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ChemInform Abstract: REACTIONS OF DIALKYL TRIMETHYLSILYL PHOSPHITE AND ETHYL TRIMETHYLSILYL ETHYLPHOSPHONITE WITH ALKYL AND ACYL HALIDES

Authors:
T. KH. GAZIZOV
T. KH. GAZIZOV
T. KH. GAZIZOV
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YU. I. SUDAREV
YU. I. SUDAREV
YU. I. SUDAREV
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A. N. PUDOVIK
A. N. PUDOVIK
A. N. PUDOVIK
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Abstract

Bei der Umsetzung der 0,0-Dialkyl-dimethylsilylphosphite (I) und (V) mit Chlormethyläther (II), Benzylchlorid (VI) oder Acetylbromid (VIII) unter milden Bedingungen beobachtet man Arbusovumlagerung zu Phosphonaten (III), (VII), (IX) und Abspaltung der Trimethylsilylgruppe als Halogenid (IV) und (X).

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