzyl carbamate with glyoxal.
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Full-text available
The gas-phase enthalpies of formation (DfH298) of guanidine and its 10 amino and nitro derivatives were calculated using the isodesmic reaction method at the Gaussian-4 level of theory. The enthalpies of sublimation (DsubH 298) were estimated in the framework of the Politzer approach that combines the empirical equation for enthalpy of sublimation with the B3LYP/cc-pVTZ calculations of the electronic properties of the molecular surfaces. The enthalpies of sublimation of mono-, di-, and triaminoguanidine were also estimated using experimental data for their salts. On the basis of the calculated DfH 298(g) and DsubH 298 values, the solid-phase enthalpies of formation were estimated for all guanidine derivatives. A predictive model confirms the available experimental data for guanidine, nitroguanidine, and some of their derivatives. The calculated value of solid-phase enthalpy of formation of high-nitrogen energetic compound 3,6-bis(2-nitroguanidino)-1,2,4,5-tetrazine is also in reasonable agreement with the reported experimental values.
Article
Full-text available
Thermal decomposition of 3,6-bis-nitroguanyl-1,2,4,5-tetrazine (NQ2Tz) its bistriaminoguanidinium salt (TAG2NQ2Tz) in isothermal and non isothermal conditions has been studied. Thermal stability of NQ2Tz exceeds to the stability of HMX, thermal stability of TAG2NQ2Tz is significantly less. Burning rates of NQ2Tz and TAG2NQ2Tz have been measured. It turned out, that obtained burning rates differ from published ones. The thermocouple measurements in the combustion wave of NQ2Tz and TAG2NQ2Tz showed that their combustion controls by condensed-phase mechanism.
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The triple dissociation of s-tetrazine to HCN + HCN + N2 has been investigated by ab initio molecular electronic structure theory.
Article
3-Substituted 6-(3,5-dimethylpyrazol-1-yl)-[1,2,4]triazolo[4,3-b][1,2,4,5]tetrazines were synthesized by cyclization of 6-hydrazino-3-(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine with ortho esters and carbon disulfide and by oxidation of the corresponding hydrazones.
Article
3,6-Bishydrazino-1,2,4,5-tetrazine was synthesized as described by hydrazinolysis of 3,6-bis-(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine. Doubly protonated 1:1 and 1:2 salts of the highly energetic anions were synthesized. These are bishydrazinium-tetrazine dichloride dihydrate (1:2) (BHT-2HCl·2H2O) (2), bishydrazinium-tetrazine (5,5′-azotetrazolate) dihydrate (1:1) (BHT-ATz·2H2O) (3), bishydrazinium-tetrazine bis (3,5-dinitrotriazolate) dihydrate (1:2) (BHT- (DNT)2·2H2O) (4), bishydrazinium-tetrazine bis (5-nitrotetrazolate) (1:2) (BHT- (NT)2) (5), bishydrazinium-tetrazine (5,5′-bistetrazolate) dihydrate (1:1) (BHTBT ·2H2O) (6), bishydrazinium-tetrazine bistetrazolylamine (1:1) (BHT-BTA) (7), bishydrazinium-tetrazine bis (3-amino-5-nitrotriazolate) (1:2) (BHT-(ANTA)2) (8) and bishydrazinium-tetrazine 4,4′,5,5′-tetranitro-2,2′-bisimidazolate (1:1) (9). Compounds 2-6 could be characterized by low temperature X-ray diffraction. All of the compounds were sufficiently analyzed by 1H and {1H}13C and 14N NMR spectroscopy, elemental analysis (CHN), mass spectroscopy (FAB)) and vibrational spectroscopy (IR and Raman). The detonation parameters of the most promising candidates 5 and 9 in terms of energetic applications were calculated using the EXPLO5 V5.05 computer code. The energies of formation were calculated using CBS-4M electronic enthalpies and the atomization method. Furthermore, since all of the compounds are energetic materials, sensitivity tests towards impact (IS), friction (FS) and electrostatical discharge (ESD) were carried out. In addition their thermal stabilities were determined using a differential scanning calorimeter with a heating rate of 5 °C min-1.
Chapter
This chapter deals mainly with aromatic systems, describes the concept of heteroaromaticity, and considers the aromaticity of heteropentalenes, particularly azapentalenes. Azapentalenes can be broadly defined as the heterocyclic analogs of pentalene which are aromatic by virtue of a 10-Π -electron system, and compounds of this type can thus be iso-Π-electronic with the pentalene dianion. Methods of synthesis, chemical reactivity, and spectroscopic properties of azapentalenes are also presented. The chapter concludes with a brief discussion on azapentalenes industrial uses and their biological activities. In specific, type A azapentalenes systems behave as two separate aromatic rings, as there is lack of interaction between the two parts. Type B azapentalenes behave as one ring, but the aromatic character in certain systems is more localized in the ring that lacks the heteroatom X. Only type C azapentalenes can accurately be represented by a delocalized Π-system extending over both rings. Certain benzo derivatives of type B and C systems behave as a benzene ring and a heteroaromatic ring joined by a bridge.